Understanding quantum thermalization through entanglement build-up in isolated quantum systems addresses fundamental questions on how unitary dynamics connects to statistical physics. Here, we study the spin dynamics and approach towards local thermal equilibrium of a macroscopic ensemble of S = 3 spins prepared in a pure coherent spin state, tilted compared to the magnetic field, under the effect of magnetic dipole-dipole interactions. The experiment uses a unit filled array of 104 chromium atoms in a three dimensional optical lattice, realizing the spin-3 XXZ Heisenberg model. The buildup of quantum correlation during the dynamics, especially as the angle approaches pi/2, is supported by comparison with an improved numerical quantum phase-space method and further confirmed by the observation that our isolated system thermalizes under its own dynamics, reaching a steady state consistent with the one extracted from a thermal ensemble with a temperature dictated from the system's energy. This indicates a scenario of quantum thermalization which is tied to the growth of entanglement entropy. Although direct experimental measurements of the Renyi entropy in our macroscopic system are unfeasible, the excellent agreement with the theory, which can compute this entropy, does indicate entanglement build-up.
Classical statistical mechanics relies on the ergodic hypothesis, which states that a system explores the entire allowed phase space during its time evolution. Pure quantum states are at odds with this concept as they remain in a single quantum state even if the system's parameters are suddenly altered. However, in a generic many-body system, coherent dynamics drive local thermalization of its subsystems. In this case, any local observable appears thermal and can be described by a statistical ensemble even though the full state remains pure. The key to understanding the phenomenon of quantum thermalization lies in the entanglement properties of the system: The presence of entanglement creates local entropy that validates the use of statistical physics.\nIn this thesis, we experimentally study the emergence of statistical mechanics in a quantum state and observe the fundamental role of quantum entanglement in facilitating this emergence. We perform microscopy on an evolving quantum system, and we see thermalization occur on a local scale while we measure that the full quantum state remains pure.\nThe only known robust exception from the paradigm of quantum thermalization is provided by disordered systems. In this case, the particle transport ceases through the system, preventing the formation of a sufficient amount of entanglement required for thermalization. However, if the many-body system is interacting, the state develops non-local quantum correlations that are inaccessible to any local observable. These correlations spread exponentially slowly in time throughout the entire system and are considered a hallmark feature of many-body-localized states.\nIn order to study the interplay between thermalization and localization in our system, we develop novel methods for high fidelity state preparation and readout. We achieved an exquisite isolation of our system from the environment, which allows us to monitor coherent many-body dynamics over multiple decades of time evolution.\nWe experimentally realize such a many-body localized system and observe the formation of non-local quantum correlations, while the particle transport is frozen in the system. Our work experimentally establishes many-body localization as a qualitatively distinct phenomenon from localization in non-interacting, disordered systems.
Isolated, many-body quantum systems, evolving under their intrinsic dynamics, exhibit a multitude of exotic phenomena and raise foundational questions about statistical mechanics. A flurry of theoretical work has been devoted to understanding how these systems reach thermal equilibrium in the absence of coupling to an external bath and, when thermalization does not occur, investigating the emergent non-equilibrium phases of matter. With the advent of synthetic quantum systems, such as ultra-cold atoms in optical lattices or trapped ions, these questions are no longer academic and can be directly studied in the laboratory. This dissertation explores the non-equilibrium phenomena that stem from the interplay between interactions, disorder, symmetry, topology, and external driving. First, we study how strong disorder, leading to many-body localization, can arrest the heating of a Floquet system and stabilize symmetry-protected topological order that does not have a static analogue. We analyze its dynamical and entanglement properties, highlight its duality to a discrete time crystal, and propose an experimental implementation in a cold-atom setting.Quenched disorder and the many-body localized state are crucial ingredients in protecting macroscopic quantum coherence. We explore the stability of many-body localization in two and higher dimensions and analyze its robustness to rare regions of weak disorder.We then study a second example of non-thermal behavior, namely integrability. We show that a class of random spin models, realizable in systems of atoms coupled to an optical cavity, gives rise to a rich dynamical phase diagram, which includes regions of integrability, classical chaos, and of a novel integrable structure whose conservation laws are reminiscent of the integrals of motion found in a many-body localized phase.The third group of disordered, non-ergodic systems we consider, spin glasses, have fascinating connections to complexity theory and the hardness of constraint satisfaction. We define a statistical ensemble that interpolates between the classical and quantum limits of such a problem and show that there exists a sharp boundary separating satisfiable and unsatisfiable phases.
