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arXiv:1701.07628 · Physical Review A

Second law of thermodynamics with quantum memory

Li-Hang Ren, Heng Fan

Published Oct 6, 2017• 7 citations
arXivHTMLPDF

Abstract

We design a heat engine with multiheat reservoir, an ancillary system, and quantum memory. We then derive an inequality related to the second law of thermodynamics and give a limitation on the work gain from the engine by analyzing the entropy change and quantum mutual information change during the process. In addition, remarkably, by the combination of two independent engines and with the help of the entropic uncertainty relation with quantum memory, we find that the total maximum work gained from those two heat engines should be larger than a quantity related to the quantum entanglement between the ancillary state and the quantum memory. This result provides a lower bound for the maximum work extracted, in contrast to the upper bound in the conventional second law of thermodynamics. However, the validity of this inequality depends on whether the maximum work can achieve the upper bound.

DOI
10.1103/physreva.96.042304

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Sadi Carnot's theorem regarding the maximum efficiency of heat engines is considered to be of fundamental importance in thermodynamics. This theorem famously states that the maximum efficiency depends only on the temperature of the heat baths used by the engine, but not on the specific structure of baths. Here, we show that when the heat baths are finite in size, and when the engine operates in the quantum nanoregime, a revision to this statement is required. We show that one may still achieve the Carnot efficiency, when certain conditions on the bath structure are satisfied; however if that is not the case, then the maximum achievable efficiency can reduce to a value which is strictly less than Carnot. We derive the maximum efficiency for the case when one of the baths is composed of qubits. Furthermore, we show that the maximum efficiency is determined by either the standard second law of thermodynamics, analogously to the macroscopic case, or by the non increase of the max relative entropy, which is a quantity previously associated with the single shot regime in many quantum protocols. This relative entropic quantity emerges as a consequence of additional constraints, called generalized free energies, that govern thermodynamical transitions in the nanoregime. Our findings imply that in order to maximize efficiency, further considerations in choosing bath Hamiltonians should be made, when explicitly constructing quantum heat engines in the future. This understanding of thermodynamics has implications for nanoscale engineering aiming to construct small thermal machines.