Abstract Large anisotropic exchange in 5 d and 4 d oxides and halides open the door to new types of magnetic ground states and excitations, inconceivable a decade ago. A prominent case is the Kitaev spin liquid, host of remarkable properties such as protection of quantum information and the emergence of Majorana fermions. Here we discuss the promise for spin-liquid behavior in the 4 d 5 honeycomb halide α -RuCl 3 . From advanced electronic-structure calculations, we find that the Kitaev interaction is ferromagnetic, as in 5 d 5 iridium honeycomb oxides, and indeed defines the largest superexchange energy scale. A ferromagnetic Kitaev coupling is also supported by a detailed analysis of the field-dependent magnetization. Using exact diagonalization and density-matrix renormalization group techniques for extended Kitaev-Heisenberg spin Hamiltonians, we find indications for a transition from zigzag order to a gapped spin liquid when applying magnetic field. Our results offer a unified picture on recent magnetic and spectroscopic measurements on this material and open new perspectives on the prospect of realizing quantum spin liquids in d 5 halides and oxides in general.
Abstract Elementary excitations in entangled states such as quantum spin liquids may exhibit exotic statistics different from those obeyed by fundamental bosons and fermions. Non-Abelian anyons exist in a Kitaev spin liquid—the ground state of an exactly solvable model. A smoking-gun signature of these excitations, namely a half-integer quantized thermal Hall conductivity, was recently reported in α-RuCl3. While fascinating, a microscopic theory for this phenomenon remains elusive because the pure Kitaev model cannot display this effect in an intermediate magnetic field. Here we present a microscopic theory of the Kitaev spin liquid emerging between the low- and high-field states. Essential to this result is an antiferromagnetic off-diagonal symmetric interaction which allows the Kitaev spin liquid to protrude from the ferromagnetic Kitaev limit under a magnetic field. This generic model displays a strong field anisotropy, and we predict a wide spin liquid regime when the field is perpendicular to the honeycomb plane.
Abstract Elementary excitations in entangled states such as quantum spin liquids may exhibit exotic statistics different from those obeyed by fundamental bosons and fermions. Non-Abelian anyons exist in a Kitaev spin liquid—the ground state of an exactly solvable model. A smoking-gun signature of these excitations, namely a half-integer quantized thermal Hall conductivity, was recently reported in α-RuCl3. While fascinating, a microscopic theory for this phenomenon remains elusive because the pure Kitaev model cannot display this effect in an intermediate magnetic field. Here we present a microscopic theory of the Kitaev spin liquid emerging between the low- and high-field states. Essential to this result is an antiferromagnetic off-diagonal symmetric interaction which allows the Kitaev spin liquid to protrude from the ferromagnetic Kitaev limit under a magnetic field. This generic model displays a strong field anisotropy, and we predict a wide spin liquid regime when the field is perpendicular to the honeycomb plane.
We investigate the thermal Hall conductivity in the Kitaev model with additional interactions under a magnetic field, employing a finite-temperature tensor network method benchmarked by a thermal pure quantum state technique. We find that the thermal Hall conductivity divided by temperature,
κxy/T, significantly overshoots the value of the half-integer quantization and exhibits a pronounced hump while decreasing temperature. Moreover, we show that the field-direction dependence of
κxy/T is consistent with the sign of the Chern number associated with the Majorana fermions across a wide range of magnetic fields. We also demonstrate that the additional off-diagonal interactions, known as the
Γ and
Γ′ terms, considerably affect
κxy/T. In particular, we show that positive
Γ and negative
Γ′ lead to a remarkable enhancement in the intermediate temperature region. From the comparison with the classical counterpart, we reveal that the effects of the
Γ term go beyond the classical picture, indicating significant quantum fluctuation effects, while those of the
Γ′ term are well captured at the classical level. These comprehensive analyses indicate that the enhanced thermal Hall response is consistently explained by dominant contributions from topological Majorana fermions, even within the polarized regime beyond the critical field. Our approach not only establishes a robust theoretical framework for understanding the thermal Hall transport in Kitaev materials such as
α-RuCl
3, but also offers a promising pathway to bridge the gap between theories and experiments across a wide range of strongly correlated materials.
Quantum spin liquid is a phase of matter featured with quantum entanglement and fractionalization, and it has been sought after in condensed matter. Kitaev quantum spin liquid has been of particular interest due to the emergent quasiparticles of Majorana fermion, which is proposed as a venue for quantum computations. Recently, experimental evidences for Majorana fermion have been reported in the Kitaev quantum magnet -RuCl3. Half-integer quantized thermal Hall effect and field-angle dependent Majorana gap were experimentally observed. In this article, we review physics of Kitaev quantum spin liquid and recent advances in experiments.
Abstract The bond-disordered Kitaev model attracts much attention due to the experimental relevance in α-RuCl3 and A3LiIr2O6 (A = H, D, Ag, etc.). Applying a magnetic field to break the time-reversal symmetry leads to a strong modulation in mass terms for Dirac cones. Because of the smallness of the flux gap of the Kitaev model, a small bond disorder can have large influence on itinerant Majorana fermions. The quantization of the thermal Hall conductivity κxy/T disappears by a quantum Hall transition induced by a small disorder, and κxy/T shows a rapid crossover into a state with a negligible Hall current. We call this immobile liquid state Anderson–Kitaev spin liquid (AKSL). Especially, the critical disorder strength δJc1 ~ 0.05 in the unit of the Kitaev interaction would have many implications for the stability of Kitaev spin liquids.