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arXiv:1806.08635 · Physical review. B./Physical review. B

Gap equation with pairing correlations beyond the mean-field approximation and its equivalence to a Hugenholtz-Pines condition for fermion pairs

L. Pisani, P. Pieri, Giancarlo Calvanese Strinati

Published Sep 11, 2018• 32 citations
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Abstract

The equation for the gap parameter represents the main equation of the pairing theory of superconductivity. Although it is formally defined through a single-particle property, physically, it reflects the pairing correlations between opposite-spin fermions. Here, we exploit this physical connection and cast the gap equation in an alternative form which explicitly highlights these two-particle correlations by showing that it is equivalent to a Hugenholtz-Pines condition for fermion pairs. At a formal level, a direct connection is established in this way between the treatment of the condensate fraction in condensate systems of fermions and bosons. At a practical level, the use of this alternative form of the gap equation is expected to make easier the inclusion of pairing fluctuations beyond mean field. As a proof-of-concept of the new method, we apply the modified form of the gap equation to the long-pending problem about the inclusion of the Gorkov-Melik-Barkhudarov correction across the whole BCS-BEC crossover, from the BCS limit of strongly overlapping Cooper pairs to the BEC limit of dilute composite bosons, and for all temperatures in the superfluid phase. Our numerical calculations yield excellent agreement with the recently determined experimental values of the gap parameter for an ultracold Fermi gas in the intermediate regime between BCS and BEC, as well as with the available quantum Monte Carlo data in the same regime.

DOI
10.1103/physrevb.98.104507

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This Thesis analyzes the role of a mean-field theory and of the fluctuations in two different fermionic systems: the BCS-BEC crossover and high-Tc superconducting cuprates. In the first part of the Thesis we introduce the mean-field theory and the Gaussian-level fluctuations for the BCS-BEC crossover, i.e. the continuous evolution observed in ultracold neutral fermionic systems, from a weakly-coupled regime where fermions form Cooper pairs, to a strongly-coupled regime where the fermions at first form bosonic molecular dimers, subsequently undergoing Bose-Einstein condensation for low enough temperatures. We then analyze some problems related to the crossover: the condensate fraction for a spin-unbalanced Fermi gas, the Beliaev decay for collective excitations and the case of a two-dimensional Fermi gas, for which we calculate the first sound velocity and the Berezinskii-Kosterlitz-Thouless critical temperature, in very good agreement with recent experimental data. Finally we analyze a regularization procedure for the equation of state in the deep-BEC limit, allowing one to analytically derive the correct ratio between the fermionic and bosonic scattering lengths. In the second part of the Thesis we introduce a gauge approach to superconductivity in cuprates in which the hole is decomposed as the product of a spinful neutral particle, the spinon, and a spinless charged particle, the holon. The statistics of each particle is modified by binding it to a gauge field providing a statistical flux, this approach being analogous to Chern-Simons bosonization. We thus obtain a model characterized by three characteristic temperatures corresponding, respectively, to the appearance of a finite density of incoherent holon pairs, of a finite density of incoherent spinon pairs and, finally, to the phase coherence leading to superconductivity. Specifically in the present Thesis within this model we study the superfluid density, demonstrating that the spinon and holon contributions sum according to a Ioffe-Larking-like rule, analogous to that they found for resistivity, showing excellent agreement with experimental data in the moderate underdoping up to optimal doping region. We also demonstrated that the formalism reproduces the quasi-universality observed in experimental data at different dopings and allows for an analytical derivation of a relation that approximates the Uemura relation for moderate dopings.

