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arXiv:2105.14358 · Physical Review A

Enhancing energy transfer in quantum systems via periodic driving: Floquet master equations

Z. Nafari Qaleh, A. T. Rezakhani

Published Jan 12, 2022• 11 citations
arXivHTMLPDF

Abstract

We provide a comprehensive study of the energy-transfer phenomenon---populating a given energy level---in three- and four-level quantum systems coupled to two thermal baths. In particular, we examine the effects of an external periodic driving and the coherence induced by the baths on the efficiency of the energy transfer. We consider the Floquet-Lindblad and the Floquet-Redfield scenarios, which both are in the Born-Markov, weak-coupling regime but differ in the treatment of the secular approximation, and for the latter we develop an appropriate Floquet-type master equation by employing a partial secular approximation. Throughout the whole analysis we keep Lamb-shift corrections in the master equations. We observe that, especially in the Floquet-Redfield scenario, the driving field can enhance the energy-transfer efficiency compared to the nondriven scenario. In addition, unlike nondriven degenerate systems where Lamb-shift corrections do not contribute significantly to the energy transfer, in the Redfield and the Floquet-Redfield scenarios these corrections have non-negligible effects.

DOI
10.1103/physreva.105.012208

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We provide a comprehensive study of the energy-transfer phenomenon---populating a given energy level---in three- and four-level quantum systems coupled to two thermal baths. In particular, we examine the effects of an external periodic driving and the coherence induced by the baths on the efficiency of the energy transfer. We consider the Floquet-Lindblad and the Floquet-Redfield scenarios, which both are in the Born-Markov, weak-coupling regime but differ in the treatment of the secular approximation, and for the latter we develop an appropriate Floquet-type master equation by employing a partial secular approximation. Throughout the whole analysis we keep Lamb-shift corrections in the master equations. We observe that, especially in the Floquet-Redfield scenario, the driving field can enhance the energy-transfer efficiency compared to the nondriven scenario. In addition, unlike nondriven degenerate systems where Lamb-shift corrections do not contribute significantly to the energy transfer, in the Redfield and the Floquet-Redfield scenarios these corrections have non-negligible effects.
We provide a comprehensive study of heat transport in periodically driven quantum systems using a master equation approach in the Floquet basis. Starting from the exact, formal expressions, we obtain, within the weak coupling regime of system-bath coupling, a generalized Floquet-Redfield master equation which does not involve Markovian or secular approximations and the corresponding formula for the heat current. From this approach we derive the standard, full secular master equation. Moreover, we present a master equation for the driven spin-boson model in the instantaneous eigenbasis. The different approaches are compared by applying them to the steady-state heat transport in the driven spin-boson model. An analytical solution is provided for the master equation in the instantaneous eigenbasis which reproduces the numerics and explains the features of the heat current as a function of the drive parameters.
The dynamics of open quantum systems is commonly described by quantum master equations derived under the assumption of weak system-bath coupling and a separation of timescales between system and bath. When the system is additionally subjected to a periodic driving, the validity of the resulting Floquet master equations is further restricted to regimes of weak or high-frequency driving. Here, we benchmark a set of commonly used Floquet master equations for a model of two locally driven spins coupled to a shared Ohmic reservoir at finite temperature. We systematically probe the accuracy of the equations as a function of the driving parameters, thus identifying limits of their applicability. Dynamical maps predicted by each master equation are compared against numerically exact non-Markovian simulations, tracking the full relaxation dynamics. We find that the accuracy of each master equation closely reflects the assumptions underlying its derivation. For the Floquet-Lindblad equation, errors can be strongly amplified near resonances where the secular approximation breaks down, while approaches that avoid the secular approximation perform better and exhibit a more systematic dependence of the error on driving frequency and amplitude.
Periodically driven open quantum systems are central to quantum thermodynamics and quantum control. These systems are typically described using Floquet-Born-Markov master equations, derived with the use of a full secular approximation, and whose thermodynamic implications are often overlooked. In this context, we show that such a strong secular approximation may lead to unphysical predictions for steady state energy currents. We then demonstrate that a coarse-grained formulation of the master equation can regularize these issues while yielding completely positive dynamics and consistent energy currents. The coarse-graining time has a clear physical interpretation, as it defines the temporal resolution at which a Markovian master equation can describe the evolution of the periodically driven system. We show the consistency and validity of our approach by comparing to an exact non-Markovian simulation in paradigmatic examples: a driven two-level system and a three-level maser coupled to hot and cold thermal reservoirs. Our work provides a practical framework for correctly applying the secular approximation in periodically driven-dissipative systems and for assessing the accuracy of master equations of the GKSL form.
