Frustrated one-dimensional (1D) magnets are known as ideal playgrounds for new exotic quantum phenomena to emerge. We consider an elementary frustrated 1D system: the spin- \frac{1}{2} 1 2 ferromagnetic ( J_1 J 1 ) Heisenberg chain with next-nearest-neighbor antiferromagnetic ( J_2 J 2 ) interactions. On the basis of density-matrix renormalization group calculations we show the existence of a finite spin gap at J_2/|J_1|>1/4 J 2 / | J 1 | > 1 / 4 and we find the ground state in this region to be a valence bond solid (VBS) with spin-singlet dimerization between third-neighbor sites. The VBS is the consequence of spontaneous symmetry breaking through order by disorder. Quite interestingly, this VBS state has a Affleck-Kennedy-Lieb-Tasaki-type topological order. This is the first example of a frustrated spin chain in which quantum fluctuations induce gapped topological order.
The phase diagram of an antiferromagnetic ladder with frustrating next-nearest-neighbor couplings along the legs is determined using numerical methods (exact diagonalization and density-matrix renormalization group) supplemented by strong-coupling and mean-field analysis. Interestingly, this model displays remarkable features, bridging the physics of the
J1-
J2 chain and of the unfrustrated ladder. The phase diagram as a function of the transverse coupling ${J}_{\ensuremath{\perp}}$ and the frustration
J2 exhibits an Ising transition between a columnar phase of dimers and the usual rung-singlet phase of two-leg ladders. The transition is driven by resonating valence bond fluctuations in the singlet sector while the triplet spin gap remains finite across the transition. In addition, frustration brings incommensurability in the real-space spin-correlation functions, the onset of which evolves smoothly from the
J1-
J2 chain value to zero in the large-${J}_{\ensuremath{\perp}}$ limit. The onset of incommensurability in the spin structure factor and in the dispersion relation is also analyzed. The physics of the frustrated rung-singlet phase is well understood using perturbative expansions and mean-field theories in the large-${J}_{\ensuremath{\perp}}$ limit. Last, we discuss the effect of the nontrivial magnon dispersion relation on the thermodynamical properties of the system. The relation of this model and its physics to experimental observations on compounds that are currently investigated, such as BiCu
2PO
6, is eventually addressed.
The frustrated ladder with alternate ferromagnetic(F) exchange
−JF and AF exchange
JA to first neighbors and F exchange
−JL to second neighbors is studied by exact diagonalization (ED) and density matrix renormalization group (DMRG) calculations in systems of
2N spins-1/2 with periodic boundary conditions. The ground state is a singlet
(S=0) and the singlet-triplet gap
εT is finite for the exchanges considered. Spin-1/2 string correlation functions
g1(N) and
g2(N) are defined for an even number
N of consecutive spins in systems with two spins per unit cell; the ladder has string order
g2(∞)>0 and
g1(∞)=0. The minimum
N∗ of
g2(N) is related to the range of ground-state spin correlations. Convergence to
g2(∞) is from below, and
g1(N) decreases exponentially for
N≥N∗. Singlet valence bond (VB) diagrams account for the size dependencies. The frustrated ladder at special values of
JF,
JL and
JA reduces to well-known models such as the spin-1 Heisenberg antiferromagnet and the
J1−J2 model, among others. Numerical analysis of ladders matches previous results for spin-1 gaps or string correlation functions and extends them to spin-1/2 systems. The nondegenerate singlet ground state of ladder is a bond-order wave, a Kekulé VB diagrams at
JL=JF/2≤JA, that is reversed on interchanging
−JF and
JA. Inversion symmetry is spontaneously broken in the dimer phase of the
J1−J2 model where the Kekulé diagrams are the doubly degenerate ground states at
J2/J1=1/2.
