We demonstrate the imaging of localized surface electric (E) field effects on the atomic spectrum in a vapor cell used in Rydberg atom-based sensors. These surface E-fields can result from an induced electric charge distribution on the surface. Induced surface charge distributions can dramatically perturb the atomic spectrum, hence degrading the ability to perform electrometry. These effects become pronounced near the walls of the vapor cell, posing challenges for vapor cell miniaturization. Using a fluorescence imaging technique, we investigate the effects of surface charge on the atomic spectrum generated with electromagnetically induced transparency (EIT). Our results reveal that visible light (480 and 511 nm), i.e., the coupling laser used in two-photon Rydberg EIT schemes, generates localized patches of charge or dipoles where this light interacts with the glass walls of the vapor cell, while a three-photon Rydberg EIT scheme using only near-infrared wavelength lasers shows no measurable field induction. Additionally, imaging in a vacuum chamber where a glass plate is placed between large electrodes confirms that the induced charge is positive. We further validate these findings by studying the photoelectric effect with broadband light during EIT and impedance measurements. These results demonstrate the power of the fluorescence imaging technique to study localized E-field distributions in vapor cells and to target the photoelectric effect of the alkali-exposed glass of vapor cells as a major disruptor in Rydberg atom-based sensors.
We present and characterize a Rb atomic vapor cell with silicon-ring electrodes embedded between borosilicate glass tubes. The ring electrodes can be externally connectorized for application of electric fields to the inside of the cell. An atom-based, all-optical, laser-spectroscopic field-sensing method is employed to measure electric fields in the cell. Here, the Stark effect of electric-field-sensitive rubidium Rydberg atoms is exploited to measure dc electric fields in the cell of approximately
5 V/cm, with a relative uncertainty of 10%. Measurement results are compared with dc field calculations, allowing us to quantify electric field attenuation due to free surface charges inside the cell. We further measure the propagation of microwave fields into the cell, using Autler-Townes splitting of Rydberg levels as a field probe. Results are obtained for a range of microwave powers and polarization angles relative to the cell's ring electrodes. We compare the results with microwave-field calculations.
Research of hot atomic vapor systems has a long history. Recently, much-improved technologies, such as lasers, microwaves and digital/analog control systems, have led to exciting progress in this reviving field. Due to its cryogenic-free and vacuum-free deployment potential, room-temperature and quantum-enabled sensing devices using gaseous atoms have become a popular research topic, and engineering such devices has received considerable attention. Proof-of-principle experiments have been performed demonstrating new ideas such as quantum-enhanced motion sensors, next-generation magnetometers, Rydberg enabled microwave sensors, etc. This thesis focuses on my work related to electromagnetic-field sensing using Rydberg atoms in vapor cells, where Rydberg atoms are excited and detected by electromagnetically induced transparency (EIT) spectroscopy. I first investigate the detection of strong magnetic fields (
sim 1~T) in the Paschen-Back regime. The diamagnetic (quadratic) response of the Rydberg levels makes the atoms sensitive to small fluctuations in field strength on a large background. By implementing an isotope-mixed cell, we demonstrate that accurate measurement, within a relative uncertainty of
pm0.12%. Many Rydberg-enabled radio frequency and microwave sensing applications require a capability of zeroing or intentional tuning of small DC electric fields inside the vapor cell. For this purpose, I explore an in-situ DC electric-field sensing and tuning method without using any bulk or thin film electrodes. I find that the photoelectric effect on the vapor cell walls (with invisible, atomic Rb aggregate layers covering the surfaces) can generate tuning fields up to 0.8~V/cm, with an inhomogeneity of about 2%. The spatial distribution of these fields can be directly monitored by quadratic Stark shifts of the Rydberg atoms. This work may inspire new approaches for DC-field control in miniaturized, metal-free atomic vapor-cell devices. Like many other quantum measurements on hot gaseous samples, short interaction time and other technical decoherence processes are the major factors which limit the precision and, in certain cases, the accuracy of the metrological results. In order to study these effects in the context of EIT, I performed an EIT experiment using a
Lambda-type quantum system consisting of the hyperfine ground states and the first excited electronic state of the Rb atoms contained in a buffer-gas-free thermal vapor cell without anti-relaxation coating. Technical line-broadening effects due to inhomogeneity of stray magnetic fields, laser frequency jitter, transverse beam intensity distribution, interaction time distribution, and atom-wall/impurity gas collisions are studied. Experimental results and numerical simulations are compared. These results provide crucial information and quantitative insights for vapor cell sensor design. The development of compact and multi-functional spectroscopy vapor cells is widely considered to be a critical engineering step towards manufacturing field-deployable sensors for real life applications. My R&D efforts towards fabrication of glass spectroscopy cells with integrated, highly-conductive silicon components are presented in the last part of my thesis. I explored various technical challenges and successfully developed a proof-of-principle prototype from scratch. The device allows the application of electric fields inside the cell for particle trapping and for tuning Rydberg transitions. Further, the highly-conductive silicon components enable microwave polarization filtering for microwave sensing applications, plasma-physics studies, etc. Preliminary experimental/technical data and simulations are presented. In summary, in my thesis I report on a comprehensive study of several spectroscopic and field sensing applications of Rydberg and ground-state atoms in vapor cells, as well as forays into novel methods to engineer vapor cells with embedded electrodes.
