Waveguides in nonlinear materials are a key component for photon pair sources and offer promising solutions to interface quantum memories through frequency conversion. To bring these technologies closer to every-day life, it is still necessary to guarantee a reliable and efficient fabrication of these devices. Therefore, a thorough understanding of the technological limitations of nonlinear waveguiding devices is paramount. In this paper, we study the link between fabrication errors of waveguides in nonlinear crystals and the final performance of such devices. In particular, we first derive a mathematical expression to qualitatively assess the technological limitations of any nonlinear waveguide. We apply this tool to study the impact of fabrication imperfections on the phasematching properties of different quantum processes realized in titanium-diffused lithium niobate waveguides. Finally, we analyse the effect of waveguide imperfections on quantum state generation and manipulation for few selected cases. Studying the impact of fabrication errors on the waveguide widths, we find that the presence of correlated noise plays a major role in the degradation of the phasematching and we suggest different possible strategies to reduce the impact of fabrication imperfections.
Waveguides in nonlinear materials are a key component for photon pair sources and offer promising solutions to interface quantum memories through frequency conversion. To bring these technologies closer to every-day life, it is still necessary to guarantee a reliable and efficient fabrication of these devices. Therefore, a thorough understanding of the technological limitations of nonlinear waveguiding devices is paramount. In this paper, we study the link between fabrication errors of waveguides in nonlinear crystals and the final performance of such devices. In particular, we first derive a mathematical expression to qualitatively assess the technological limitations of any nonlinear waveguide. We apply this tool to study the impact of fabrication imperfections on the phasematching properties of different quantum processes realized in titanium-diffused lithium niobate waveguides. Finally, we analyse the effect of waveguide imperfections on quantum state generation and manipulation for few selected cases. Studying the impact of fabrication errors on the waveguide widths, we find that the presence of correlated noise plays a major role in the degradation of the phasematching and we suggest different possible strategies to reduce the impact of fabrication imperfections.
Entanglement is the hallmark of quantum mechanics. Quantum entanglement -- putting two or more identical particles into a non-factorable state -- has been leveraged for applications ranging from quantum computation and encryption to high-precision metrology. Entanglement is a practical engineering resource and a tool for sidestepping certain limitations of classical measurement and communication. Engineered nonlinear optical waveguides are an enabling technology for generating entangled photon pairs and manipulating the state of single photons. This dissertation reports on: i) frequency conversion of single photons from the mid-infrared to 843nm as a tool for incorporating quantum memories in quantum networks, ii) the design, fabrication, and test of a prototype broadband source of polarization and frequency entangled photons; and iii) a roadmap for further investigations of this source, including applications in quantum interferometry and high-precision optical metrology. \n \nThe devices presented herein are quasi-phase-matched lithium niobate waveguides. Lithium niobate is a second-order nonlinear optical material and can mediate optical energy conversion to different wavelengths. This nonlinear effect is the basis of both quantum frequency conversion and entangled photon generation, and is enhanced by i) confining light in waveguides to increase conversion efficiency, and ii) quasi-phase matching, a technique for engineering the second-order nonlinear response by locally altering the direction of a material's polarization vector. Waveguides are formed by diffusing titanium into a lithium niobate wafer. Quasi-phase matching is achieved by electric field poling, with multiple stages of process development and optimization to fabricate the delicate structures necessary for broadband entangled photon generation. \n \nThe results presented herein update and optimize past fabrication techniques, demonstrate novel optical devices, and propose future avenues for device development. Quantum frequency conversion from 1848nm to 843nm is demonstrated for the first time, with >75% single-photon conversion efficiency. A new electric field poling methodology is presented, combining elements from multiple historical techniques with a new fast-feedback control system. This poling technique is used to fabricate the first chirped-and-apodized Type-II quasi-phase-matched structures in titanium-diffused lithium niobate waveguides, culminating in a measured phasematching spectrum that is predominantly Gaussian (R^2 = 0.80), nearly eight times broader than the unchirped spectrum, and agrees well with simulations.
Lithium niobate (LiNbO3) serves as one of the most competitive materials in nonlinear integrated photonics and becomes a key platform for the realization of integrated optical quantum technology, because it is physically and chemically very stable and it has a larger refractive index, a wider transparent wavelength range and better nonlinear optical characteristics than most of the traditional materials. Using the second-order nonlinear effect of periodically polarized lithium niobate (PPLN) crystal, single-photon frequency conversion was successfully realized to satisfy the quantum measurement requirements. LiNbO3and PPLN Waveguides were widely developed to solve the problems such as easy beam divergence in crystals, so that the improved nonlinear conversion effect promotes the successful fabrication of many quantum devices such as single photon sources, entangled photon sources and single photon detectors etc. By combining LiNbO3waveguides with other waveguide technologies, one can fabricate various LiNbO3integrated optical components serving as the core devices of quantum interfaces, quantum memories and etc. Based on these progresses, we see the attractive potential of LiNbO3material to play a deterministic role in quantum information technology.
