Nature imposes fundamental limits on how precisely we can probe the physical world. Quantum metrology is the study of achieving higher precision and accuracy in estimating the physical parameters by harnessing quantum resources. It is considered one of the most promising quantum technologies, offering significant advantages over classical ones in both near‑term and long‑term applications. However, existing theoretical research in quantum metrology often falls short of providing a unified and rigorous understanding of the ultimate precision under realistic experimental limitations on available quantum resources. In this thesis, we conduct a systematic investigation of the optimal precision limits in quantum metrology and identify the metrological strategies that achieve optimality under specified resource constraints. We primarily focus on the single-parameter estimation of quantum processes, a cornerstone task in quantum metrology. We first establish a general framework of strictly optimal quantum metrology using semidefinite programming within the formalism of higher-order quantum operations. This framework reveals a strict hierarchy for the performance of different families of strategies---parallel, sequential, and indefinite-causal-order ones---each subject to specific causal constraints. Our results rigorously demonstrate a quantum metrological advantage of indefinite causal order in finite-dimensional systems, which has recently aroused rapidly growing interest. In realistic scenarios, a fully optimized quantum metrology protocol may be experimentally demanding due to the complexity of state preparation and control. Tailored to practical constraints on the allowed ancilla and control operations, we propose a highly efficient tensor network algorithm to optimize the probe state and a long sequence of control for quantum metrology. When the number of control steps tends to infinity, we develop an asymptotic theory of quantum metrology for achieving the ultimate precision limit---Heisenberg limit---without ancilla. This contrasts with the traditional approach using quantum error correction for metrology that typically requires noiseless and controllable ancilla. Our results pave the way for exploiting the full potential of quantum resources in metrology. In the near term, our methods enable high-precision estimation with limited interaction with the unknown process using experimentally feasible control techniques. In the long term, they lay the foundation for scalable and fault-tolerant quantum metrology.
Nature imposes fundamental limits on how precisely we can probe the physical world. Quantum metrology is the study of achieving higher precision and accuracy in estimating the physical parameters by harnessing quantum resources. It is considered one of the most promising quantum technologies, offering significant advantages over classical ones in both near‑term and long‑term applications. However, existing theoretical research in quantum metrology often falls short of providing a unified and rigorous understanding of the ultimate precision under realistic experimental limitations on available quantum resources. In this thesis, we conduct a systematic investigation of the optimal precision limits in quantum metrology and identify the metrological strategies that achieve optimality under specified resource constraints. We primarily focus on the single-parameter estimation of quantum processes, a cornerstone task in quantum metrology. We first establish a general framework of strictly optimal quantum metrology using semidefinite programming within the formalism of higher-order quantum operations. This framework reveals a strict hierarchy for the performance of different families of strategies---parallel, sequential, and indefinite-causal-order ones---each subject to specific causal constraints. Our results rigorously demonstrate a quantum metrological advantage of indefinite causal order in finite-dimensional systems, which has recently aroused rapidly growing interest. In realistic scenarios, a fully optimized quantum metrology protocol may be experimentally demanding due to the complexity of state preparation and control. Tailored to practical constraints on the allowed ancilla and control operations, we propose a highly efficient tensor network algorithm to optimize the probe state and a long sequence of control for quantum metrology. When the number of control steps tends to infinity, we develop an asymptotic theory of quantum metrology for achieving the ultimate precision limit---Heisenberg limit---without ancilla. This contrasts with the traditional approach using quantum error correction for metrology that typically requires noiseless and controllable ancilla. Our results pave the way for exploiting the full potential of quantum resources in metrology. In the near term, our methods enable high-precision estimation with limited interaction with the unknown process using experimentally feasible control techniques. In the long term, they lay the foundation for scalable and fault-tolerant quantum metrology.
Estimating multiple unknown parameters simultaneously is essential for practical quantum sensing. However, it faces a fundamental challenge: the optimal strategy for estimating one parameter is often incompatible with that for another, making it impossible to simultaneously achieve the ultimate precision limits for all parameters. Here we develop a general and efficient computational framework that jointly optimizes probe states, control operations, and measurements across different strategy families, including parallel, sequential, and those with indefinite causal order. Our approach provides exact semidefinite-program formulations for several precision bounds, including the Holevo, Nagaoka-Hayashi, and quantum Cramér-Rao bounds. We demonstrate the capabilities of the framework in multiparameter magnetometry and frequency estimation, identifying optimal protocols within each class and revealing a strict hierarchy among the achievable performances of different classes in the multiparameter regime. The framework also directly incorporates resource constraints, such as energy budgets, enabling systematic investigation of experimentally realistic sensing scenarios. Furthermore, we develop a finite-memory optimization method for sequential strategies with restricted ancillary-memory dimension. By decomposing the protocol into initial probe preparation and intermediate control operations, this method provides a practical route to designing resource-constrained sequential sensing schemes. Our work establishes a versatile computational tool for determining fundamental precision limits and designing optimal quantum-sensing protocols in complex multiparameter settings.