A Rydberg atom is a special type of atom characterized by a high principal quantum number. Electric field sensors based on Rydberg atoms have received widespread attention due to their high polarizability. However, there is currently little research on the use of Rydberg atoms for direct current (DC) or low-frequency electric fields, mainly due to the shielding effect of atomic vapor cells in low-frequency electric fields, which makes accurate measurement of the electric fields extremely challenging. In this paper, we construct a Rydberg ladder configuration by using probe laser at 852 nm and coupling laser at 510 nm in a room-temperature cesium vapor cell with integrated electrode plates, thereby enabling the realizing of a Floquet-EIT (electromagnetically induced transparency) spectrum dressed by a radio frequency (RF) field in the presence of a DC electric field. We further study the influence of DC electric field on spectral characteristic. Experimentally, it is observed that when only the RF electric field is applied, the EIT spectrum displays solely even-order sidebands. Furthermore, when both the RF field and the DC electric field are simultaneously present, the first-order sideband signal of the Floquet-EIT is observed. As the intensity of the DC electric field increases, the amplitude of the first-order sideband gradually increases. However, increasing the DC electric field to a sufficient magnitude induces sideband interference, which leads the sideband amplitudes to decrease. Furthermore, increasing the RF frequency can alleviate the interference effects induced by the DC electric field on the first-order sideband. Finally, comparing the relative standard deviation of the sideband amplitudes of the Floquet-EIT spectra with the frequency shifts of the DC-Stark spectra under weak DC electric fields, we find that the measurement accuracy of the former is significantly superior to that of the latter. This work makes use of a Cs atomic vapor cell with an integrated electrode to avoid shielding effects. By observing Floquet-EIT spectra, the response of the spectra to DC electric fields is investigated. This experiment provides novel insights into the quantum sensing measurements of DC and low-frequency electric fields.
We demonstrate the measurement of super low-frequency electric field using Rydberg atoms in an atomic vapor cell with inside parallel electrodes, thus overcoming the low-frequency electric-field-screening effect at frequencies below a few kHz. Rydberg electromagnetically induced transparency (EIT) spectra involving 52 D 5/2 state is employed to measure the signal electric field. An auxiliary DC field is applied to improve the sensitivity. A DC Stark map is demonstrated, where the utilized 52 D 5/2 exhibits m j = 1/2, 3/2, 5/2 Stark shifts and splittings. The m j = 1/2 state is employed to detect the signal field because of its larger polarizability than that of m j = 3/2, 5/2. Also, we show that the strength of the spectrum is dependent on the angle between the laser polarizations and the electric field. With optimization of the applied DC field to shift the m j = 1/2 Rydberg energy level to a high sensitivity region and the laser polarizations to obtain the maximum m j = 1/2 signal, we achieve the detection of the signal electric field with a frequency of 100 Hz down to 214.8 µ V/cm with a sensitivity of 67.9 µ V cm −1 Hz −1/2 , and the linear dynamic range is over 37 dB. Our work extends the measurement frequency of Rydberg sensors to super low frequency with high sensitivity, which has the advantages of high sensitivity and miniaturization for receiving super low frequency.
The use of Rydberg atoms for radio frequency electric field sensing has emerged as a promising alternative to traditional antenna-based designs that enables all-optical readout. However, the need for atomic vapor cells comprised of dielectric materials can adversely affect the electric field distribution at the probing volume. Here we describe the effects of electric field inhomogeneity on measured optical electromagnetically induced transparency (EIT) spectra. This is accomplished using custom-designed waveguide-embedded atomic vapor cells with stub tuners that allow control of the degree of electric field inhomogeneity within the cell. We describe the resulting broadening of the measured EIT feature and the associated reduction in magnitude, which results in an overall reduced sensitivity of the resulting measurement.