The dynamics and thermalization of classical systems have been extensively studied in the past. However, the corresponding quantum phenomena remain, to a large extent, uncharted territory. Recent experiments with ultracold quantum gases have at last allowed exploration of the coherent dynamics of isolated quantum systems, as well as observation of non-equilibrium phenomena that challenge our current understanding of the dynamics of quantum many-body systems. These experiments have also posed many new questions. How can we control the dynamics to engineer new states of matter? Given that quantum dynamics is unitary, under which conditions can we expect observables of the system to reach equilibrium values that can be predicted by conventional statistical mechanics? And, how do the observables dynamically approach their statistical equilibrium values? Could the approach to equilibrium be hampered if the system is trapped in long-lived metastable states characterized, for example, by a certain distribution of topological defects? How does the dynamics depend on the way the system is perturbed, such as changing, as a function of time and at a given rate, a parameter across a quantum critical point? What if, conversely, after relaxing to a steady state, the observables cannot be described by the standard equilibrium ensembles of statistical mechanics? How would they depend on the initial conditions in addition to the other properties of the system, such as the existence of conserved quantities? The search for answers to questions like these is fundamental to a new research field that is only beginning to be explored, and to which researchers with different backgrounds, such as nuclear, atomic, and condensed-matter physics, as well as quantum optics, can make, and are making, important contributions. This body of knowledge has an immediate application to experiments in the field of ultracold atomic gases, but can also fundamentally change the way we approach and understand many-body quantum systems. This focus issue of New Journal Physics brings together both experimentalists and theoreticians working on these problems to provide a comprehensive picture of the state of the field. Focus on Dynamics and Thermalization in Isolated Quantum Many-Body Systems Contents Spin squeezing of high-spin, spatially extended quantum fields Jay D Sau, Sabrina R Leslie, Marvin L Cohen and Dan M Stamper-Kurn Thermodynamic entropy of a many-body energy eigenstate J M Deutsch Ground states and dynamics of population-imbalanced Fermi condensates in one dimension Masaki Tezuka and Masahito Ueda Relaxation dynamics in the gapped XXZ spin-1/2 chain Jorn Mossel and Jean-Sébastien Caux Canonical thermalization Peter Reimann Minimally entangled typical thermal state algorithms E M Stoudenmire and Steven R White Manipulation of the dynamics of many-body systems via quantum control methods Julie Dinerman and Lea F Santos Multimode analysis of non-classical correlations in double-well Bose–Einstein condensates Andrew J Ferris and Matthew J Davis Thermalization in a quasi-one-dimensional ultracold bosonic gas I E Mazets and J Schmiedmayer Two simple systems with cold atoms: quantum chaos tests and non-equilibrium dynamics Cavan Stone, Yassine Ait El Aoud, Vladimir A Yurovsky and Maxim Olshanii On the speed of fluctuations around thermodynamic equilibrium Noah Linden, Sandu Popescu, Anthony J Short and Andreas Winter A quantum central limit theorem for non-equilibrium systems: exact local relaxation of correlated states M Cramer and J Eisert Quantum quench dynamics of the sine-Gordon model in some solvable limits A Iucci and M A Cazalilla Nonequilibrium quantum dynamics of atomic dark solitons A D Martin and J Ruostekoski Quantum quenches in the anisotropic spin-1⁄2 Heisenberg chain: different approaches to many-body dynamics far from equilibrium Peter Barmettler, Matthias Punk, Vladimir Gritsev, Eugene Demler and Ehud Altman Crossover from adiabatic to sudden interaction quenches in the Hubbard model: prethermalization and non-equilibrium dynamics Michael Moeckel and Stefan Kehrein Quantum quenches in integrable field theories Davide Fioretto and Giuseppe Mussardo Dynamical delocalization of Majorana edge states by sweeping across a quantum critical point A Bermudez, L Amico and M A Martin-Delgado Thermometry with spin-dependent lattices D McKay and B DeMarco Near-adiabatic parameter changes in correlated systems: influence of the ramp protocol on the excitation energy Martin Eckstein and Marcus Kollar Sudden change of the thermal contact between two quantum systems J Restrepo and S Camalet Reflection of a Lieb–Liniger wave packet from the hard-wall potential D Jukić and H Buljan Probing interaction-induced ferromagnetism in optical superlattices J von Stecher, E Demler, M D Lukin and A M Rey Sudden interaction quench in the quantum sine-Gordon model Javier Sabio and Stefan Kehrein Dynamics of an inhomogeneous quantum phase transition Jacek Dziarmaga and Marek M Rams
Thermalization, the evolution of an interacting many-body system towards a thermal Gibbs ensemble after initialization in an arbitrary non-equilibrium state, is currently a phenomenon of great interest, both in theory and experiment. As the time evolution of a quantum system is unitary, the proposed mechanism of thermalization in quantum many-body systems corresponds to the so-called eigenstate thermalization hypothesis (ETH) and the typicality of eigenstates. Although this formally solves the contradiction of thermalizing but unitary dynamics in a closed quantum many-body system, it does neither make any statement on the dynamical process of thermalization itself nor in which way the coupling of the system to an environment can hinder or modify the relaxation dynamics. In this thesis, we address both the question whether or not a quantum system driven away from equilibrium is able to relax to a thermal state, which fulfills detailed balance, and if one can identify universal behavior in the non-equilibrium relaxation dynamics. As a first realization of driven quantum systems out of equilibrium, we investigate a system of Ising spins, interacting with the quantized radiation field in an optical cavity. For multiple cavity modes, this system forms a highly entangled and frustrated state with infinite correlation times, known as a quantum spin glass. In the presence of drive and dissipation, introduced by coupling the intra-cavity radiation field to the photon vacuum outside the cavity via lossy mirrors, the quantum glass state is modified in a universal manner. For frequencies below the photon loss rate, the dissipation takes over and the system shows the universal behavior of a dissipative spin glass, with a characteristic spectral density
