Quantum metrology is a rapidly developing branch of quantum technologies. While various theories have been established on quantum metrology for Markovian processes, i.e., quantum channel estimation, quantum metrology for non-Markovian processes is much less explored. In this Letter, we establish a general framework of non-Markovian quantum metrology. For any parametrized non-Markovian process on a finite-dimensional system, we derive a formula for the maximal amount of quantum Fisher information that can be extracted from it by an optimally controlled probe state. In addition, we design an algorithm that evaluates this quantum Fisher information via semidefinite programming. We apply our framework to noisy frequency estimation, where we find that the optimal performance of quantum metrology is better in the non-Markovian scenario than in the Markovian scenario and explore the possibility of efficient sensing via simple variational circuits.
Quantum metrology is a rapidly developing branch of quantum technologies. While various theories have been established on quantum metrology for Markovian processes, i.e., quantum channel estimation, quantum metrology for non-Markovian processes is much less explored. In this Letter, we establish a general framework of non-Markovian quantum metrology. For any parametrized non-Markovian process on a finite-dimensional system, we derive a formula for the maximal amount of quantum Fisher information that can be extracted from it by an optimally controlled probe state. In addition, we design an algorithm that evaluates this quantum Fisher information via semidefinite programming. We apply our framework to noisy frequency estimation, where we find that the optimal performance of quantum metrology is better in the non-Markovian scenario than in the Markovian scenario and explore the possibility of efficient sensing via simple variational circuits.
The problem of quantum metrology in the context of a particular non-Markovian quantum evolution is explored. We study the dynamics of the quantum Fisher information (QFI) of a composite quantum probe coupled to a Lorentzian environment, for a full variety of different classes of parameters. We are able to find the best metrological state, which is not maximally entangled but is the one which evolves the most rapidly. This is shown by demonstrating a connection between QFI and different quantum speed limits. At the same time, by optimizing a control field acting on the probes, we show how the total information flow is actively manipulated by the control so as to enhance the parameter estimation at a given final evolution time. Finally, under this controlled scenario, a sharp interplay between the dynamics of QFI, non-Markovianity, and entanglement is revealed within different control schemes.
Quantum metrology promises unprecedented precision of parameter estimation, but it is often vulnerable to noise. While significant efforts have been devoted to improving the metrology performance in Markovian environments, practical control schemes specifically designed for non-Markovian noises are much less investigated. Here, we propose two control-enhanced quantum metrology schemes that are suitable for tackling general non-Markovian noises described by noise channels or noise spectra. We conduct experiments to verify the efficacy of these schemes on a nuclear magnetic resonance system. The experimental results involving multiqubit probes show that the parameter estimation precision can be greatly improved, significantly surpassing the standard quantum limit, with our schemes. At present, non-Markovian noises are widely encountered on diverse quantum devices, the proposed schemes are relevant for realistic metrology applications on these platforms. Quantum metrology, a powerful paradigm for surpassing classical measurement precision, has been extensively studied for Markovian noise, while most practical physical processes obey non-Markovian dynamics. In this paper, the authors propose control-enhanced quantum metrology schemes to counteract non-Markovian noise and experimentally verify their efficacy.
Abstract Finding the optimal control is of importance to quantum metrology under a noisy environment. In this paper, we tackle the problem of finding the optimal control to enhance the performance of quantum metrology under an arbitrary non-Markovian bosonic environment. By introducing an equivalent pseudomode model, the non-Markovian dynamic evolution is reduced to a Lindblad master equation, which helps us to calculate the gradient of quantum Fisher information and perform the gradient ascent algorithm to find the optimal control. Our approach is accurate and circumvents the need for the Born–Markovian approximation. As an example, we consider the frequency estimation of a spin with pure dephasing under two types of non-Markovian environments. By maximizing the quantum Fisher information at a fixed evolution time, we obtain the optimal multi-axis control, which results in a notable enhancement in quantum metrology. The advantage of our method lies in its applicability to the arbitrary non-Markovian bosonic environment.
