The confinement of atoms at the nanoscale is of interest for a diverse range of applications, from spatially selective sensing on the submicrometer scale to emerging quantum technologies. This study describes a bespoke method for manufacturing robust vapor cells with arbitrary nanoscale-confinement geometries. The device is designed with versatile, high-NA optical access. Spectroscopy of Rb atoms in purpose-built cells yields important insight into the diffusion and spatial distribution of a thermal vapor confined to a nanochannel. This work offers routes toward engineering solutions for localized control of atom numbers for scalable quantum optical experiments.
The confinement of atoms at the nanoscale is of interest for a diverse range of applications, from spatially selective sensing on the submicrometer scale to emerging quantum technologies. This study describes a bespoke method for manufacturing robust vapor cells with arbitrary nanoscale-confinement geometries. The device is designed with versatile, high-NA optical access. Spectroscopy of Rb atoms in purpose-built cells yields important insight into the diffusion and spatial distribution of a thermal vapor confined to a nanochannel. This work offers routes toward engineering solutions for localized control of atom numbers for scalable quantum optical experiments.
Atom-light interactions in nano-scale systems hold great promise for novel technologies based on integrated emitters and optical modes. We present the design architecture, construction method, and characterization of an all-glass alkali-metal vapor cell with nanometer-scale internal structure. Our cell has a glue-free design which allows versatile optical access, in particular with high numerical aperture optics. By performing spectroscopy in different illumination and detection schemes, we investigate atomic densities and velocity distributions in various nanoscopic landscapes. We apply a two-photon excitation scheme to atoms confined in one dimension within our cells, achieving a resonance line-width of 32 MHz in a counter-propagating geometry, and 57.5 MHz in a co-propagating geometry. Both of these are considerably narrower than the Doppler width (GHz), and are limited by transit time broadening and velocity selection. We also demonstrate sub-Doppler line-widths for atoms confined in two dimensions to micron-sized channels. Furthermore, we illustrate control over vapor density within our cells through nano-scale confinement alone, which could offer a scalable route towards room-temperature devices with single atoms within an interaction volume. Our design offers a robust platform for miniaturized devices that could easily be combined with integrated photonic circuits.
We present the design, fabrication, and operation of a new genera-tion of thermal alkali vapour nano-cells. The nano-cells include in-ternal structures with length scales 200−2000 nm created by laserlithography and reactive ion etching. The assembly process adoptsoptical contact bonding and glassblowing, avoiding the requirementfor any bonding agents or adhesives. We demonstrate a novel methodfor characterising the size of the internal vapour nano-channels. Thedesign allows for greater optical access and compatibility with highnumerical aperture (NA=0.7) optics; we demonstrate this with totalinternal reflection fluorescence spectroscopy and high resolution ima-ging of the nano-channels. Additionally, we report for the first time onthe photon statistics of light from a thin atomic ensemble. Finally, wediscuss the diffusion of atoms inside confined geometries with a num-ber of detection methods, and investigate options for controlling andmanipulating the atomic density and its diffusion. In total, we presentour new nano-cell design as a significant advancement of the field andpropose its use in scalable atomic and quantum optics applications andtechnologies.
We combined experimental and theoretical investigations of an effective two-level atomic system operating in the near-infrared telecom wavelength regime, realized using hot rubidium vapor confined within a sub-micron-thick cell. In this strongly confined geometry, atomic coherence is profoundly influenced by wall-induced relaxation arising from frequent atom-surface collisions. By analyzing both absorption and fluorescence spectra, we demonstrate that the optical response is dominated by a closed cycling transition, which effectively isolates the atomic dynamics to a two-level configuration despite the presence of multiple hyperfine states. This confinement-induced selection suppresses optical pumping into uncoupled states and enables robust, controllable light-matter interaction at telecom wavelengths within a miniature atomic platform. Our results establish a practical route to realizing near-infrared atomic two-level systems in compact vapor-cell devices, opening new opportunities for integrated quantum photonic technologies, including on-chip quantum memories, telecom-band frequency references, and scalable quantum information processing.
