Few-mode models are a cornerstone of the theoretical work in quantum optics, with the famous singlemode Jaynes-Cummings model being only the most prominent example.In this work, we develop an ab initio few-mode theory, a framework connecting few-mode system-bath models to ab initio methods.We first present a method to derive exact few-mode Hamiltonians for noninteracting quantum potential scattering problems and demonstrate how to rigorously reconstruct the scattering matrix from such few-mode Hamiltonians.We show that, upon inclusion of a background scattering contribution, an ab initio version of the well-known input-output formalism is equivalent to standard scattering theory.On the basis of these exact results for noninteracting systems, we construct an effective few-mode expansion scheme for interacting theories, which allows us to extract the relevant degrees of freedom from a continuum in an open quantum system.As a whole, our results demonstrate that few-mode as well as input-output models can be extended to a general class of problems and open up the associated toolbox to be applied to various platforms and extreme regimes.We outline differences of the ab initio results to standard model assumptions, which may lead to qualitatively different effects in certain regimes.The formalism is exemplified in various simple physical scenarios.In the process, we provide a proof of concept of the method, demonstrate important properties of the expansion scheme, and exemplify new features in extreme regimes.
Few-mode models are a cornerstone of the theoretical work in quantum optics, with the famous singlemode Jaynes-Cummings model being only the most prominent example.In this work, we develop an ab initio few-mode theory, a framework connecting few-mode system-bath models to ab initio methods.We first present a method to derive exact few-mode Hamiltonians for noninteracting quantum potential scattering problems and demonstrate how to rigorously reconstruct the scattering matrix from such few-mode Hamiltonians.We show that, upon inclusion of a background scattering contribution, an ab initio version of the well-known input-output formalism is equivalent to standard scattering theory.On the basis of these exact results for noninteracting systems, we construct an effective few-mode expansion scheme for interacting theories, which allows us to extract the relevant degrees of freedom from a continuum in an open quantum system.As a whole, our results demonstrate that few-mode as well as input-output models can be extended to a general class of problems and open up the associated toolbox to be applied to various platforms and extreme regimes.We outline differences of the ab initio results to standard model assumptions, which may lead to qualitatively different effects in certain regimes.The formalism is exemplified in various simple physical scenarios.In the process, we provide a proof of concept of the method, demonstrate important properties of the expansion scheme, and exemplify new features in extreme regimes.
The thesis addresses the fundamental interplay between indistinguishability and interactions in few- and many-body quantum systems, treated in two separate approaches, both analytic in nature, using semiclassical methods. The few-body sector, considering a strictly fixed number of particles, is addressed within the framework of first quantization. By sticking to descriptions as (micro-)canonical ensembles the approach overcomes the inappropriate use of virial expansions. It is based on cluster expansions where quantum statistics are treated exactly and interparticle forces are described non-perturbatively. After a full formal development the cluster expansions are supplemented with short-time dynamical information that is equated with the description of smooth spectral properties or equivalently temperatures above strong quantum degeneracy, which, in the single-particle context, is the essential ingredient to what is known as semiclassical Weyl expansions. This reduction allows for the fully analytical description of universal features of large classes of systems by either truncating to a specific class of allowed collision processes, i.e., two-body collisions, or by extracting higher-order interaction kernels from related integrable models. The consistent combination with scaling considerations, minimal ground-state information and strong-coupling expansions leads to a toolbox providing most of the thermodynamic and spectral properties of one-dimensional systems with short-range interactions, all in terms of the lowest-order interaction kernels. The analytical results are in excellent qualitative and quantitative agreement with extensive numerical simulations for both integrable and non-integrable models of experimental relevance in cold atom physics. The many-body sector is in contrast treated in the second quantized formulation of quantum mechanics making use of the well-known collection of semiclassical methods that are subsumed under the name periodic orbit theory. As these methods apply in a highly system specific manner, the attractive Bose gas on a ring is chosen as exemplary model to show a case where the semiclassical quantization of mean-field dynamics, here considered as the classical analogue, can be used to obtain analytical non-trivial information on correlation-related many-body effects, especially related to quantum critical behavior in this model. After a simplification by truncating to the lowest single-particle momentum modes the consistent application of Einstein-Brillouin-Keller quantization yields a description valid for large numbers of bosons. Besides analytically reproducing numerical spectra to high accuracy, the approach enables one to extract asymptotic scaling laws for level spacings around quantum criticality, representing properties. These (finite) energy differences are intrinsically tied to inter-particle correlations and therefore elude a more conventional description by means of a mean-field theory extended with Bogoliubov quasi particles. An application to the scrambling time of the system, related to a pseudo quantum butterfly effect that stems from a local instability, underlines the importance of the method in the otherwise inaccessible regime of extreme particle numbers.
Understanding dynamics of localized quantum systems embedded in engineered bosonic environments is a central problem in quantum optics and open quantum system theory. We present a formalism for studying few-particle scattering from a localized quantum system interacting with an bosonic bath described by an inhomogeneous wave-equation. In particular, we provide exact relationships between the quantum scattering matrix of this interacting system and frequency domain solutions of the inhomogeneous wave-equation thus providing access to the spatial distribution of the scattered few-particle wave-packet. The formalism developed in this paper paves the way to computationally understanding the impact of structured media on the scattering properties of localized quantum systems embedded in them without simplifying assumptions on the physics of the structured media.
