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arXiv:2104.04792

Thermodynamics of a chemical reaction model for the atom-field interaction in a three-level laser

Peter F. Muys

Published Apr 10, 2021• 0 citations
arXivHTMLPDF

Abstract

The temporal evolution of the levels in a three-level laser is macroscopically described by a closed set of rate equations. Here, we complement this picture by providing a model which describes through chemical reactions how the levels are evolving. In most textbooks, the chemical potential is introduced as a concept in quantum statistics. In this paper, we alternatively base its definition on population densities of the excited states in a dopant atom. Then the chemical reaction model delivers a clear and intuitive framework to define the further thermodynamic characteristics of the atom-field interactions such as the chemical potential of the photon and the photon entropy.

DOI
10.48550/arxiv.2104.04792

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The temporal evolution of the levels in a three-level laser is macroscopically described by a closed set of rate equations. Here, we complement this picture by providing a model which describes through chemical reactions how the levels are evolving. In most textbooks, the chemical potential is introduced as a concept in quantum statistics. In this paper, we alternatively base its definition on population densities of the excited states in a dopant atom. Then the chemical reaction model delivers a clear and intuitive framework to define the further thermodynamic characteristics of the atom-field interactions such as the chemical potential of the photon and the photon entropy.
Theory of the interaction between atom and radiation field: three pictures in quantum mechanics description two-level atom and the optical Bloch equation quantized description of the radiation field Dicke Hamiltonian and Jaynes - Cummings model quantum theory of a small system coupling to a reservoir. The quantum properties of light: coherence of light squeezed states of light resonance fluorescence superfluorescence optical bistability effects of virtual photon processes. Quantum properties of the atomic behaviour under the interaction of the radiation field: collapses and revivals of the atomic populations squeezing effects of the atomic operators coherent trapping of the atomic population quantum characteristics of a two-atom system under the interaction of radiation field autoionization of the atom in a laser field motion of the atom in a laser field laser cooling.
The steepest entropy ascent (SEA) dynamical principle provides a general framework for modeling the dynamics of nonequilibrium (NE) phenomena at any level of description, including the atomistic one. It has recently been shown to provide a precise implementation and meaning to the maximum entropy production principle and to encompass many well-established theories of nonequilibrium thermodynamics into a single unifying geometrical framework. Its original formulation in the framework of quantum thermodynamics (QT) assumes the simplest and most natural Fisher-Rao metric to geometrize from a dynamical standpoint the manifold of density operators, which represent the thermodynamic NE states of the system. This simplest SEAQT formulation is used here to develop a general mathematical framework for modeling the NE time evolution of the quantum state of a chemically reactive mixture at an atomistic level. The method is illustrated for a simple two-reaction kinetic scheme of the overall reaction F+H_{2}⇔HF+F in an isolated tank of fixed volume. However, the general formalism is developed for a reactive system subject to multiple reaction mechanisms. To explicitly implement the SEAQT nonlinear law of evolution for the density operator, both the energy and the particle number eigenvalue problems are set up and solved analytically under the dilute gas approximation. The system-level energy and particle number eigenvalues and eigenstates are used in the SEAQT equation of motion to determine the time evolution of the density operator, thus effectively describing the overall kinetics of the reacting system as it relaxes toward stable chemical equilibrium. The predicted time evolution in the near-equilibrium limit is compared to the reaction rates given by a standard detailed kinetic model so as to extract the single time constant needed by the present SEA model.
We present here a fully quantum-mechanical treatment of the laser using a three-level atom model. The phase-space method employed is identical to that in a previous publication of ours [Phys. Rev. A 38, 4073 (1988)] and again results in a Fokker-Planck description of the laser without any approximations. The third level only provides extra deterministic terms and, if it is regarded as a further reservoir to the lasing levels, then the resultant stochastic equations have much improved stability. These equations are suitable for extensive theoretical analysis of both the laser and optical bistability, although in this paper we have concentrated on the adiabatically eliminated limit and calculated the leading noise terms in various regimes. However, we do use the technique of direct numerical simulation to solve exactly the full system of laser equations. The results display clearly many of the known laser characteristics.
The temporal evolution of quantum statistical properties of an interacting atom–radiation field system in the presence of a classical homogeneous gravitational field is investigated within the framework of the Jaynes–Cummings model. To analyse the dynamical evolution of the atom–radiation system a quantum treatment of the internal and external dynamics of the atom is presented based on an alternative su(2) dynamical algebraic structure. By solving the Schrödinger equation in the interaction picture, the evolving state of the system is found by which the influence of the gravitational field on the dynamical behaviour of the atom–radiation system is explored. Assuming that initially the radiation field is prepared in a coherent state and the two-level atom is in a coherent superposition of the excited and ground states, the influence of gravity on the collapses and revivals of the atomic population inversion, atomic dipole squeezing, atomic momentum diffusion, photon counting statistics and quadrature squeezing of the radiation field is studied.