We report two results complementing the second law of thermodynamics for Markovian open quantum systems coupled to multiple reservoirs with different temperatures and chemical potentials. First, we derive a nonequilibrium free energy inequality providing an upper bound for a maximum power output, which for systems with inhomogeneous temperature is not equivalent to the Clausius inequality. Second, we derive local Clausius and free energy inequalities for subsystems of a composite system. These inequalities differ from the total system one by the presence of an information-related contribution and build the ground for thermodynamics of quantum information processing. Our theory is used to study an autonomous Maxwell demon.
We report two results complementing the second law of thermodynamics for Markovian open quantum systems coupled to multiple reservoirs with different temperatures and chemical potentials. First, we derive a nonequilibrium free energy inequality providing an upper bound for a maximum power output, which for systems with inhomogeneous temperature is not equivalent to the Clausius inequality. Second, we derive local Clausius and free energy inequalities for subsystems of a composite system. These inequalities differ from the total system one by the presence of an information-related contribution and build the ground for thermodynamics of quantum information processing. Our theory is used to study an autonomous Maxwell demon.
We review a general theory of thermodynamics of information processing. The background of this topic is the recently-developed nonequilibrium statistical mechanics and quantum (and classical) information theory. These theories are closely related to the modern technologies to manipulate and observe small systems; for example, macromolecules and colloidal particles in the classical regime, and quantum-optical systems and quantum dots in the quantum regime. First, we review a generalization of the second law of thermodynamics to the situations in which small thermodynamic systems are subject to quantum feedback control. The generalized second law is expressed in terms of an inequality that includes the term of information obtained by the measurement, as well as the thermodynamic quantities such as the free energy. This inequality leads to the fundamental upper bound of the work that can be extracted by a “Maxwell's demon”, which can be regarded as a feedback controller with a memory that stores measurement outcomes. Second, we review generalizations of the second law of thermodynamics to the measurement and information erasure processes of the memory of the demon that is a quantum system. The generalized second laws consist of inequalities that identify the lower bounds of the energy costs that are needed for the measurement and the information erasure. The inequality for the erasure leads to the celebrated Landauer's principle for a special case. Moreover, these inequalities enable us to reconcile Maxwell's demon with the second law of thermodynamics. In these inequalities, thermodynamic quantities and information contents are treated on an equal footing. In fact, the inequalities are model-independent, so that they can be applied to a broad class of information processing. Therefore, these inequalities can be called the second law of “information thermodynamics”.
Thermodynamics of information identifies information flow as a thermodynamic resource, but whether quantum coherence and collective coupling can enhance it at low entropy-production cost remains unresolved. We address this question for interacting open quantum systems by deriving a thermodynamic uncertainty relation that bounds information flow in terms of entropy production in nonequilibrium steady states. We construct a quantum engine in which N-fold degenerate ground and excited states are collectively coupled to heat baths. Collective jumps enhance heat currents and information flow linearly with N, while entropy production remains independent of N, realizing a high-power, low-dissipation autonomous quantum Maxwell's demon that leverages collectively enhanced information flow to pump heat against a temperature gradient. Beyond steady states, collective interactions amplify the unitary component of quantum information flow, yielding a quadratic enhancement of the free-energy charging power of quantum batteries. Our results reveal scalable advantages of quantum coherence and collective effects in quantum engines.
We design a heat engine with multiheat reservoir, an ancillary system, and quantum memory. We then derive an inequality related to the second law of thermodynamics and give a limitation on the work gain from the engine by analyzing the entropy change and quantum mutual information change during the process. In addition, remarkably, by the combination of two independent engines and with the help of the entropic uncertainty relation with quantum memory, we find that the total maximum work gained from those two heat engines should be larger than a quantity related to the quantum entanglement between the ancillary state and the quantum memory. This result provides a lower bound for the maximum work extracted, in contrast to the upper bound in the conventional second law of thermodynamics. However, the validity of this inequality depends on whether the maximum work can achieve the upper bound.
