We construct a class of Hamiltonians that describe the photodetection process from beginning to end. Our Hamiltonians describe the creation of a photon, how the photon travels to an absorber (such as a molecule), how the molecule absorbs the photon, and how the molecule after irreversibly changing its configuration triggers an amplification process---at a wavelength that may be very different from the photon's wavelength---thus producing a macroscopic signal. We use a simple prototype Hamiltonian to describe the single-photon detection process analytically in the Heisenberg picture, which neatly separates desirable from undesirable effects. Extensions to more complicated Hamiltonians are pointed out.
We construct a class of Hamiltonians that describe the photodetection process from beginning to end. Our Hamiltonians describe the creation of a photon, how the photon travels to an absorber (such as a molecule), how the molecule absorbs the photon, and how the molecule after irreversibly changing its configuration triggers an amplification process---at a wavelength that may be very different from the photon's wavelength---thus producing a macroscopic signal. We use a simple prototype Hamiltonian to describe the single-photon detection process analytically in the Heisenberg picture, which neatly separates desirable from undesirable effects. Extensions to more complicated Hamiltonians are pointed out.
Quantum mechanics cements the intimate relationship between the nature of light and its detection. Historically, quantum theories of photodetection have generally fallen into two categories: the first tries to determine what quantum field observable is measured when photoelectrons are detected, laying the theoretical groundwork for photodetection being possible. The second type are phenomenological theories, which take great care to model the details of specific photodetectors. In this dissertation, we fill in the gap between these two models in the modern literature on photodetection by constructing a fully quantum-mechanical and sufficiently realistic model that includes all stages of the photodetection process. We accomplish this within the framework of quantum information theory using the language of positive operator valued measures (POVMs). \n\nA POVM provides the most general description of a quantum measurement. In the context of single-photon detection, the photodetector POVM provides a complete characterization of the single-photon detector (SPD) from which all figures of merit can be calculated. Each element of the POVM is comprised of a weighted sum over single-photon state projectors. To construct SPD POVMs, we identify the states projected onto by a measurement and the associated weights. We first accomplish this for a simple time-dependent system, laying out how to efficiently project onto arbitrary single-photon states. Then, we describe the three stages of a realistic SPD: transmission, amplification, and measurement.\n\nIn the transmission stage of photodetection a photon enters a network of discrete energy levels, its energy propagating through that network and finally exiting into another output continuum of modes, a process entirely described by a single complex function. In the amplification stage of photodetection, a single excitation is amplified into a macroscopic signal via a nonlinear amplification mechanism. In the final stage, an inefficient ``classical'' measurement is made on the macroscopic signal. By combining these three stages we form a chain of inference from the final ``click'' to the input photon and construct a POVM projecting onto the input Hilbert space. Lastly, we discuss limits and tradeoffs that arise at each stage and implications for photodetection applications.\n\nThis dissertation contains previously published and unpublished material.
Single photon detection generally consists of several stages: the photon has to interact with one or more charged particles, its excitation energy will be converted into other forms of energy, and amplification to a macroscopic signal must occur, thus leading to a ``click.'' We focus here on the part of the detection process before amplification (which we have studied in a separate publication). We discuss how networks consisting of coupled discrete quantum states and structured continua (e.g., band gaps) provide generic models for that first part of the detection process. The input to the network is a single continuum (the continuum of single photon states); the output is again a single continuum describing the next irreversible step. The process of a single photon entering the network, its energy propagating through that network, and finally exiting into another output continuum of modes can be described by a single dimensionless complex transmission amplitude, $T(\ensuremath{\omega})$. We discuss how to obtain from $T(\ensuremath{\omega})$ the photodetection efficiency, how to find sets of parameters that maximize this efficiency, as well as expressions for other input-independent quantities such as the frequency-dependent group delay and spectral bandwidth. We then study a variety of networks, discuss how to engineer different transmission functions $T(\ensuremath{\omega})$ amenable to photodetection, and discuss implications for single photon detection technology.
Quantum mechanics cements the intimate relationship between the nature of light and its detection. Historically, quantum theories of photodetection have generally fallen into two categories: the first tries to determine what quantum field observable is measured when photoelectrons are detected, laying the theoretical groundwork for photodetection being possible. The second type are phenomenological theories, which take great care to model the details of specific photodetectors. In this dissertation, we fill in the gap between these two models in the modern literature on photodetection by constructing a fully quantum mechanical and sufficiently realistic model that includes all stages of the photodetection process: transmission, amplification, and a final classical measurement. We accomplish this within the framework of quantum information theory using the language of positive operator valued measures (POVMs). This dissertation contains material previously published in three papers: Propp, Tz. B & van Enk, S. J. (2019). On nonlinear amplification: improved quantum limits for photon counting. Optics Express 27, 16, 23454-23463. Propp, Tz. B & van Enk, S. J. (2019). Quantum networks for single photon detection. Physical Review A, 100, 033836. Propp, Tz. B & van Enk, S. J. (2020). How to project onto an arbitrary single-photon wavepacket. Physical Review A, 102, 053707.
Quantum mechanics does neither give information on details of the emission of a photon from a single atom or molecule nor on the physical size of a photon. Experiments to get answers to such questions have, at least in principle, become possible only recently with the advent of single molecule photon sources. If diffraction of light at wavelength sized apertures is already a property of individual photons, some clear statements on emisission can be made: The energy of an individual photon, which at the start of the process is concentrated in an Angstrom sized atom or molecule, is diluted to micrometer dimensions, i.e. by many orders of magnitude. Since single photons can still be detected at least 18 m after their emission, the dilution must be terminated at some point. A photon model presented in an accompanying paper suggests a size for a photon of λ / 2π and explains what does stop and revert the expansion process, thus starting an oscillation.
In optical quantum information processing, two of the most basic elements are the sources of quantum mechanical states of light, and the devices that can detect these states. In this chapter, we narrow this down to photon sources and photodetectors. We will describe first how detectors work, starting from abstract ideal detectors, via a complete description of realistic detectors in terms of POVMS, to a brief overview of current photodetectors. Subsequently, we will define what is a single-photon source, and how we can determine experimentally whether a source produces single photons or something else. Having laid down the ground rules, we will survey some of the most popular ways photons are produced in the laboratory. Finally, we take a look at the production of entangled photon sources and quantum non-demolition measurements of photons. A mathematical model of photodetectors Photodetectors are devices that produce a macroscopic signal when triggered by one or more photons. In the ideal situation, every photon that hits the detector contributes to the macroscopic signal, and there are no ‘ghost’ signals, or so-called dark counts. In this situation we can define two types of detector, namely the ‘photon-number detector’, and ‘detectors without number resolution’. First, the photon number detector is a (largely hypothetical) device that tells us how many photons there are in a given optical mode that is properly localized in space and time. This property is called ‘photon-number resolution’.
In semiclassical theory, light is a classical electromagnetic wave and the fundamental source of photodetection noise is the shot effect arising from the discreteness of the electron charge. In quantum theory, light is a quantum-mechanical entity and the fundamental source of photodetection noise comes from measuring the photon-flux operator. The Glauber coherent states are Gaussian quantum states which represent classical electromagnetic radiation. Quantum photodetection of these states yields statistics that are indistinguishable from the corresponding Poisson point-process results of semiclassical photodetection. Optical parametric interactions, however, can be used to produce other Gaussian quantum states, states whose photodetection behavior cannot be characterized semiclassically. A unified analytical framework is presented for Gaussian-state photodetection that includes the full panoply of nonclassical effects that have been produced via parametric interactions.