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arXiv:1911.06630

Quantum theory and functional analysis

Klaas Landsman

Published Nov 15, 2019• 8 citations
arXivHTMLPDF

Abstract

Quantum theory and functional analysis were created and put into essentially their final form during similar periods ending around 1930. Each was also a key outcome of the major revolutions that both physics and mathematics as a whole underwent at the time. This paper studies their interaction in this light, emphasizing the leading roles played by Hilbert in preparing the ground and by von Neumann in bringing them together during the crucial year of 1927, when he gave the modern, abstract definition of a Hilbert space and applied this concept to quantum mechanics (consolidated in his famous monograph from 1932). Subsequently, I give a very brief overview of three areas of functional analysis that have had fruitful interactions with quantum theory since 1932, namely unbounded operators, operator algebras, and distributions. The paper closes with some musings about the role of functional analysis in actual physics.

DOI
10.48550/arxiv.1911.06630

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Quantum theory and functional analysis were created and put into essentially their final form during similar periods ending around 1930. Each was also a key outcome of the major revolutions that both physics and mathematics as a whole underwent at the time. This paper studies their interaction in this light, emphasizing the leading roles played by Hilbert in preparing the ground and by von Neumann in bringing them together during the crucial year of 1927, when he gave the modern, abstract definition of a Hilbert space and applied this concept to quantum mechanics (consolidated in his famous monograph from 1932). Subsequently, I give a very brief overview of three areas of functional analysis that have had fruitful interactions with quantum theory since 1932, namely unbounded operators, operator algebras, and distributions. The paper closes with some musings about the role of functional analysis in actual physics.
The aim of this thesis is to present a reasonable account of some of the applications that functional analysis, or more specifically operator theory, has in the theory of quantum scattering. We begin by introducing the physical scattering experiment as well as establishing the standard framework for discussing quantum theory, that of a Hilbert space. This leads to a discussion of the properties of operators acting in a Hilbert space and the role played by unbounded selfadjoint operators in quantum physics. We also spend some time discussing the position, momentum and energy operators which are of most relevance here. This in turn leads logically to the problem of formulating the scattering problem mathematically using these operators. The stationary equations of scattering theory are also rigorously derived and their suitability for two-body scattering problems is proven. We show that this analysis does not extend to three-body scattering problems, and introduce the Faddeev formulation for three-body systems to supplement the theory. This thesis concludes with a brief overview of how our scattering equations can be modified to take into account effects such as particle spin and identical particles, before discussing an example of a three-body scattering problem (incorporating these features) and deriving a mathematically satisfactory set of equations which are amenable to numerical solution.
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In this chapter, we present the basic principles of the quantum mechanics of particle systems from a modern mathematical perspective. The proper study of quantum mechanics brings together several interesting mathematical ideas, ranging from group representations to the spectral theory of unbounded self-adjoint operators in Hilbert spaces and the theory of C * algebras. The facts from analysis of operators in Hilbert spaces and C * algebras needed in this chapter are presented in detail in the appendices at the end of the book. More on the mathematical foundations of quantum mechanics can be found in the books by L. Fadeev and O. Yakubovskii [FY], G. Mackey [M], and F. Strocchi [Str] listed in the bibliography. The birth of quantum theory The origins of quantum theory can be traced back to M. Planck's study, published in 1900, of so-called black-body radiation. It is well known that matter glows when heated, going from red-hot to white-hot as the temperature rises. The color (or frequency of radiation) of the radiating body is independent of its surface, and for a black body it is found to be a function of temperature alone. The behavior of the radiation energy as a function of temperature seemed quite different at high temperatures and low temperatures. In a desperate attempt to fit these different behaviors into a single law, Planck introduced the hypothesis that energy was not continuous, but came in discrete packets or quanta . At the beginning of the twentieth century, a number of experiments pointed to a breakdown of the laws of classical mechanics at very small (subatomic) scales.
Quantum mechanics and the theory of operators on Hilbert space have been deeply linked since their beginnings in the early twentieth century. States of a quantum system correspond to certain elements of the configuration space and observables correspond to certain operators on the space. This book is a brief, but self-contained, introduction to the mathematical methods of quantum mechanics, with a view towards applications to Schrodinger operators. Part 1 of the book is a concise introduction to the spectral theory of unbounded operators. Only those topics that will be needed for later applications are covered. The spectral theorem is a central topic in this approach and is introduced at an early stage. Part 2 starts with the free Schrodinger equation and computes the free resolvent and time evolution. Position, momentum, and angular momentum are discussed via algebraic methods. Various mathematical methods are developed, which are then used to compute the spectrum of the hydrogen atom. Further topics include the nondegeneracy of the ground state, spectra of atoms, and scattering theory. This book serves as a self-contained introduction to spectral theory of unbounded operators in Hilbert space with full proofs and minimal prerequisites: Only a solid knowledge of advanced calculus and a one-semester introduction to complex analysis are required. In particular, no functional analysis and no Lebesgue integration theory are assumed. It develops the mathematical tools necessary to prove some key results in nonrelativistic quantum mechanics. Mathematical Methods in Quantum Mechanics is intended for beginning graduate students in both mathematics and physics and provides a solid foundation for reading more advanced books and current research literature. This new edition has additions and improvements throughout the book to make the presentation more student friendly.
In Mathematical Foundations of Quantum Mechanics (1932) von Neumann made separability of Hilbert space an axiom. Subsequent work in mathematics (some of it by von Neumann himself) investigated non-separable Hilbert spaces, and mathematical physicists have sometimes made use of them. This note discusses some of the problems that arise in trying to treat quantum systems with non-separable spaces. Some of the problems are "merely technical" but others point to interesting foundations issues for quantum theory, both in its abstract mathematical form and its applications to physical systems. Nothing new or original is attempted here. Rather this note aims to bring into focus some issues that have for too long remained on the edge of consciousness for philosophers of physics.