Results are presented for the quench dynamics of a clean and interacting electron system, where the quench involves varying the strength of the attractive interaction along arbitrary quench trajectories. The initial state before the quench is assumed to be a normal electron gas, and the dynamics is studied in a regime where long-range order is absent, but nonequilibrium superconducting fluctuations need to be accounted for. A quantum kinetic equation using a two-particle irreducible formalism is derived. Conservation of energy, particle number, and momentum emerge naturally, with the conserved currents depending on both the electron Green's functions and the Green's functions for the superconducting fluctuations. The quantum kinetic equation is employed to derive a kinetic equation for the current, and the transient optical conductivity relevant to pump-probe spectroscopy is studied. The general structure of the kinetic equation for the current is also justified by a phenomenological approach that assumes model F in the Halperin-Hohenberg classification, corresponding to a nonconserved order parameter coupled to a conserved density. Linear response conductivity and the diffusion coefficients in thermal equilibrium are also derived, and connections with Aslamazov-Larkin fluctuation corrections are highlighted. Results are also presented for the time evolution of the local density of states. It is shown that Andreev scattering processes result in an enhanced density of states at low frequencies. For a quench trajectory corresponding to a sudden quench to the critical point, the density of states is shown to grow in a manner where the time after the quench plays the role of the inverse detuning from the critical point.
Results are presented for the quench dynamics of a clean and interacting electron system, where the quench involves varying the strength of the attractive interaction along arbitrary quench trajectories. The initial state before the quench is assumed to be a normal electron gas, and the dynamics is studied in a regime where long-range order is absent, but nonequilibrium superconducting fluctuations need to be accounted for. A quantum kinetic equation using a two-particle irreducible formalism is derived. Conservation of energy, particle number, and momentum emerge naturally, with the conserved currents depending on both the electron Green's functions and the Green's functions for the superconducting fluctuations. The quantum kinetic equation is employed to derive a kinetic equation for the current, and the transient optical conductivity relevant to pump-probe spectroscopy is studied. The general structure of the kinetic equation for the current is also justified by a phenomenological approach that assumes model F in the Halperin-Hohenberg classification, corresponding to a nonconserved order parameter coupled to a conserved density. Linear response conductivity and the diffusion coefficients in thermal equilibrium are also derived, and connections with Aslamazov-Larkin fluctuation corrections are highlighted. Results are also presented for the time evolution of the local density of states. It is shown that Andreev scattering processes result in an enhanced density of states at low frequencies. For a quench trajectory corresponding to a sudden quench to the critical point, the density of states is shown to grow in a manner where the time after the quench plays the role of the inverse detuning from the critical point.
Results are presented for the time evolution of fermions initially in a nonzero temperature normal phase, following the switch on of an attractive interaction. The dynamics are studied in the disordered phase close to the critical point, where the superfluid fluctuations are large. The analysis is conducted within a two-particle irreducible, large N approximation. The system is considered from the perspective of critical quenches where it is shown that the fluctuations follow universal model A dynamics. A signature of this universality is found in a singular correction to the fermion lifetime, given by a scaling form ${t}^{(3\ensuremath{-}d)/2}{S}_{d}({\ensuremath{\varepsilon}}^{2}t)$, where d is the spatial dimension, t is the time since the quench, and $\ensuremath{\varepsilon}$ is the fermion energy. The singular behavior of the spectral density is interpreted as arising due to incoherent Andreev reflections off superfluid fluctuations.
There has been significant interest in the generation of very short-lived superconducting states in solid-state films. Here, we consider the role of nonequilibrium superconducting fluctuations in such systems, generated by an interaction quench, considering the limit of large static disorder. In particular, we argue that because of critical slowing down, the regime of the fluctuation dominated normal state is more important than might be naively thought. We show how such a state might appear in the optical conductivity, and give the appropriate nonequilibrium generalization of the Azlamazov-Larkin and Maki-Thompson fluctuation corrections to the optical conductivity. For a quench to the superconducting critical point, we show that the fluctuation corrections lead to power-law aging behavior in the optical conductivity. The power-law aging from Azlamazov-Larkin and Maki-Thompson terms are qualitatively different, despite the effect of the two being similar in dc measurements in thermal equilibrium. These signatures provide a road map for experiments to identify the role of superconducting fluctuations in a transient state.
Recent advances in ultra-fast measurement in cold atoms, as well as pump-probe spectroscopy of K3C60 films, have opened the possibility of rapidly quenching systems of interacting fermions to, and across, a finite temperature superfluid transition. However determining that a transient state has approached a second-order critical point is difficult, as standard equilibrium techniques are inapplicable. We show that the approach to the superfluid critical point in a transient state may be detected via time-resolved transport measurements, such as the optical conductivity. We leverage the fact that quenching to the vicinity of the critical point produces a highly time dependent density of superfluid fluctuations, which affect the conductivity in two ways. Firstly by inelastic scattering between the fermions and the fluctuations, and secondly by direct conduction through the fluctuations. The competition between these two effects leads to non-monotonic behavior in the time-resolved optical conductivity, providing a signature of the critical transient state.