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The equation for the gap parameter represents the main equation of the pairing theory of superconductivity. Although it is formally defined through a single-particle property, physically, it reflects the pairing correlations between opposite-spin fermions. Here, we exploit this physical connection and cast the gap equation in an alternative form which explicitly highlights these two-particle correlations by showing that it is equivalent to a Hugenholtz-Pines condition for fermion pairs. At a formal level, a direct connection is established in this way between the treatment of the condensate fraction in condensate systems of fermions and bosons. At a practical level, the use of this alternative form of the gap equation is expected to make easier the inclusion of pairing fluctuations beyond mean field. As a proof-of-concept of the new method, we apply the modified form of the gap equation to the long-pending problem about the inclusion of the Gorkov-Melik-Barkhudarov correction across the whole BCS-BEC crossover, from the BCS limit of strongly overlapping Cooper pairs to the BEC limit of dilute composite bosons, and for all temperatures in the superfluid phase. Our numerical calculations yield excellent agreement with the recently determined experimental values of the gap parameter for an ultracold Fermi gas in the intermediate regime between BCS and BEC, as well as with the available quantum Monte Carlo data in the same regime.
Most theoretical treatments of inhomogeneous superconductivity/fermionic superfluidity have been based on the Bogoliubov-deGennes equations (or, else, on their various simplified forms), which implement a standard mean-field decoupling in the presence of spatial inhomogeneities. This approach is reliable even at finite temperature for weak interparticle attraction, when the Cooper pair size is much larger than the average interparticle distance (corresponding to the BCS limit of the BCS-BEC crossover). However, it loses accuracy for increasing attraction when the Cooper pair size becomes comparable or even smaller than the average interparticle distance (corresponding to the BEC limit of the BCS-BEC crossover), in particular when finite-temperature effects are considered. In these cases, inclusion of pairing fluctuations beyond mean field is required, a task that turns out to be especially difficult in the presence of inhomogeneities. Here, we implement the inclusion of pairing fluctuations directly on a coarse-graining version of the Bogoliubov-deGennes equations, which makes it simpler and faster to obtain a solution over the whole sector of the temperature-coupling phase diagram of the BCS-BEC crossover in the broken-symmetry phase. We apply this method in the presence of a supercurrent flow, such that problems related to the Josephson effect throughout the BCS-BEC crossover can be addressed under a variety of circumstances. This is relevant in the view of recent experimental data with ultracold Fermi atoms, to which the results of the present approach are shown to favorably compare in the companion paper.
The generalized Bose–Einstein condensation (GBEC) theory of superconductivity (SC) is briefly surveyed. It hinges on three distinct new ingredients: (i) Treatment of Cooper pairs (CPs) as actual bosons since they obey Bose statistics, in contrast to BCS pairs which do not obey Bose commutation relations; (ii) inclusion of two-hole Cooper pairs (2hCPs) on an equal footing with two-electron Cooper pairs (2eCPs), thus making this a complete boson–fermion (BF) model; and (iii) inclusion in the resulting ternary ideal BF gas with particular BF vertex interactions that drive boson formation/disintegration processes. GBEC subsumes as special cases both BCS (having its 50–50 symmetry of both kinds of CPs) and ordinary BEC theories (having no 2hCPs), as well as the now familiar BCS-Bose crossover theory. We extended the crossover theory with the explicit inclusion of 2hCPs and construct a phase diagram of [Formula: see text] versus [Formula: see text], where [Formula: see text] and [Formula: see text] are the critical and Fermi temperatures, [Formula: see text] is the total number density and [Formula: see text] that of unbound electrons at [Formula: see text]. Also, with this extended crossover one can construct the energy gap [Formula: see text] versus [Formula: see text] for some elemental SCs by solving at least two equations numerically: a gap-like and a number equation. In 50–50 symmetry, the energy gap curve agrees quite well with experimental data. But ignoring 2hCPs altogether leads to the gap curve falling substantially below that with 50–50 symmetry which already fits the data quite well, showing that 2hCPs are indispensable to describe SCs.
We investigate the phase diagram of two-component fermions in the BCS-BEC (Bose-Einstein condensate) crossover. Using functional renormalization-group equations we calculate the effect of quantum fluctuations on the fermionic self-energy parametrized by a wave-function renormalization, an effective Fermi radius, and the gap. This allows us to follow the modifications of the Fermi surface and the dispersion relation for fermionic excitations throughout the whole crossover region. We also determine the critical temperature of the second-order phase transition to superfluidity. Our results are in agreement with BCS theory including Gorkov's correction for a small negative scattering length aaa and with an interacting Bose gas for a small positive aaa. At the unitarity point the result for the gap at zero temperature agrees well with quantum Monte Carlo simulations, while the critical temperature differs.