Periodically driven quantum systems are commonly modeled using master equations constructed in the eigenbasis of an undriven Hamiltonian, implicitly assuming that environmental dissipation couples to static energy transitions even under strong time-periodic driving. The validity of this approximation beyond weak or near-resonant driving remains poorly understood. To address the need for a more self-consistent quantum theory approach, we formulate a nonsecular Floquet--Markov generalized master equation (F-GME) in the quasienergy basis, treating interaction-induced (internal) and drive-induced (external) nonperturbative dressing on an equal footing. We subsequently investigate dissipation in two minimal driven open quantum systems---a harmonically driven two-level system and a harmonically driven coupled-two-level-system---each weakly coupled to a Markovian bath. Comparing the F-GME to a time-independent dressed-basis master equation, we show that even for a flat-bath spectral density and weak dissipation, the two approaches can yield qualitatively different steady-state populations and emission spectra. We resolve dissipation into drive-assisted sideband processes decaying via Floquet extended-space quasienergy channels, and show these channels can hybridize through nonsecular couplings into collective Floquet--Liouville modes governing observable spectral resonances. This analysis demonstrates that time-independent dissipative descriptions can incorrectly weight multiphoton Floquet transitions by collapsing quasienergy-resolved decay pathways into static energy gaps. The F-GME framework provides a systematic diagnostic for identifying regimes where Floquet-consistent dissipation is essential and clarifies the physical origin of discrepancies between commonly used master-equation approaches.
Time-periodic quantum systems are present all over science and technology. They have been successfully studied using Floquet theory, and a broad diversity of interesting phenomena such as coherent destruction of tunnelling, dynamical localization and creation of new phases of matter have been discovered. Furthermore, periodic driving has also been introduced as a tool for engineering novel quantum systems that have no static analogue. Besides these remarkable achievements for isolated systems, in reality, systems always interact with their surroundings. Taking the effect of the environment into account, time-periodic quantum systems have been mainly described using the Floquet-Markov approach, which consists in deriving a weak coupling master equation in the Floquet basis. In this thesis, we focus on how to overcome these standard approximations in the description of driven open quantum systems. We start by providing a general review on the topics of isolated driven systems, open quantum systems and the Floquet-Markov approach, before presenting the main results of this work. Under the effect of high-frequency driving, we provide an analytic solution to a large class of open quantum systems. Our method relies on discrete symmetries of the system-bath Hamiltonian and grants access to the time evolution operator of the full system, including bath degrees of freedom. The solution can be interpreted as the stroboscopic evolution of a family of observables under the influence of an effective static Hamiltonian. This provides a flexible simulation procedure of nontrivial Hamiltonians. The results are exemplified with the driven spin-boson model, where a coherent control of dissipation is observed. By a novel combination of Floquet theory, full counting statistics and a Markovian embedding strategy (reaction coordinate mapping), more intricate scenarios with additional driven system-environment interactions are addressed. Hereby, we can access the dynamics and thermodynamics of a periodically driven thermal machine. For the particular case where the working medium is a two-level system, we identify four different operating regimes, including a heat engine and a refrigerator. As the coupling strength is increased, their efficiency and coefficient of performance decrease and the refrigerator regime disappears. Notably, our model reproduces the setup of laser cooling of trapped ions in a specific parameter limit. Following the same combination of methods, we investigate electron pumping through a single quantum dot with periodically modulated energy and tunnelling amplitudes. In the high-frequency regime, the direction of the current can be controlled with the driving phase and a rectification effect that is exclusive to the non-Markovian character of the model is observed. In the low-frequency regime, we apply an additional transformation to view the model as three independent transport channels and observe that the coupling strength also controls the current direction. Studying charge fluctuations we validate that our model behaves as a single-electron source.
We study the dynamics of open quantum systems driven by an external time-periodic force. Combining Floquet theory and the time-convolutionless projection operator technique we derive a time-local quantum master equation which exactly takes into account the periodic driving, while treating the system-environment interaction within second order in the coupling strength without performing the Markov approximation. The resulting equation of motion for the reduced density matrix is called Floquet time-convolutionless master equation. Employing the example of the driven spin-boson system, we demonstrate that this master equation is capable of describing strong non-Markovian effects, while yielding the Floquet-Lindblad master equation in the Markovian limit. A characteristic feature of memory effects in such driven dissipative systems is the emergence of sharp peaks of the trace-distance based non-Markovianity measure as a function of the driving amplitude, which can be traced back to quasienergy crossings leading to almost decoherence-protected subspaces through a quasienergy-induced dissipative decoupling mechanism.