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arXiv:1806.10075 · Quantum Science and Technology

An out-of-equilibrium non-Markovian quantum heat engine

Marco Pezzutto, Mauro Paternostro, Yasser Omar

Published Dec 3, 2018• 70 citations
arXivHTMLPDF

Abstract

Abstract We study the performance of a quantum Otto cycle using a harmonic work medium and undergoing collisional dynamics with finite-size reservoirs. We span the dynamical regimes of the work strokes from strongly non-adiabatic to quasi-static conditions, and address the effects that non-Markovianity of the open-system dynamics of the work medium can have on the efficiency of the thermal machine. While such efficiency never surpasses the classical upper bound valid for finite-time stochastic engines, the behaviour of the engine shows clear-cut effects induced by both the finiteness of the evolution time, and the memory-bearing character of the system-environment evolution.

DOI
10.1088/2058-9565/aaf5b4

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Abstract We study the performance of a quantum Otto cycle using a harmonic work medium and undergoing collisional dynamics with finite-size reservoirs. We span the dynamical regimes of the work strokes from strongly non-adiabatic to quasi-static conditions, and address the effects that non-Markovianity of the open-system dynamics of the work medium can have on the efficiency of the thermal machine. While such efficiency never surpasses the classical upper bound valid for finite-time stochastic engines, the behaviour of the engine shows clear-cut effects induced by both the finiteness of the evolution time, and the memory-bearing character of the system-environment evolution.
Abstract Real quantum heat engines lack the separation of time and length scales that is characteristic for classical engines. They must be understood as open quantum systems in non-equilibrium with time-controlled coupling to thermal reservoirs as integral part. Here, we present a systematic approach to describe a broad class of engines and protocols beyond conventional weak coupling treatments starting from a microscopic modeling. For the four stroke Otto engine the full dynamical range down to low temperatures is explored and the crucial role of the work associated with the coupling/de-coupling to/from reservoirs as an integral part in the energy balance is revealed. Quantum correlations turn out to be instrumental to enhance the efficiency which opens new ways for optimal control techniques.
It is investigated whether non-Markovianity, i.e., the memory effects resulting from the coupling of the system to its environment, can be beneficial for the performance of quantum heat engines. Specifically, two physical models are considered. The first one is a well-known single-qubit Otto engine; the non-Markovian behavior is there implemented by replacing standard thermalization strokes with so-called extremal thermal operations which cannot be realized without the memory effects. The second one is a three-stroke engine in which the cycle consists of two extremal thermal operations and a single qubit rotation. It is shown that the non-Markovian Otto engine can generate more work-per-cycle for a given efficiency than its Markovian counterpart, whereas performance of both setups is superior to the three-stroke engine. Furthermore, both the non-Markovian Otto engine and the three-stroke engine can reduce the work fluctuations in comparison with the Markovian Otto engine, with their relative advantage depending on the performance target. This demonstrates the beneficial influence of non-Markovianity on both the average performance and the stability of operation of quantum heat engines.
Enhancement of thermal efficiency of quantum heat engines has been discussed mainly in terms of quantumness of working substances. In the present study, we propose as another possibility to utilize a quantum-mechanical (reversible) feature of system-reservoir interaction, which reveals itself in the short-time regime as a non-Markovian effect on the reduced dynamics of the substance, before asymptotically approaching irreversible processes. For this purpose, we study a limit cycle of the quantum Otto engine comprising a working two-level system and two reservoirs, including the non-Markovian effect for the finite-time isochoric processes while the work-extracting processes are kept quantum adiabatic. Assuming that the system interacts weakly with the reservoirs consisting of infinite bosons, we find a parameter regime beyond the Carnot efficiency in which a positive work is extracted by including a non-Markovian effect called energy backflow. We also find that the interaction energy is finite and contributes to the positive work even for the weak interaction. The work diminishes if we include into the work the energy for detaching the working substance from reservoirs.
We have presented an analytical and numerical study of efficiency fluctuations in quantum Carnot and Otto engines with pistons operating under non-quasi-static adiabatic expansion and compression processes at constant speed, along with quasi-static isothermal (for the Carnot engine) or isochoric processes (for the Otto engine). We have considered the two-point measurement scheme during the adiabatic strokes in this regard. By considering each of the pistons as a single quantum particle in a 1-D box with a non-quasi-statically movable boundary, we capture the stochastic nature of the work output resulting from the unitary evolution of the quantum mechanical state of the system during non-equilibrium processes. Furthermore, we have explicitly shown how the piston speed during quantum non-equilibrium strokes introduces additional quantum fluctuations that modify the average efficiency of both the engines.
The fast-developing quantum technology is propelling thermal machine, which lies at the heart of thermodynamics, into a new golden era. Being stochastic because of the non-negligible thermal and quantum fluctuations, the efficiency and power of a finite-time quantum heat engine exhibit a trade-off, preventing the simultaneous achievement of high power and high efficiency. Conventional studies treat the statistics of a heat engine by assuming canonical thermalization, which is valid only under weak-coupling conditions. We here investigate the noncanonical effect on the statistics of the efficiency and power for a finite-time quantum Otto cycle. It is revealed that their average values and variances are highly controllable by engineering the energy spectrum structure of the composite system consisting of the working substance and the bath. Near the quantum critical point induced by the formation of a bound state in the energy spectrum, the average efficiency and power can be boosted simultaneously, meanwhile, both of their variances are decreased. Deepening our understanding of the usefulness of quantum reservoir engineering in thermodynamics, our result lays the foundation for the realization of efficient and stable quantum energy devices.
The quantum Otto cycle serves as a bridge between the macroscopic world of heat engines and the quantum regime of thermal devices composed from a single element. We compile recent studies of the quantum Otto cycle with a harmonic oscillator as a working medium. This model has the advantage that it is analytically trackable. In addition, an experimental realization has been achieved, employing a single ion in a harmonic trap. The review is embedded in the field of quantum thermodynamics and quantum open systems. The basic principles of the theory are explained by a specific example illuminating the basic definitions of work and heat. The relation between quantum observables and the state of the system is emphasized. The dynamical description of the cycle is based on a completely positive map formulated as a propagator for each stroke of the engine. Explicit solutions for these propagators are described on a vector space of quantum thermodynamical observables. These solutions which employ different assumptions and techniques are compared. The tradeoff between power and efficiency is the focal point of finite-time-thermodynamics. The dynamical model enables the study of finite time cycles limiting time on the adiabatic and the thermalization times. Explicit finite time solutions are found which are frictionless (meaning that no coherence is generated), and are also known as shortcuts to adiabaticity.The transition from frictionless to sudden adiabats is characterized by a non-hermitian degeneracy in the propagator. In addition, the influence of noise on the control is illustrated. These results are used to close the cycles either as engines or as refrigerators. The properties of the limit cycle are described. Methods to optimize the power by controlling the thermalization time are also introduced. At high temperatures, the Novikov–Curzon–Ahlborn efficiency at maximum power is obtained. The sudden limit of the engine which allows finite power at zero cycle time is shown. The refrigerator cycle is described within the frictionless limit, with emphasis on the cooling rate when the cold bath temperature approaches zero.