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arXiv:2011.05699 · Physical review. E

Quantumness and thermodynamic uncertainty relation of the finite-time Otto cycle

Sangyun Lee, Meesoon Ha, Hawoong Jeong

Published Feb 22, 2021• 18 citations
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Abstract

To reveal the role of the quantumness in the Otto cycle and to discuss the validity of the thermodynamic uncertainty relation (TUR) in the cycle, we study the quantum Otto cycle and its classical counterpart. In particular, we calculate exactly the mean values and relative error of thermodynamic quantities. In the quasistatic limit, quantumness reduces the productivity and precision of the Otto cycle compared to that in the absence of quantumness, whereas in the finite-time mode, it can increase the cycle's productivity and precision. Interestingly, as the strength (heat conductance) between the system and the bath increases, the precision of the quantum Otto cycle overtakes that of the classical one. Testing the conventional TUR of the Otto cycle, in the region where the entropy production is large enough, we find a tighter bound than that of the conventional TUR. However, in the finite-time mode, both quantum and classical Otto cycles violate the conventional TUR in the region where the entropy production is small. This implies that another modified TUR is required to cover the finite-time Otto cycle. Finally, we discuss the possible origin of this violation in terms of the uncertainty products of the thermodynamic quantities and the relative error near resonance conditions.

