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arXiv:2107.04425 · Quantum

Optimal nonequilibrium thermometry in Markovian environments

Pavel Sekatski, Martí Perarnau-Llobet

Published Dec 7, 2022• 29 citations
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Abstract

What is the minimum time required to take a temperature? In this paper, we solve this question for a large class of processes where temperature is inferred by measuring a probe (the thermometer) weakly coupled to the sample of interest, so that the probe's evolution is well described by a quantum Markovian master equation. Considering the most general control strategy on the probe (adaptive measurements, arbitrary control on the probe's state and Hamiltonian), we provide bounds on the achievable measurement precision in a finite amount of time, and show that in many scenarios these fundamental limits can be saturated with a relatively simple experiment. We find that for a general class of sample-probe interactions the scaling of the measurement uncertainty is inversely proportional to the time of the process, a shot-noise like behaviour that arises due to the dissipative nature of thermometry. As a side result, we show that the Lamb shift induced by the probe-sample interaction can play a relevant role in thermometry, allowing for finite measurement resolution in the low-temperature regime. More precisely, the measurement uncertainty decays polynomially with the temperature as T→0 , in contrast to the usual exponential decay with T−1 . We illustrate these general results for (i) a qubit probe interacting with a bosonic sample, where the role of the Lamb shift is highlighted, and (ii) a collective superradiant coupling between a N -qubit probe and a sample, which enables a quadratic decay with N of the measurement uncertainty.

