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arXiv:2606.27894

Non-equilibrium quantum thermometry with bosonic samples

Marek Winczewski, Michał Horodecki, Ricard Ravell Rodríguez

quant-phSubmitted Jun 26, 2026• Announced Jun 29, 2026• 0 citations
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Abstract

We study low-temperature non-equilibrium quantum thermometry with a bosonic probe: a quantum harmonic oscillator strongly coupled to a bosonic bath at temperature $T$ through a Drude--Ohmic spectral density. We treat the probe--bath dynamics both exactly, using the quadratic solution of Boyanovsky and Jasnow, and within a renormalized Gorini--Kossakowski--Lindblad--Sudarshan (GKLS) master equation. From the time-dependent covariance matrix we extract the quantum Fisher information (QFI) for general single-mode Gaussian probe states, including squeezed ones. In the strong-coupling, non-Markovian regime the QFI is non-monotonic in time, displaying bath-memory revivals that make a finite interrogation time $t^*>0$ strictly optimal. By contrast, we prove that the Markovian QFI rises monotonically to its stationary value and develops no interior optimum, so that its optimum is always pinned to the boundary $t^*\to\infty$; this complements existing Markovian precision-rate bounds, which concern $(\mathcal F(t)/t)$ rather than the single-shot QFI $(\mathcal F(t))$. Squeezed initial states yield a large transient advantage that thermalisation eventually erases, establishing squeezing and interrogation time as complementary thermometric resources. At equilibrium, strong coupling replaces the exponential Boltzmann suppression of the low-temperature relative error by a far milder polynomial divergence. As the model maps directly onto circuit quantum electrodynamics, these protocols appear within current experimental reach.