DOI
10.1103/physreve.103.022136

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To reveal the role of the quantumness in the Otto cycle and to discuss the validity of the thermodynamic uncertainty relation (TUR) in the cycle, we study the quantum Otto cycle and its classical counterpart. In particular, we calculate exactly the mean values and relative error of thermodynamic quantities. In the quasistatic limit, quantumness reduces the productivity and precision of the Otto cycle compared to that in the absence of quantumness, whereas in the finite-time mode, it can increase the cycle's productivity and precision. Interestingly, as the strength (heat conductance) between the system and the bath increases, the precision of the quantum Otto cycle overtakes that of the classical one. Testing the conventional TUR of the Otto cycle, in the region where the entropy production is large enough, we find a tighter bound than that of the conventional TUR. However, in the finite-time mode, both quantum and classical Otto cycles violate the conventional TUR in the region where the entropy production is small. This implies that another modified TUR is required to cover the finite-time Otto cycle. Finally, we discuss the possible origin of this violation in terms of the uncertainty products of the thermodynamic quantities and the relative error near resonance conditions.
In order to reveal the quantumness of the Otto cycle and discuss the validity of the thermodynamic uncertainty relation (TUR) in the cycle, we study the quantum Otto cycle and its classical counterpart. In particular, we calculate exactly the mean values and fluctuations of numerous thermodynamic quantities. In the quasistatic limit, quantumness reduces the productivity and reliability of the Otto cycle compared to that in the absence of quantumness, while in the finite-time limit, it can increase the cycle's productivity and reliability. Interestingly, as the strength (heat conductance) between the system and the bath increases, the reliability of the quantum Otto cycle overtakes that of the classical one. In testing the conventional TUR, in the region where the entropy production is large enough, we find a tighter bound than that of the conventional TUR, and also that the TUR of the Otto cycle in the quasistatic limit is still valid. However, in the finite-time mode, both quantum and classical Otto cycles violate the conventional TUR. This implies that another modified TUR is required to cover the finite-time Otto cycle. Finally, we discuss the possible origin of this violation in terms of the uncertainty products of the thermodynamic quantities and the relative fluctuations near resonance conditions.
The thermodynamic uncertainty relation (TUR) is a fundamental principle in nonequilibrium thermodynamics that relates entropy production to fluctuations in a system, establishing a trade-off between the precision of an observable and the thermodynamic cost. Investigating TUR violations challenges classical thermodynamic limits, offering the potential for improved precision-entropy trade-offs, which is crucial for enhancing performance and optimization in quantum technologies. In this work, we investigate the thermodynamic uncertainty relation within a quantum collisional model, which offers the advantage of discretizing interactions into successive collisions with auxiliaries, allowing for precise tracking of dynamics and the incorporation of memory effects and non-Markovian behavior. We consider three types of dynamics in the collisional model: one is Markovian evolution, achieved by taking the continuous-time limit and imposing the stability condition, while the other two are non-Markovian dynamics—one arising from increasing the collision time between the system and the auxiliaries, and the other from incorporating interactions between the auxiliaries. For the Markovian dynamics, we examine the classical and quantum TUR bounds in the nonequilibrium steady-state regime, and also the finite-time TUR bound. We identify two distinct regimes of classical TUR violation: in some cases, the maximum violation occurs in the steady state, while in others, it is necessarily transient—appearing only at early times and vanishing with further evolution. For the two non-Markovian approaches, we find that both the degree and type of non-Markovianity crucially affect TUR violations. The second approach shows more pronounced violations during transient times, while the first approach has much stronger violations in the steady-state regime for a certain parameter window.
The thermodynamic uncertainty relation (TUR) imposes a fundamental constraint between current fluctuations and entropy production, providing a refined formulation of the second law for micro- and nanoscale systems. Quantum violations of the classical TUR reveal genuinely quantum thermodynamic effects, which are essential for improving performance and enabling optimization in quantum technologies. In this work, we analyze the TUR in a class of paradigmatic quantum thermal-machine models whose operation is enabled by coherent coupling between two energy levels forming a virtual qubit. Steady-state coherences are confined to this virtual-qubit subspace, while in the absence of coherent coupling the system satisfies detailed balance with the thermal reservoirs and supports no steady-state heat currents. We show that the steady-state currents and entropy production can be fully reproduced by an effective classical Markov process, whereas current fluctuations acquire an additional purely quantum correction originating from coherence. As a result, the thermodynamic uncertainty naturally decomposes into a classical (diagonal) contribution and a coherent contribution. The latter becomes negative under resonant conditions and reaches its minimum at the coupling strength that maximizes steady-state coherence. We further identify the conditions for minimizing the thermodynamic uncertainty, and the criteria for surpassing the classical TUR bound in the vicinity of the reversible limit.
In quantum thermodynamics, entropy production is usually defined in terms of the quantum relative entropy between two states. We derive a lower bound for the quantum entropy production in terms of the mean and variance of quantum observables, which we refer to as a thermodynamic uncertainty relation (TUR) for the entropy production. In the absence of coherence between the states, our result reproduces classic TURs in stochastic thermodynamics. For the derivation of the TUR, we introduce a lower bound for a quantum generalization of the χ^{2} divergence between two states and discuss its implications for stochastic and quantum thermodynamics, as well as the limiting case where it reproduces the quantum Cramér-Rao inequality.
We study finite-time quantum Otto cycles whose working medium is a harmonic oscillator undergoing a quantum Brownian motion described by the Caldeira-Leggett model when the oscillator is in contact with heat baths in isochoric processes. The time evolution of the Otto cycle is studied by analytically solving the exact Heisenberg-Langevin equations for the system variables and the interaction energy between the system and the bath. This enables us to investigate non-Markovian strong-coupling effects on the quantum Otto cycle. We obtain cyclic steady states and study the thermodynamic properties of the Otto cycle for various values of the parameters describing the heat baths and the coupling between the system and the bath. We compare our results with those obtained in the Markovian limit, where the time evolution is described by the Lindblad equation. We find that the change in the interaction energy during the isochoric process contributes to both work and heat and plays a crucial role in determining the thermodynamic behavior of the cycle. This is in contrast to the behavior of the state observables of the working medium, which show relatively small change compared to the Markovian counterparts. We find that non-Markovian effects only become significant when we consider thermodynamic fluxes such as work and heat with the system-bath interaction fully taken into account. We also compare our results with the power-efficiency trade-off relation recently proposed for the Markovian quantum Otto engine.
For classic systems, the thermodynamic uncertainty relation (TUR) states that the fluctuations of a current have a lower bound in terms of the entropy production. Some TURs are rooted in information theory, particularly derived from relations between observations (mean and variance) and dissimilarities, such as the Kullback-Leibler divergence, which plays the role of entropy production in stochastic thermodynamics. We generalize this idea for quantum systems, where we find a lower bound for the uncertainty of quantum observables given in terms of the quantum relative entropy. We apply the result to obtain a quantum thermodynamic uncertainty relation in terms of the quantum entropy production, valid for arbitrary dynamics and nonthermal environments.