We investigate the quantum spin-1/2 zigzag chain with frustrated ${J}_{1}\ensuremath{-}{J}_{2}$ Heisenberg interactions, incorporating additional off-diagonal exchange interactions known as the $\mathrm{\ensuremath{\Gamma}}$ term, both with and without an applied magnetic field. Based on the density-matrix renormalization group calculation, we map out the ground-state phase diagram that shows a variety of magnetic and nonmagnetic phases including multicritical points and several exactly solvable points. Upon introducing a finite $\mathrm{\ensuremath{\Gamma}}$ term, we observe the persistent dimer-singlet state of the ${J}_{1}\ensuremath{-}{J}_{2}$ Heisenberg model, sustaining a nonzero spin gap, while also hosting a gapless nonmagnetic excitation that manifests in the substantial zero-energy peak in the nematic dynamical structure factor. This gapless peak-mode, remaining almost as a fluctuation to the ground state, induces a dilute but robust concentration of nematicity on top of singlets on dimers, which we call the nematic singlet-dimer phase. When the whole nematic excited mode condenses and replaces the singlet, the nematic-dimer phase transforms into the Ising-type ferromagnetic or antiferromagnetic long-range orders. The $\mathrm{\ensuremath{\Gamma}}$ term spontaneously selects magnetic easy axes, and their orientations dictate the type of magnetic order under geometric frustration effects as predicted by Landau's mean-field theory. These theoretical findings provide insights into the exotic low-temperature phase observed in
YbCuS2, characterized by gapless excitations and seemingly nonmagnetic behavior.
We study a kagomelike spin-
21 Heisenberg ladder with competing ferromagnetic (FM) and antiferromagnetic (AFM) exchange interactions. Using the density-matrix renormalization group based calculations, we obtain the ground-state phase diagram as a function of the ratio between the FM and AFM exchange interactions. Five different phases exist. Three of them are spin-polarized phases: an FM phase and two kinds of ferrimagnetic (FR) phases (referred to as FR1 and FR2 phases). The spontaneous magnetization per site is
m=21,31, and
61 in the FM, FR1, and FR2 phases, respectively. This can be understood from the fact that an effective spin-1 Heisenberg chain formed by the upper and lower leg spins has a three-step fractional quantization of the magnetization per site as
m=1,21, and 0. In particular, an anomalous ``intermediate'' state
m=21 of the effective spin-1 chain with the reduced Hilbert space of a spin from three to two dimensional is highly unexpected in the context of conventional spin-1 physics. Thus, surprisingly, the effective spin-1 chain behaves like a spin-
21 chain with SU(2) symmetry. The remaining two phases are spin-singlet phases with translational symmetry breaking in the presence of valence bond formations. One of them is octamer-singlet phase with a spontaneous octamerization long-range order of the system, and the other is period-4 phase characterized by the magnetic superstructure with a period of four structural unit cells. In these spin-singlet phases, we find the coexistence of valence bond structure and gapless chain. Although this may be emerged through the order-by-disorder mechanism, there can be few examples of such a coexistence.
We study the one-dimensional spin-
21 Heisenberg model with antiferromagnetic nearest-neighbor
J1 and next-nearest-neighbor
J2 exchange couplings in magnetic field
h. With varying dimensionless parameters
J2/J1 and
h/J1, the ground state of the model exhibits several phases including three gapped phases (dimer, 1/3-magnetization plateau, and fully polarized phases) and four types of gapless Tomonaga-Luttinger liquid (TLL) phases which we dub TLL1, TLL2, spin-density-wave
(SDW2), and vector chiral phases. From extensive numerical calculations using the density-matrix renormalization-group method, we investigate various (multiple-)spin-correlation functions in detail and determine dominant and subleading correlations in each phase. For the one-component TLLs, i.e., the TLL1,
SDW2, and vector chiral phases, we fit the numerically obtained correlation functions to those calculated from effective low-energy theories of TLLs and find good agreement between them. The low-energy theory for each critical TLL phase is thus identified, together with TLL parameters which control the exponents of power-law decaying correlation functions. For the TLL2 phase, we develop an effective low-energy theory of two-component TLL consisting of two free bosons (central charge
c=1+1), which explains numerical results of entanglement entropy and Friedel oscillations of local magnetization. Implications of our results to possible magnetic phase transitions in real quasi-one-dimensional compounds are also discussed.