The superfluid density is a fundamental quantity describing the response to a rotation as well as in two-fluid collisional hydrodynamics. We present extensive calculations of the superfluid density ${\ensuremath{\rho}}_{s}$ in the BCS-BEC crossover regime of a uniform superfluid Fermi gas at finite temperatures. We include strong-coupling or fluctuation effects on these quantities within a Gaussian approximation. We also incorporate the same fluctuation effects into the BCS single-particle excitations described by the superfluid order parameter $\ensuremath{\Delta}$ and Fermi chemical potential $\ensuremath{\mu}$, using the Nozi\`eres--Schmitt-Rink approximation. This treatment is shown to be necessary for consistent treatment of ${\ensuremath{\rho}}_{s}$ over the entire BCS-BEC crossover. We also calculate the condensate fraction Nc{N}_{c}Nc​ as a function of the temperature, a quantity which is quite different from the superfluid density ${\ensuremath{\rho}}_{s}$. We show that the mean-field expression for the condensate fraction Nc{N}_{c}Nc​ is a good approximation even in the strong-coupling BEC regime. Our numerical results show how ${\ensuremath{\rho}}_{s}$ and Nc{N}_{c}Nc​ depend on temperature, from the weak-coupling BCS region to the BEC region of tightly bound Cooper pair molecules. In a companion paper [Phys. Rev. A 74, 063626 (2006)], we derive an equivalent expression for ${\ensuremath{\rho}}_{s}$ from the thermodynamic potential, which exhibits the role of the pairing fluctuations in a more explicit manner.
This Thesis analyzes the role of a mean-field theory and of the fluctuations in two different fermionic systems: the BCS-BEC crossover and high-Tc superconducting cuprates. In the first part of the Thesis we introduce the mean-field theory and the Gaussian-level fluctuations for the BCS-BEC crossover, i.e. the continuous evolution observed in ultracold neutral fermionic systems, from a weakly-coupled regime where fermions form Cooper pairs, to a strongly-coupled regime where the fermions at first form bosonic molecular dimers, subsequently undergoing Bose-Einstein condensation for low enough temperatures. We then analyze some problems related to the crossover: the condensate fraction for a spin-unbalanced Fermi gas, the Beliaev decay for collective excitations and the case of a two-dimensional Fermi gas, for which we calculate the first sound velocity and the Berezinskii-Kosterlitz-Thouless critical temperature, in very good agreement with recent experimental data. Finally we analyze a regularization procedure for the equation of state in the deep-BEC limit, allowing one to analytically derive the correct ratio between the fermionic and bosonic scattering lengths. In the second part of the Thesis we introduce a gauge approach to superconductivity in cuprates in which the hole is decomposed as the product of a spinful neutral particle, the spinon, and a spinless charged particle, the holon. The statistics of each particle is modified by binding it to a gauge field providing a statistical flux, this approach being analogous to Chern-Simons bosonization. We thus obtain a model characterized by three characteristic temperatures corresponding, respectively, to the appearance of a finite density of incoherent holon pairs, of a finite density of incoherent spinon pairs and, finally, to the phase coherence leading to superconductivity. Specifically in the present Thesis within this model we study the superfluid density, demonstrating that the spinon and holon contributions sum according to a Ioffe-Larking-like rule, analogous to that they found for resistivity, showing excellent agreement with experimental data in the moderate underdoping up to optimal doping region. We also demonstrated that the formalism reproduces the quasi-universality observed in experimental data at different dopings and allows for an analytical derivation of a relation that approximates the Uemura relation for moderate dopings.
The problem of the evolution from BCS theory with cooperative Cooper pairing to the formation and condensation of composite bosons has attracted considerable attention for the past several decades. It has gained renewed impetus in the mid-eighties with the discovery of the high-Tc superconductors, which have a coherence length comparable to the interparticle spacing. More recently, this subject has spurred a great deal of research activity in connection with experiments involving dilute atomic gases of fermionic atoms. The initial objective of this work will be to use functional integral techniques to analyze the low-temperature BCS-to-BEC evolution of d-wave superconductors within the saddle point (mean field) approximation for a continuum model. Then, the same mathematical formalism will be applied to the problem of the BCS-to-BEC evolution of fully spin-polarized p-wave Fermi gases in two dimensions. We find that a quantum phase transition occurs for both systems as they are driven from the BCS-like regime of weakly interacting fermionic pairs to the opposite BEC-like regime of strongly interacting bosonic molecules. This is in contrast to the smooth crossover predicted and observed in systems that exhibit s-wave pairing symmetry. We calculate several spectroscopic and thermodynamic properties that signal the occurrence of this phase transition, and suggest some possible experimental realizations. Finally, fluctuations about the saddle point solution are included in the calculations, and the effects of such correction are analyzed in the low (T~0) and high (T~Tc) temperature limits. We conclude that, at high temperatures, the bosonic degrees of freedom that arise from two-particle bound states become essential to describe the strong coupling limit,\nas the saddle point approximation alone becomes unreliable.