Abstract This tutorial introduces a systematic approach for addressing the key question of quantum metrology: For a generic task of sensing an unknown parameter, what is the ultimate precision given a constrained set of admissible strategies. The approach outputs the maximal attainable precision (in terms of the maximum of quantum Fisher information) as a semidefinite program and optimal strategies as feasible solutions thereof. Remarkably, the approach can identify the optimal precision for different sets of strategies, including parallel, sequential, quantum SWITCH‐enhanced, causally superposed, and generic indefinite‐causal‐order strategies. The tutorial consists of a pedagogic introduction to the background and mathematical tools of optimal quantum metrology, a detailed derivation of the main approach, and various concrete examples. As shown in the tutorial, applications of the approach include, but are not limited to, strict hierarchy of strategies in noisy quantum metrology, memory effect in non‐Markovian metrology, and designing optimal strategies. Compared with traditional approaches, the approach here yields the exact value of the optimal precision, offering more accurate criteria for experiments and practical applications. It also allows for the comparison between conventional strategies and the recently discovered causally‐indefinite strategies, serving as a powerful tool for exploring this new area of quantum metrology.
We derive ultimate precision bounds for estimating parameters encoded in \emph{time-dependent} Hamiltonians in the presence of general Markovian noise, allowing for arbitrary adaptive protocols with fast controls and noiseless ancillas. Extending the minimization-over-purifications framework to time-varying continuous channels, we obtain a differential upper bound on the achievable quantum Fisher information (QFI) that can be evaluated at all times via semidefinite programming. For parameter-independent noise, we prove a universal long-time scaling law: if the coherent (noiseless) dynamics yields Qcoh(T)∼T2k, then under Markovian noise the QFI scales at most as Q(T)∼T2k in the DHNLS regime, whereas in the DHLS regime it is fundamentally limited to Q(T)∼T2k−1. We illustrate these behaviors on paradigmatic driven-qubit sensors, exhibiting T4 and T3 scalings under dephasing and spontaneous emission, respectively. Finally, we provide explicit continuous exact and approximate quantum error correction constructions -- supplemented by spin-squeezed probes -- that asymptotically saturate the bounds, establishing their tightness.
Nature imposes fundamental limits on how precisely we can probe the physical world. Quantum metrology is the study of achieving higher precision and accuracy in estimating the physical parameters by harnessing quantum resources. It is considered one of the most promising quantum technologies, offering significant advantages over classical ones in both near‑term and long‑term applications. However, existing theoretical research in quantum metrology often falls short of providing a unified and rigorous understanding of the ultimate precision under realistic experimental limitations on available quantum resources. In this thesis, we conduct a systematic investigation of the optimal precision limits in quantum metrology and identify the metrological strategies that achieve optimality under specified resource constraints. We primarily focus on the single-parameter estimation of quantum processes, a cornerstone task in quantum metrology. We first establish a general framework of strictly optimal quantum metrology using semidefinite programming within the formalism of higher-order quantum operations. This framework reveals a strict hierarchy for the performance of different families of strategies---parallel, sequential, and indefinite-causal-order ones---each subject to specific causal constraints. Our results rigorously demonstrate a quantum metrological advantage of indefinite causal order in finite-dimensional systems, which has recently aroused rapidly growing interest. In realistic scenarios, a fully optimized quantum metrology protocol may be experimentally demanding due to the complexity of state preparation and control. Tailored to practical constraints on the allowed ancilla and control operations, we propose a highly efficient tensor network algorithm to optimize the probe state and a long sequence of control for quantum metrology. When the number of control steps tends to infinity, we develop an asymptotic theory of quantum metrology for achieving the ultimate precision limit---Heisenberg limit---without ancilla. This contrasts with the traditional approach using quantum error correction for metrology that typically requires noiseless and controllable ancilla. Our results pave the way for exploiting the full potential of quantum resources in metrology. In the near term, our methods enable high-precision estimation with limited interaction with the unknown process using experimentally feasible control techniques. In the long term, they lay the foundation for scalable and fault-tolerant quantum metrology.