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arXiv:2104.14350 · Reviews of Modern Physics

Nonequilibrium boundary-driven quantum systems: Models, methods, and properties

Gabriel Teixeira Landi, Dario Poletti, Gernot Schaller

Published Dec 13, 2022• 17 citations
arXivHTMLPDF

Abstract

Systems whose boundaries are in contact with heat baths at different temperatures allow for the realization of nonequilibrium steady states (NESS) characterized by distribution functions that are still time independent, yet different from the equilibrium distributions. Such states have interesting properties even in classical statistical mechanics, but recently their quantum analogs have received attention, for both fundamental and applied reasons. This review provides an account of recent progress in this field. It introduces various models to describe the rich NESS phenomenology and covers analytic and numerical methods for analyzing them.

DOI
10.1103/revmodphys.94.045006

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Systems whose boundaries are in contact with heat baths at different temperatures allow for the realization of nonequilibrium steady states (NESS) characterized by distribution functions that are still time independent, yet different from the equilibrium distributions. Such states have interesting properties even in classical statistical mechanics, but recently their quantum analogs have received attention, for both fundamental and applied reasons. This review provides an account of recent progress in this field. It introduces various models to describe the rich NESS phenomenology and covers analytic and numerical methods for analyzing them.
We study the nonequilibrium steady state (NESS) in a quantum system in contact with two heat baths at different temperatures. We use a time-independent perturbative expansion with respect to the coupling with the two heat baths to obtain the density matrix for the NESS. In particular, we show an explicit representation of the density matrix for the reflection symmetric and weakly nonequilibrium case. We also calculate the expectation value of the energy current and show that the Kubo formula holds in this case.
We investigate nonequilibrium steady states of driven-dissipative ideal quantum gases of both bosons and fermions. We focus on systems of sharp particle number that are driven out of equilibrium either by the coupling to several heat baths of different temperature or by time-periodic driving in combination with the coupling to a heat bath. Within the framework of (Floquet-)Born-Markov theory, several analytical and numerical methods are described in detail. This includes a mean-field theory in terms of occupation numbers, an augmented mean-field theory taking into account also nontrivial two-particle correlations, and quantum-jump-type Monte Carlo simulations. For the case of the ideal Fermi gas, these methods are applied to simple lattice models and the possibility of achieving exotic states via bath engineering is pointed out. The largest part of this work is devoted to bosonic quantum gases and the phenomenon of Bose selection, a nonequilibrium generalization of Bose condensation, where multiple single-particle states are selected to acquire a large occupation [Phys. Rev. Lett. 111, 240405 (2013)]. In this context, among others, we provide a theory for transitions where the set of selected states changes, describe an efficient algorithm for finding the set of selected states, investigate beyond-mean-field effects, and identify the dominant mechanisms for heat transport in the Bose-selected state.
The quasi-static evolution of steady states far from equilibrium is investigated from the point of view of quantum statistical mechanics. As a concrete example of a thermodynamic system, a two-level quantum dot coupled to several reservoirs of free fermions at different temperatures is considered. A novel adiabatic theorem for unbounded and nonnormal generators of evolution is proven and applied to study the quasi-static evolution of the nonequilibrium steady state (NESS) of the coupled system. © Birkhäuser Verlag Basel/Switzerland 2007.
The existence and uniqueness of a steady state for nonequilibrium systems (NESS) is a fundamental subject and a main theme of research in statistical mechanics for decades. For Gaussian systems, such as a chain of harmonic oscillators connected at each end to a heat bath, and for anharmonic oscilla-tors under specified conditions, definitive answers exist in the form of proven theorems. Answering this question for quantum many-body systems poses a challenge for the present. In this work we address this issue by deriving the stochastic equations for the reduced system with self-consistent backaction from the two baths, calculating the energy flow from one bath to the chain to the other bath, and exhibiting a power balance relation in the total (chain + baths) system which testifies to the existence of a NESS in this system at late times. Its insensitivity to the initial conditions of the chain corroborates to its uniqueness. The functional method we adopt here entails the use of the influence functional, the coarse-grained and stochastic effective actions, from which one can derive the stochastic equations and calculate the average values of physical variables in open quantum systems. This involves both taking the expectation values of
Continuing our work on the nature and existence of fluctuation-dissipation relations (FDR) in linear and nonlinear open quantum systems [J.-T. Hsiang, B. L. Hu, and S.-Y. Lin, Phys. Rev. D 100, 025019 (2019); J.-T. Hsiang, B. L. Hu, S.-Y. Lin, and K. Yamamoto, Phys. Lett. B 795, 694 (2019); J.-T. Hsiang and B. L. Hu, Physics (Utrecht) 1, 430 (2019); J.-T. Hsiang and B. L. Hu, Phys. Rev. D 101, 125003 (2020)], here we consider such relations when a linear system is in a nonequilibrium steady state (NESS). With the model of two-oscillators (considered as a short harmonic chain with the two ends) each connected to a thermal bath of different temperatures we find that when the chain is fully relaxed due to interaction with the baths, the relation that connects the noise kernel and the imaginary part of the dissipation kernel of the chain in one bath does not assume the conventional form for the FDR in equilibrium cases. There exists an additional term we call the ``bias current'' that depends on the difference of the bath's initial temperatures and the interoscillator coupling strength. We further show that this term is related to the steady heat flow between the two baths when the system is in an NESS. The ability to know the real-time development of the interheat exchange (between the baths and the end-oscillators) and the intraheat transfer (within the chain) and their dependence on the parameters in the system offers possibilities for quantifiable control, and in the design of quantum heat engines, or thermal devices.
Traditionally the study of quantum mechanical ensembles was focused on the exploration of their equilibrium properties: the program has consisted of the classification of the quantum mechanical states of matter, and the identification of the striking phase transitions between them. On the other hand, questions about the out of equilibrium properties of quantum ensembles have largely remained academic until fairly recently. Particularly, the rapid technological progress in the field of atomic physics has enabled experimental demonstrations of nontrivial out of equilibrium phenomena which moreover are describable in terms of relatively simple theoretical models with a few parameters. Thus the time is ripe for a theoretical exploration of nonequilibrium physics. To this end, quantum impurity models offer a natural and simple starting point for studying nonequilibrium phenomena in the context of ultracold atoms, and pave the way toward the study of more complicated systems. I will discuss how the impurity-bath model offers a clean, simple realization of rich phenomenology including the dynamics of polaron formation as well as the orthogonality catastrophe, and can be engineered using dilute mixtures of cold atomic gases. Moreover I will demonstrate how impurity models are also embedded in the more complicated physics of the response of a one-dimensional system to an external perturbation, or a sudden local parameter change. Lastly, I will describe the approach to equilibrium of a more\ncomplicated system, the one dimensional Bose gas, following a sudden parameter change, and discuss some of the important questions which arise in this connection: does a quantum mechanical system thermalize? What is the appropriate asymptotic description of a nonequilibrium state? Does such a system retain a memory of its initial state?