We propose a new, alternative method for ab-initio calculations of the electronic structure of solids, which has been specifically adapted to treat many-body effects in a more rigorous way than many existing ab-initio methods. We start from a standard band-structure calculation for an effective one-particle Hamiltonian approximately describing the material of interest. This yields a suitable set of one-particle basis functions, from which well localized Wannier functions can be constructed using a method proposed by Marzari and Vanderbilt. Within this (minimal) basis of localized Wannier functions the matrix elements of the non-interacting (one-particle) Hamiltonian as well as the Coulomb matrix elements can be calculated. The result is a many-body Hamiltonian in second quantization with parameters determined from first principles calculations for the material of interest. The Hamiltonian is in the form of a multi-band Hamiltonian in second quantization (a kind of extended, multi-band Hubbard model) such that all the standard many-body methods can be applied. We explicitly show how this approach can be solved in the simplest many-body approximation, the mean-field Hartree-Fock approximation (HFA), which takes into account exact exchange and corrects for self-interaction effects.
Simulation of the interaction of light with matter, including at the few-photon level, is important for understanding the optical and optoelectronic properties of materials and for modeling next-generation nonlinear spectroscopies that use entangled light. At the few-photon level the quantum properties of the electromagnetic field must be accounted for with a quantized treatment of the field, and then such simulations quickly become intractable, especially if the matter subsystem must be modeled with a large number of degrees of freedom, as can be required to accurately capture many-body effects and quantum noise sources. Motivated by this we develop a quantum simulation framework for simulating such light-matter interactions on platforms with controllable bosonic degrees of freedom, such as vibrational modes in the trapped ion platform. The key innovation in our work is a scheme for simulating interactions with a continuum field using only a few discrete bosonic modes, which is enabled by a Green's function (response function) formalism. We develop the simulation approach, sketch how the simulation can be performed using trapped ions, and then illustrate the method with numerical examples. Our work expands the reach of quantum simulation to important light-matter interaction models and illustrates the advantages of extracting dynamical quantities such as response functions from quantum simulations.
Abstract Quantum collision models (CMs) provide advantageous case studies for investigating major issues in open quantum systems theory, and especially quantum non-Markovianity. After reviewing their general definition and distinctive features, we illustrate the emergence of a CM in a familiar quantum optics scenario. This task is carried out by highlighting the close connection between the well-known input-output formalism and CMs. Within this quantum optics framework, usual assumptions in the CMs’ literature - such as considering a bath of noninteracting yet initially correlated ancillas - have a clear physical origin.
The quantum theory of many-particle systems is deeply connected to the mathematical formalism and techniques of quantum field theory, which are crucial in order describe the emergent phenomena that arise in condensed matter physics. The main goal of this thesis is to provide a unified description of quantum field theory methods in the context of many-particle physics in order to extend and develop these techniques to better understand the different quantum properties of matter. This both furthers the conceptual understanding of quantum many-body correlation and also allows for the development of novel theoretical techniques that combine the different formalisms employed in condensed matter theory, quantum chemistry and nuclear physics. To achieve this aim, the thesis is composed of two parts. Part I deals with many-body fermion-fermion interactions and is physically motivated by the non-relativistic electronic structure problem. Here, we introduce the Keldysh contour formulation of quantum field theory to provide a unified presentation of quantum systems both in and out-ofequilibrium. Then, we extend the conventional quantum theory of many-particle systems, based on hermitian quantum mechanics, to describe systems governed by non-hermitan Hamiltonians. This allows us to present a natural unification of two major pillars in the ab initio quantum theory of many-particle systems: coupled-cluster theory and the Green’s function formalism. This unification is further demonstrated through the emergence of the coupled-cluster amplitude equations from the Green’s function formalism. In particular, this analysis has direct bearing on the development of novel theoretical approaches to the electronic structure and nuclear many-body problems. Our findings are also relevant to the study of general non-hermitian as well as open quantum systems. Part II focuses on the quantum field theory of electron-nuclear interactions in infinite solids. Here, we use the Keldysh contour representation presented in Part I to understand excited state dynamics that include electron-electron and electron-lattice interactions in materials. We also derive the analytic continuation of the Green’s function for systems that have continuous eigenspectra. This analysis demonstrates the relationship between the Green’s function formalism and scattering theory, making the role of the continuum and causality conditions explicitly clear in the context of the pole condition of the Dyson equation. Using the analytic continuation of the propagator, we provide an in-depth analysis of electron-phonon and exciton-phonon scattering channels, with a particular focus on phonon-driven exciton dissociation scattering. Our theoretical analysis then firmly demonstrates the connection between the extension of the Bethe-Salpeter equation approach to include electron-phonon interactions and effective field theories based on composite exciton-phonon coupling. We subsequently combine the techniques presented in Part I, based on the Dyson supermatrix formulation, with the analysis presented in Part II to calculate, from first principles, the effects of including electron-phonon interactions on the excited states of heterogeneous semiconductors. Finally, we provide a summary of the fundamental contributions presented in this thesis and the potential further research directions to be pursued.