Comments
15+9 pages, 5 figures

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We study low-temperature non-equilibrium quantum thermometry with a bosonic probe: a quantum harmonic oscillator strongly coupled to a bosonic bath at temperature TTT through a Drude--Ohmic spectral density. We treat the probe--bath dynamics both exactly, using the quadratic solution of Boyanovsky and Jasnow, and within a renormalized Gorini--Kossakowski--Lindblad--Sudarshan (GKLS) master equation. From the time-dependent covariance matrix we extract the quantum Fisher information (QFI) for general single-mode Gaussian probe states, including squeezed ones. In the strong-coupling, non-Markovian regime the QFI is non-monotonic in time, displaying bath-memory revivals that make a finite interrogation time t∗>0t^*>0t∗>0 strictly optimal. By contrast, we prove that the Markovian QFI rises monotonically to its stationary value and develops no interior optimum, so that its optimum is always pinned to the boundary t∗→∞t^*\to\inftyt∗→∞; this complements existing Markovian precision-rate bounds, which concern (F(t)/t)(\mathcal F(t)/t)(F(t)/t) rather than the single-shot QFI (F(t))(\mathcal F(t))(F(t)). Squeezed initial states yield a large transient advantage that thermalisation eventually erases, establishing squeezing and interrogation time as complementary thermometric resources. At equilibrium, strong coupling replaces the exponential Boltzmann suppression of the low-temperature relative error by a far milder polynomial divergence. As the model maps directly onto circuit quantum electrodynamics, these protocols appear within current experimental reach.
Abstract We characterise the measurement sensitivity, quantified by the quantum Fisher information (QFI), of a single-fermionic thermometric probe strongly coupled to the sample of interest, a fermionic bath, at temperature T. For nonequilibrium protocols, in which the probe is measured before reaching equilibrium with the sample, we find new behaviour of the measurement sensitivity arising due to non-Markovian dynamics. First, we show that the QFI displays a highly non-monotonic behaviour in time, in contrast to the Markovian case where it grows monotonically until equilibrium, so that non-Markovian revivals can be exploited to reach a higher QFI. Second, the QFI rate is maximised at a finite interrogation time t ∗ , which we characterize, in contrast to the solution t ∗ → 0 known in the Markovian limit (Pavel Sekatski and Martí Perarnau-Llobet 2022 Quantum 6 869). Finally, we consider probes make up of few fermions and discuss different collective enhancements in the measurement precision.
The fundamental metrological limits of temperature sensing in open quantum systems remain largely unresolved, particularly regarding the role of non-Gaussian quantum resources. In this letter, we establish analytic bounds on the quantum Fisher information (QFI) for temperature estimation using non-Gaussian states undergoing dissipative bosonic evolution. By focusing on the short-time regime governed by a time-local master equation, we derive precise scaling laws that elucidate when and how non-Gaussian probes decisively outperform Gaussian states under identical energy constraints. Our analysis uncovers a distinct linear-in-time QFI enhancement unique to Fock states, in contrast to the inherently weaker, quadratic scaling of Gaussian probes. These theoretical insights are substantiated through exact numerical simulations and mapped onto experimentally accessible platforms such as circuit QED. Our results not only clarify the quantum thermometric advantage of non-Gaussianity but also chart a realistic pathway toward harnessing it in noisy quantum technologies.
Accurate temperature estimation in the quantum and cryogenic regimes remains a fundamental challenge. Here, we investigate nonequilibrium quantum thermometry using a single-qubit probe coupled to a bosonic bath through noncommuting interaction operators, which unify pure dephasing and dissipative dynamics within a spin-boson model. We show that the interference between these two coupling channels induces strong non-Markovian feedback between populations and coherences, leading to coherence trapping and enhanced thermal sensitivity. Remarkably, by tuning the coupling structure, the probe's temperature sensitivity exhibits a quadratic low-temperature scaling, even under weak coupling. Moreover, while coherence-based measurements are formally suboptimal, they become the most informative in the early nonequilibrium regime, where memory effects dominate. Our findings identify noncommutative system-bath couplings as a practical and tunable resource for achieving high-precision quantum thermometry in realistic open-system architectures.
We investigate a nonequilibrium quantum thermometry protocol in which an ensemble of qubits, acting as temperature probes, is weakly coupled to a macroscopic thermal bath. The temperature of the bath, the parameter of interest, is encoded in the dissipator of a Markovian thermalization process. For some relevant initial states, we observe a peak in the Quantum Fisher Information (QFI) during the transient of the thermalization, indicating enhanced sensitivity in early-time dynamics. This effect becomes more pronounced at higher bath temperatures and is further enhanced when the initial reduced state of the qubits has a large ground-state population and/or it is highly coherent. We also focus on the role of initial quantum correlations in the thermometric performance, which emerge as a central feature of this work. We find strong numerical evidence that, given same single-qubit reduced states, the inclusion of quantum correlations among the qubits of the ensemble always yields an enhanced QFI. Moreover, even if none of the considered states outperform the (pure, separable) ground state, maximally entangled states display QFIs values remarkably close to the standard quantum limit when probing extremely hot thermal baths. Finally, although the Markovian dynamics does not permit superlinear scaling of the QFI with the number of probes, we identify the most effective initial states for designing high-precision quantum thermometers within this setting. We also provide concrete guidelines for experimental implementations.
Quantum thermometry provides a key capability for nanoscale devices and quantum technologies, but most existing strategies rely on probes initialized near equilibrium. This equilibrium paradigm imposes intrinsic limitations: sensitivity is tied to long-time thermalization and often cannot be improved in fast, noisy, or nonstationary settings. In contrast, the \textit{Mpemba effect}, the counterintuitive phenomenon where hotter states relax faster than colder ones, has mostly been viewed as a thermodynamic anomaly. Here, we bridge this gap by proving that Mpemba-type inversions generically yield a finite-time enhancement of the quantum Fisher information (QFI) for temperature estimation, thereby converting an anomalous relaxation effect into a concrete metrological resource. Through explicit analyses of two-level and ΛΛΛ-level probes coupled to bosonic baths, we show that nonequilibrium initializations can transiently outperform both equilibrium strategies and colder states, realizing a \emph{metrological Mpemba effect}. Our results establish anomalous relaxation as a general design principle for nonequilibrium quantum thermometry, enabling ultrafast and nanoscale sensing protocols that exploit, rather than avoid, transient dynamics.
What is the minimum time required to take the temperature? In this paper, we solve this question for any process where temperature is inferred by measuring a probe (the thermometer) weakly coupled to the sample of interest, so that the probe's evolution is well described by a quantum Markovian master equation. Considering the most general control strategy on the probe (adaptive measurements, arbitrary control on the probe's state and Hamiltonian), we provide bounds on the achievable measurement precision in a finite amount of time, and show that in many scenarios these fundamental limits can be saturated with a relatively simple experiment. We find that for a general class of sample-probe interactions the scaling of the measurement uncertainty is inversely proportional to the time of the process, a shot-noise like behaviour that arises due to the dissipative nature of thermometry. As a side result, we show that the Lamb shift induced by the probe-sample interaction can play a relevant role in thermometry, allowing for finite measurement resolution in the low-temperature regime (more precisely, the measurement uncertainty decays polynomially with the temperature as T→0T\rightarrow 0T→0, in contrast to the usual exponential decay with T−1T^{-1}T−1). We illustrate these general results for (i) a qubit probe interacting with a bosonic sample, where the role of the Lamb shit is highlighted, and (ii) a collective superradiant coupling between a NNN-qubit probe and a sample, which enables a quadratic decay with N2N^2N2 of the measurement uncertainty.