Integrating alkali atomic vapors with nanophotonic devices offers a scalable route to quantum technologies that leverage strong atom-photon interactions. While there have been many approaches to such integration, the general reliance on traditional glass vapor cells, distilled alkali metals, and epoxy sealing limits reproducibility and scalability. Moreover, mitigating adverse Rb-photonics interactions is essential, particularly as devices become more compact and the alkali source lies in close proximity to the photonic elements. Here, we demonstrate the successful operation of compact and fully integrated devices that combine silicon nitride photonic integrated circuits (PICs) with microfabricated borosilicate vapor cells and pill-type rubidium (Rb) dispensers through hermetic seals via anodic bonding. We show how successful operation hinges on optically activating the dispenser in a low-power pulsed mode, releasing controlled amounts of Rb vapor on demand while mitigating photonic degradation. Simultaneously, a counter-propagating desorption laser completely suppresses Rb-induced losses and enables waveguide-based atomic vapor spectroscopy. Using this approach, we demonstrate repeatable control of vapor density by tuning activation pulse length, duty cycle, and device temperature. These results establish a compact, manufacturable, and scalable vapor-PIC device, and set the stage for future demonstrations in cavity quantum electrodynamics, quantum nonlinear optics, and chip-scale atomic sensors.
Integrating alkali atomic vapors with nanophotonic devices offers a scalable route to quantum technologies that leverage strong atom–photon interactions. While there have been many approaches to such integration, the general reliance on traditional glass vapor cells, distilled alkali metals, and epoxy sealing limits reproducibility and scalability. Moreover, mitigating adverse Rb-photonics interactions is essential, particularly as devices become more compact and the alkali source lies in close proximity to the photonic elements. Here, we demonstrate the successful operation of compact and fully integrated devices that combine silicon nitride photonic integrated circuits (PICs) with microfabricated borosilicate vapor cells and pill-type rubidium (Rb) dispensers through hermetic seals via anodic bonding. We show how successful operation hinges on optically activating the dispenser in a low-power pulsed mode, releasing controlled amounts of Rb vapor on demand while mitigating photonic degradation. Simultaneously, a counter-propagating desorption laser completely suppresses Rb-induced losses and enables waveguide-based atomic vapor spectroscopy. Using this approach, we demonstrate repeatable control of vapor density by tuning activation pulse length, duty cycle, and device temperature. These results establish a compact, manufacturable, and scalable vapor–PIC device, and set the stage for future demonstrations in cavity quantum electrodynamics, quantum nonlinear optics, and chip-scale atomic sensors.
Alkali vapors confined in nano-scale cells are promising tools for future integrated atom-based sensor. In this thesis, we investigate the interaction between light and an ensemble of atoms confined in a nano-geometry. We focus on the different processes that can modify the optical response of the atomic ensemble and possibly affect the sensitivity of a sensor based on that technology. First, we study the non-local response of atoms to a light excitation due the atomic motion in thermal vapors. When the distance over which the atoms relaxes is larger than the size of the cell, the optical response depends on the size of the system. We have observed that for transmission spectroscopy, this leads to a periodic modification of the optical response with a period equal to the wavelength of the optical transition. Subsequently we showed that when the density of atom increases, the atomic response becomes local again. In this dense regime, the resonant dipole-dipole interaction in a sub-wavelength geometry leads to collective frequency shifts of the spectral lines. We demonstrate that these shifts were induced by the cavity formed by the cell walls, hence clarifying a long-standing issue. We developed a model to extract the density shifts deconvolved from the cavity effects. Close to a surface, the optical response is also affected by the van der Waals atom-surface interaction. We introduced a new method to extract precisely the strength of this interaction. We also developed a new generation of super-polished glass nano-cells and we presented promising spectroscopic signals. Finally, using these cells, we have compared transmission and off-axis spectroscopic techniques.