Quantum metrology with indefinite causal order (ICO) has attracted intense interest due to its potential to surpass the limitations of conventional fixed-order strategies. A key open question is whether ICO can fundamentally enhance asymptotic precision scaling. In this work, we bridge this gap for the estimation of a single parameter encoded in N identical uses of a finite-dimensional quantum channel. We first establish a universal Heisenberg-scaling upper bound for the full general ICO process-matrix class and show that for unitary channels its optimal quantum Fisher information (QFI) coincides exactly with that of parallel strategies. For noisy channels, a structurally refined bound shows that channels restricted to the standard quantum limit (SQL) under parallel strategies remain SQL-limited under general ICO strategies. Most significantly, an asymptotically tight (AT) bound is derived to close the remaining possibility of an asymptotic ICO advantage by showing that general ICO and optimal parallel strategies have exactly the same leading QFI coefficient in both the SQL and Heisenberg regimes. For the operationally motivated class of quantum circuits with quantum control of causal order, we further obtain an iterative constraint on finite-query precision whose asymptotic limit agrees with that of the AT bound. Our results clarify the ultimate role of indefinite causality as a metrological resource for quantum channel estimation.
The traditional framework of quantum metrology commonly assumes unlimited access to resources, overlooking resource constraints in realistic scenarios. As such, the optimal strategies therein can be infeasible in practice. Here, we investigate quantum metrology where the total energy consumption of the probe state preparation, intermediate control operations, and the final measurement is subject to a constraint. We establish a comprehensive theoretical framework for characterizing energy-constrained multistep quantum processes, based on which we develop a general optimization method for energy-constrained quantum metrology that determines both the optimal precision and the corresponding strategy. Using the method, we determine the ultimate precision limit of energy-constrained phase estimation and identify a novel advantage of quantum superpositions of causal orders in enhancing the energy efficiency of adaptive quantum estimation.
One of the main quests in quantum metrology is to attain the ultimate precision limit with given resources, where the resources are not only of the number of queries, but more importantly of the allowed strategies. With the same number of queries, the restrictions on the strategies constrain the achievable precision. In this Letter, we establish a systematic framework to identify the ultimate precision limit of different families of strategies, including the parallel, the sequential, and the indefinite-causal-order strategies, and provide an efficient algorithm that determines an optimal strategy within the family of strategies under consideration. With our framework, we show there exists a strict hierarchy of the precision limits for different families of strategies.
Precise estimation of physical parameters underpins both scientific discovery and technological development. A central goal of quantum metrology and sensing is to exploit quantum resources like entanglement to devise optimal strategies for estimating physical parameters as precisely as possible. While substantial progress has been made in single-parameter quantum metrology, the multiparameter scenario remains significantly more challenging due to the issue of parameter incompatibility. In this work, we present a unified and computable approach for the simultaneous estimation of multiple parameters that attains the ultimate precision permitted by quantum mechanics. The core of our approach is to integrate the quantum tester formalism into the recently proposed tight Cramér-Rao type bound. This formulation enables us to figure out the highest achievable precision via upper and lower bounds that are computable via semidefinite programs. More importantly, within this formulation, diverse quantum resources, including entanglement, coherence, quantum control, and indefinite causal order, are treated on equal footing and systematically optimized for the purpose of achieving the ultimate precision in multiparameter estimation. As a result, our approach is applicable to various metrological strategies both in the presence and absence of noise. To demonstrate its utility, we revisit three-dimensional magnetic-field estimation, uncovering the strengths and limitations of existing analytical results and further establishing a strict hierarchy among different types of strategies.
Abstract This tutorial introduces a systematic approach for addressing the key question of quantum metrology: For a generic task of sensing an unknown parameter, what is the ultimate precision given a constrained set of admissible strategies. The approach outputs the maximal attainable precision (in terms of the maximum of quantum Fisher information) as a semidefinite program and optimal strategies as feasible solutions thereof. Remarkably, the approach can identify the optimal precision for different sets of strategies, including parallel, sequential, quantum SWITCH‐enhanced, causally superposed, and generic indefinite‐causal‐order strategies. The tutorial consists of a pedagogic introduction to the background and mathematical tools of optimal quantum metrology, a detailed derivation of the main approach, and various concrete examples. As shown in the tutorial, applications of the approach include, but are not limited to, strict hierarchy of strategies in noisy quantum metrology, memory effect in non‐Markovian metrology, and designing optimal strategies. Compared with traditional approaches, the approach here yields the exact value of the optimal precision, offering more accurate criteria for experiments and practical applications. It also allows for the comparison between conventional strategies and the recently discovered causally‐indefinite strategies, serving as a powerful tool for exploring this new area of quantum metrology.