Recent advances in ultrafast measurement in cold atoms, as well as pump-probe spectroscopy of K_{3}C_{60} films, have opened the possibility of rapidly quenching systems of interacting fermions to, and across, a finite temperature superfluid transition. However, determining that a transient state has approached a second-order critical point is difficult, as standard equilibrium techniques are inapplicable. We show that the approach to the superfluid critical point in a transient state may be detected via time-resolved transport measurements, such as the optical conductivity. We leverage the fact that quenching to the vicinity of the critical point produces a highly time dependent density of superfluid fluctuations, which affect the conductivity in two ways. First, by inelastic scattering between the fermions and the fluctuations, and second by direct conduction through the fluctuations, with the latter providing a lower resistance current carrying channel. The competition between these two effects leads to nonmonotonic behavior in the time-resolved optical conductivity, providing a signature of the critical transient state.
Motivated by the experiment by M. Budden {\em et al.} [Nature Physics {\bf 17}, 611 (2021)], who observed signatures of long-lived photo-induced superconductivity, we develop an accurate analytical/computational approach to non-equilibrium superconductivity following a quench. We consider the BCS-Holstein model, which includes both integrable local electron-electron interactions and integrability-breaking electron-phonon coupling. We develop Keldysh-Eliashberg theory on the Kadanoff-Baym contour, which enables us to describe non-equilibrium dynamics of the superconductor. We consider a quench in interactions, which results in a dynamic transition from the initial superconducting state to a normal thermal state in the end of the evolution. It is shown that the dynamics contain two stages: The early-time integrable behavior, involving coherent oscillations of the superconducting order parameter, crosses over to the late-time ergodic dynamics exhibiting a thermal decay into an equilibrium state. In the former regime, our computational approach both reproduces exact analytical results on the integrable dynamics of the order parameter and generalizes those to the case of an initial thermal state. The method also succeeds for the first time in describing both integrable-to-thermalizing crossover and the late-time thermal decay, which is shown to be consistent with the time-dependent Ginzburg-Landau theory (with the exponential decay time dependent on the density of quasiparticle excitations). We observe the electron distribution function approaching the Fermi-Dirac thermal distribution at final stages. The details of two-time non-equilibrium dynamics depend on the density of quasiparticles in the initial state and the integrability-breaking parameters, which under certain conditions may result in a long-lived transient superconductivity consistent with experiment.
This thesis reports on theoretical investigations of the ultrafast nonequilibrium dynamics in superconductors. In particular, two nonequilibrium scenarios are modeled by combining several analytical and numerical methods: transient superconducting phase transition and collective excitations of a superconducting condensate. In the first part of the thesis the possibility to induce singlet superconducting correlations far from equilibrium is explored by applying time-dependent Lanczos algorithm to the one-dimensional extended Hubbard model. Here, the system is driven into a nonequilibrium state by (i) interaction quench and (ii) quench by pulse. In both cases the buildup of the superconducting correlations is studied in view of several correlation functions. Moreover, a transient Meissner effect, which reflects fingerprints of the induced superconductivity, is observed in calculations of the important for experiments time-dependent optical conductivity. In addition, the differences between nonequilibrium dynamics of the extended Hubbard model initiated by interaction quench and by pulse quench are discussed in detail. The second part is devoted to the excitation of collective modes in a superconductor out of equilibrium. First of all, focus is given to the properties of collective modes close to equilibrium conditions, where a linearized response can be expected. Within the framework of the (Nambu-) matrix kinetic theory in the clean limit a comprehensive gauge-invariant description of the collective modes associated with phase fluctuations of the order parameter is analytically formulated for the generalized case of two- band superconducting systems. Particular emphasis is on the application to the recently discovered noncentrosymmetric superconductors. A detailed analysis of the collective modes includes specification of the gauge mode (common to all superconductors) and the Leggett mode (collective fluctuations of the interband phase difference), and investigation of their subtle interplay in view of validity of the charge conservation law and the participation in the Anderson-Higgs mechanism. Further, the nonequilibrium excitation of the superconducting gaps for the case of two-band superconductors with singlet pairing correlations is investigated in a view of optical pump-probe experiments. For this purpose a semi-numerical method based on the density- matrix theory is formulated. In this case additional amplitude (Higgs) modes were identified, which allow to directly detect the properties of the superconducting condensates as a function of time. Moreover, a new interplay between the phase (Leggett) and amplitude (Higgs) modes is studied in detail. In particular it was found that the nonadiabatic excitation process leads to strong coupling between both modes. Finally, based on calculations of the time-dependent optical conductivity the prediction is made that the coupled Higgs and Leggett modes can be clearly visible in the pump-probe absorption spectra.