DOI
10.22331/q-2022-12-07-869

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What is the minimum time required to take a temperature? In this paper, we solve this question for a large class of processes where temperature is inferred by measuring a probe (the thermometer) weakly coupled to the sample of interest, so that the probe's evolution is well described by a quantum Markovian master equation. Considering the most general control strategy on the probe (adaptive measurements, arbitrary control on the probe's state and Hamiltonian), we provide bounds on the achievable measurement precision in a finite amount of time, and show that in many scenarios these fundamental limits can be saturated with a relatively simple experiment. We find that for a general class of sample-probe interactions the scaling of the measurement uncertainty is inversely proportional to the time of the process, a shot-noise like behaviour that arises due to the dissipative nature of thermometry. As a side result, we show that the Lamb shift induced by the probe-sample interaction can play a relevant role in thermometry, allowing for finite measurement resolution in the low-temperature regime. More precisely, the measurement uncertainty decays polynomially with the temperature as T→0 , in contrast to the usual exponential decay with T−1 . We illustrate these general results for (i) a qubit probe interacting with a bosonic sample, where the role of the Lamb shift is highlighted, and (ii) a collective superradiant coupling between a N -qubit probe and a sample, which enables a quadratic decay with N of the measurement uncertainty.
What is the minimum time required to take the temperature? In this paper, we solve this question for any process where temperature is inferred by measuring a probe (the thermometer) weakly coupled to the sample of interest, so that the probe's evolution is well described by a quantum Markovian master equation. Considering the most general control strategy on the probe (adaptive measurements, arbitrary control on the probe's state and Hamiltonian), we provide bounds on the achievable measurement precision in a finite amount of time, and show that in many scenarios these fundamental limits can be saturated with a relatively simple experiment. We find that for a general class of sample-probe interactions the scaling of the measurement uncertainty is inversely proportional to the time of the process, a shot-noise like behaviour that arises due to the dissipative nature of thermometry. As a side result, we show that the Lamb shift induced by the probe-sample interaction can play a relevant role in thermometry, allowing for finite measurement resolution in the low-temperature regime (more precisely, the measurement uncertainty decays polynomially with the temperature as T→0T\rightarrow 0T→0, in contrast to the usual exponential decay with T−1T^{-1}T−1). We illustrate these general results for (i) a qubit probe interacting with a bosonic sample, where the role of the Lamb shit is highlighted, and (ii) a collective superradiant coupling between a NNN-qubit probe and a sample, which enables a quadratic decay with N2N^2N2 of the measurement uncertainty.
We investigate the limits of thermometry using quantum probes at thermal equilibrium within the Bayesian approach. We consider the possibility of engineering interactions between the probes in order to enhance their sensitivity, as well as feedback during the measurement process, i.e., adaptive protocols. On the one hand, we obtain an ultimate bound on thermometry precision in the Bayesian setting, valid for arbitrary interactions and measurement schemes, which lower bounds the error with a quadratic (Heisenberg-like) scaling with the number of probes. We develop a simple adaptive strategy that can saturate this limit. On the other hand, we derive a no-go theorem for nonadaptive protocols that does not allow for better than linear (shot-noise-like) scaling even if one has unlimited control over the probes, namely, access to arbitrary many-body interactions.
We consider the problem of estimating the temperature TTT of a very cold equilibrium sample. The temperature estimates are drawn from measurements performed on a quantum Brownian probe strongly coupled to it. We model this scenario by resorting to the canonical Caldeira-Leggett Hamiltonian and find analytically the exact stationary state of the probe for arbitrary coupling strength. In general, the probe does not reach thermal equilibrium with the sample, due to their nonperturbative interaction. We argue that this is advantageous for low-temperature thermometry, as we show in our model that (i) the thermometric precision at low TTT can be significantly enhanced by strengthening the probe-sampling coupling, (ii) the variance of a suitable quadrature of our Brownian thermometer can yield temperature estimates with nearly minimal statistical uncertainty, and (iii) the spectral density of the probe-sample coupling may be engineered to further improve thermometric performance. These observations may find applications in practical nanoscale thermometry at low temperatures---a regime which is particularly relevant to quantum technologies.
We study low-temperature non-equilibrium quantum thermometry with a bosonic probe: a quantum harmonic oscillator strongly coupled to a bosonic bath at temperature TTT through a Drude--Ohmic spectral density. We treat the probe--bath dynamics both exactly, using the quadratic solution of Boyanovsky and Jasnow, and within a renormalized Gorini--Kossakowski--Lindblad--Sudarshan (GKLS) master equation. From the time-dependent covariance matrix we extract the quantum Fisher information (QFI) for general single-mode Gaussian probe states, including squeezed ones. In the strong-coupling, non-Markovian regime the QFI is non-monotonic in time, displaying bath-memory revivals that make a finite interrogation time t∗>0t^*>0t∗>0 strictly optimal. By contrast, we prove that the Markovian QFI rises monotonically to its stationary value and develops no interior optimum, so that its optimum is always pinned to the boundary t∗→∞t^*\to\inftyt∗→∞; this complements existing Markovian precision-rate bounds, which concern (F(t)/t)(\mathcal F(t)/t)(F(t)/t) rather than the single-shot QFI (F(t))(\mathcal F(t))(F(t)). Squeezed initial states yield a large transient advantage that thermalisation eventually erases, establishing squeezing and interrogation time as complementary thermometric resources. At equilibrium, strong coupling replaces the exponential Boltzmann suppression of the low-temperature relative error by a far milder polynomial divergence. As the model maps directly onto circuit quantum electrodynamics, these protocols appear within current experimental reach.
Abstract Temperature estimation plays a vital role across natural sciences. A standard approach is provided by probe thermometry, where a probe is brought into contact with the sample and examined after a certain amount of time has passed. In situations where, for example, preparation of the probe is non-trivial or total measurement time of the experiment is the main resource that must be optimized, continuously monitoring the probe may be preferred. Here, we consider a minimal model, where the probe is provided by a two-level system coupled to a thermal reservoir. Monitoring thermally activated transitions enables real-time estimation of temperature with increasing accuracy over time. Within this framework we comprehensively investigate thermometry in both bosonic and fermionic environments employing a Bayesian approach. Furthermore, we explore adaptive strategies and find a significant improvement on the precision. Additionally, we examine the impact of noise and find that adaptive strategies may suffer more than non-adaptive ones for short observation times. While our main focus is on thermometry, our results are easily extended to the estimation of other environmental parameters, such as chemical potentials and transition rates.
Accurate temperature estimation in the quantum and cryogenic regimes remains a fundamental challenge. Here, we investigate nonequilibrium quantum thermometry using a single-qubit probe coupled to a bosonic bath through noncommuting interaction operators, which unify pure dephasing and dissipative dynamics within a spin-boson model. We show that the interference between these two coupling channels induces strong non-Markovian feedback between populations and coherences, leading to coherence trapping and enhanced thermal sensitivity. Remarkably, by tuning the coupling structure, the probe's temperature sensitivity exhibits a quadratic low-temperature scaling, even under weak coupling. Moreover, while coherence-based measurements are formally suboptimal, they become the most informative in the early nonequilibrium regime, where memory effects dominate. Our findings identify noncommutative system-bath couplings as a practical and tunable resource for achieving high-precision quantum thermometry in realistic open-system architectures.