A consistent theory of non-equilibrium thermodynamics for Markovian open quantum systems has been developed in the late seventies in analogy with Classical Irreversible Thermodynamics. The time-evolution of these open systems is usually described by means of effective master equations in Lindblad form, that turn out to be reliable when there is a separation of time-scales between system and environment, such that memory effects are negligible and the so-called Markovian approximation is justified. In this framework, the variations of energy and entropy in the system are consistently described, distinguishing between heat and work contributions and providing a statement of the second law of thermodynamics as positivity of the entropy production.\nHowever, there is empirical evidence that many physical systems like photosynthetic complexes,\nopto-mechanical resonators and superconducting qubits, just to mention a few, experience more general non-Markovian dynamics. The formulation of the laws of thermodynamics in a non-Markovian setting is matter of current research and represents the main topic of the present work. As a first step, we show that the entropy production defined as in the Markovian case can be negative for a class of non-Markovian dynamics. We argue that this outcome should not be interpreted as a violation of the second law of thermodynamics because the environment must be explicitly taken into account in the balance of entropy in the non-Markovian setting. In order to justify this claim we adopt a more general point of view, studying a closed bipartite quantum system, such that each of the two subsystems plays the role of a finite environment out of equilibrium for the other one. We concentrate on the balance of energy first and construct an effective Hamiltonian for each subsystem using physically reasonable requirements; then we define heat and work as in the standard Markovian treatment, with the effective Hamiltonian replacing the free Hamiltonian. It turns out that, in our framework, the work power is perfectly balanced between subsystems, while the correlations can store a part of energy locally inaccessible and exchange it with both subsystems in the form of heat.\nConcerning the balance of entropy, a quite general formulation of the second law of thermodynamics can be given as follows: under the assumption of a factorized initial state for the compound system, the sum of the total variations of the entropies in the two subsystems is always nonnegative. We show with an explicit example that this general formulation does not correspond to the statement presented in the framework of Markovian master equations, which should not be considered a priori the second law of thermodynamics.\nIn the last part of the thesis we concentrate of the so-called fluctuation relations, that are results extending the thermodynamic formalism beyond the behavior of average quantities. After reviewing the main theoretical outcomes, such as the Jarzynski equality and the Crooks fluctuation theorem, we describe a proposal to access experimentally the work performed on an ensemble of diatomic molecules by a time-dependent electric field coupled with their vibrational degree of freedom. This procedure could then be used to test the quantum Jarzynski equality. With respect to the results so far appeared in the literature, in which the left-hand side of the equality is inferred from an experiment and the right-hand side is computed according to a model, in our proposed setting we should be able to estimate from the experiment both the left-hand side and the right-hand side of the equality, independently.
We expand the standard thermodynamic framework of a system coupled to a thermal reservoir by considering a stream of independently prepared units repeatedly put into contact with the system. These units can be in any nonequilibrium state and interact with the system with an arbitrary strength and duration. We show that this stream constitutes an effective resource of nonequilibrium free energy and identify the conditions under which it behaves as a heat, work or information reservoir. We also show that this setup provides a natural framework to analyze information erasure ("Landauer's principle") and feedback controlled systems ("Maxwell's demon"). In the limit of a short system-unit interaction time, we further demonstrate that this setup can be used to provide a thermodynamically sound interpretation to many effective master equations. We discuss how non-autonomously driven systems, micromasers, lasing without inversion, and the electronic Maxwell demon, can be thermodynamically analyzed within our framework. While the present framework accounts for quantum features (e.g. squeezing, entanglement, coherence), we also show that quantum resources do not offer any advantage compared to classical ones in terms of the maximum extractable work.
We formulate a complete theory of quantum thermodynamics in the Rényi entropic formalism exploiting the Rényi relative entropies, starting from the maximum entropy principle. In establishing the first and second laws of quantum thermodynamics, we have correctly identified accessible work and heat exchange in both equilibrium and nonequilibrium cases. The free energy (internal energy minus temperature times entropy) remains unaltered, when all the entities entering this relation are suitably defined. Exploiting Rényi relative entropies we have shown that this "form invariance" holds even beyond equilibrium and has profound operational significance in isothermal process. These results reduce to the Gibbs-von Neumann results when the Rényi entropic parameter α approaches 1. Moreover, it is shown that the universality of the Carnot statement of the second law is the consequence of the form invariance of the free energy, which is in turn the consequence of maximum entropy principle. Further, the Clausius inequality, which is the precursor to the Carnot statement, is also shown to hold based on the data processing inequalities for the traditional and sandwiched Rényi relative entropies. Thus, we find that the thermodynamics of nonequilibrium state and its deviation from equilibrium together determine the thermodynamic laws. This is another important manifestation of the concepts of information theory in thermodynamics when they are extended to the quantum realm. Our work is a substantial step towards formulating a complete theory of quantum thermodynamics and corresponding resource theory.