Lithium niobate is a critical material extensively used in nonlinear optics. The recent development of nanophotonic lithium niobate devices further extends their importance with enhanced nonlinearity and scalability. However, the performance of nonlinear optical processes in lithium niobate is influenced by the photorefractive effect. In this work, we study the impact of the photorefractive effect on second-order nonlinear optical processes in nanophotonic lithium niobate waveguides. We simulate the parametric down-conversion for squeezed light generation and second-harmonic generation in nanophotonic lithium niobate waveguides, considering the photorefractive effect. The squeezing generation with parametric down-conversion only experiences a constant wavelength shift as the refractive index change remains constant. On the other hand, the second-harmonic generation spectrum is distorted, and a decrease in nonlinear efficiency is observed. This is because the strength of the photorefractive effect varies along the waveguide. We further show that the ideal efficiency of second-harmonic generation can be recovered by the adapted poling technique, where the phase matching condition change caused by the photorefractive effect is compensated by adjusting the poling period of lithium niobate waveguides. Eventually, we analyze the cascaded process of second-harmonic generation and parametric down-conversion for squeezed light generation, and show that squeezing level up to 17.6 dB can be realized using 10 mW power with current performance of nanophotonic lithium niobate devices.
This thesis describes a series of experimental research primarily revolving around the applications of periodically poled lithium niobate (PPLN). Initially, a set of work is described regarding the fabrication and characterisation of PPLN ridge waveguides designed for frequency doubling into the blue/UV range. These waveguides are fabricated via diffusion of zinc into the crystal structure. A precision dicing process creates the sidewall definition for modal confinement and also optical facet preparation. Preliminary results with the most efficient waveguide fabricated produced a maximum conversion efficiency of 6.9%/W in a 14 mm-long device, generating 391 nm light. This was performed with a novel near-IR VECSEL; designed and built as part of a collaboration with the research undertaken in this thesis to investigate new routes for miniaturised UV sources. The development of a non-destructive route to characterise the physical dimensions of a ridge waveguide for nonlinear applications is also presented. This presented methodology uses white light interferometry and standard edge recognition algorithms to determine the waveguide width profile. In combination with numerical propagation constant data for these waveguides, a numerical phasematching spectra can be calculated. A comparison to the experimental phasematching spectra of the second-harmonic generation process enables the discrimination between issues in the fabrication processes. Using bulk PPLN, a final application is presented for communications using mid-IR radiation and all commercial components. This configuration involves the use of differencefrequency generation followed by sum-frequency generation to create the transmitter and receiver systems, respectively. This enables final detection of 809 nm light (firmly within the silicon absorption band). Bit error ratios as low as 10−7 from single-pass nonlinear conversion for both systems without the need for an additional optical amplifier in the receiver. Finally, the propagation of relative intensity noise within the system as the source lasers propagate through a two step nonlinear conversion is presented and discussed within.
Nonlinear photonics studies situations in which light passing through a material can be used to create, reshape, or convert other light in ways that are not possible in ordinary optical systems. In recent years, this has become especially important for quantum photonics, where carefully prepared states of light are used as resources for emerging technologies such as secure communication, ultra-precise measurement, and new forms of information processing. A major challenge, however, is that these effects are delicate, difficult to control, and highly sensitive to the imperfections that arise when trying to build practical devices on a chip. This thesis examines how such nonlinear quantum-optical processes can be both engineered more deliberately and modelled more realistically, with the broader goal of helping move quantum photonic technology from proof-of-principle laboratory demonstrations toward robust and scalable implementation. To do this, the thesis first places nonlinear quantum photonics in a broader technological context and explains the main physical ideas needed to understand how quantum states of light are generated, transformed, and measured. It then develops this picture through a set of concrete examples. These include a method for generating quantum light on a chip while avoiding one of the field’s standard fabrication steps, a proposed chip-scale device that could help connect otherwise incompatible quantum systems by changing the colour and spectral width of light, and a modelling framework that links quantum theory directly to realistic fabricated waveguides, including common imperfections such as loss, non-uniformity, and writing errors. The thesis also reviews a wider class of design methods in which the nonlinear properties of a material are deliberately patterned in order to tailor the light produced. Taken together, the central message is that progress in quantum photonics will depend not only on discovering new effects, but on learning how to design, fabricate, and model these devices in ways that make them practical outside idealized laboratory conditions.
Advanced photonic quantum technologies—from quantum key distribution to quantum computing—require on-chip sources of entangled photons that are both efficient and readily scalable. This theoretical study demonstrates the generation of polarization-entangled Bell states in structurally simple waveguides by exploiting the intrinsic properties of nonlinear crystals. Elaborate phase-matching strategies that commonly involve the spatial modulation of a waveguide’s linear or nonlinear optical properties are thereby circumvented. This study begins with the derivation of general criteria for the second-order susceptibility tensor that enable the generation of cross-polarized photon pairs via spontaneous parametric down-conversion in single-material waveguides. Based on these criteria, all birefringent, non-centrosymmetric crystal classes are then categorized regarding their suitability. Finally, using coupled mode theory, a numerical analysis is performed of cuboid waveguides made from two materials that are highly relevant to integrated photonics: lithium niobate, a well-established platform, and barium titanate, an emerging alternative. Barium titanate is found to consistently outperform lithium niobate by providing a higher nonlinear efficiency and high concurrence over a significantly broader spectral range. These findings outline a practical route towards highly efficient, fabrication-friendly, and scalable sources of polarization-entangled photons for integrated quantum photonic circuits.