mathcalA(omega)simsqrtomega. On the other hand, for frequencies above the loss rate, the system retains the universal behavior of a zero temperature, quantum spin glass. Remarkably, at the glass transition, the two subsystems of spins and photons thermalize to a joint effective temperature, even in the presence of photon loss. This thermalization is a consequence of the strong spin-photon interactions, which favor detailed balance in the system and detain photons from escaping the cavity. In the thermalized system, the features of the spin glass are mirrored onto the photon degrees of freedom, leading to an emergent photon glass phase. Exploiting the inherent photon loss of the cavity, we make predictions of possible measurements on the escaping photons, which contain detailed information of the state inside the cavity and allow for a precise, non-destructive measurement of the glass state. As a further set of non-equilibrium systems, we consider one-dimensional quantum fluids driven out of equilibrium, whose universal low energy theory is formed by the so-called Luttinger Liquid description, which, due to its large degree of universality, is of intense theoretical and experimental interest. A set of recent experiments in research groups in Vienna, Innsbruck and Munich have probed the non-equilibrium time-evolution of one-dimensional quantum fluids for different experimental realizations and are pushing into a time regime, where thermalization is expected. From a theoretical point of view, one-dimensional quantum fluids are particular interesting, as Luttinger Liquids are integrable and therefore, due to an infinite number of constants of motion, do not thermalize. The leading order correction to the quadratic theory is irrelevant in the sense of the renormalization group and does therefore not modify static correlation functions, however, it breaks integrability and will therefore, even if irrelevant, induce a completely different non-equilibrium dynamics as the quadratic Luttinger theory alone. In this thesis, we derive for the first time a kinetic equation for interacting Luttinger Liquids, which describes the time evolution of the excitation densities for arbitrary initial states. The resonant character of the interaction makes a straightforward derivation of the kinetic equation, using Fermi\'s golden rule, impossible and we have to develop non-perturbative techniques in the Keldysh framework. We derive a closed expression for the time evolution of the excitation densities in terms of self-energies and vertex corrections. Close to equilibrium, the kinetic equation describes the exponential decay of excitations, with a decay rate
sigmaR=mboxImSigmaR, determined by the self-energy at equilibrium. However, for long times
tau, it also reveals the presence of dynamical slow modes, which are the consequence of exactly energy conserving dynamics and lead to an algebraic decay
simtau−etasubD with
etaD=0.58. The presence of these dynamical slow modes is not contained in the equilibrium Matsubara formalism, while they emerge naturally in the non-equilibrium formalism developed in this thesis. In order to initialize a one-dimensional quantum fluid out of equilibrium, we consider an interaction quench in a model of interacting, dispersive fermions in Chap.~\\ref{sec:Quench}. In this scenario, the fermionic interaction is suddenly changed at time
t=0, such that for
t>0 the system is not in an eigenstate and therefore undergoes a non-trivial time evolution. For the quadratic theory, the stationary state in the limit
trightarrowinfty is a non-thermal, or prethermal, state, described by a generalized Gibbs ensemble (GGE). The GGE takes into account for the conservation of all integrals of motion, formed by the eigenmodes of the Hamiltonian. On the other hand, in the presence of non-linearities, the final state for
trightarrowinfty is a thermal state with a finite temperature
T>0. . The spatio-temporal, dynamical thermalization process can be decomposed into three regimes: A prequench regime on the largest distances, which is determined by the initial state, a prethermal plateau for intermediate distances, which is determined by the metastable fixed point of the quadratic theory and a thermal region on the shortest distances. The latter spreads sub-ballistically
simtalpha in space with
0<alpha<1 depending on the quench. Until complete thermalization (i.e. for times
t<infty), the thermal region contains more energy than the prethermal and prequench region, which is expressed in a larger temperature
Tt>Tinfty, decreasing towards its final value
Tinfty. As the system has achieved local detailed balance in the thermalized region, energy transport to the non-thermal region can only be performed by the macroscopic dynamical slow modes and the decay of the temperature
Tt−Tinftysimt−etasubD again witnesses the presence of these slow modes. The very slow spreading of thermalization is consistent with recent experiments performed in Vienna, which observe a metastable, prethermal state after a quench and only observe the onset of thermalization on much larger time scales. As an immediate indication of thermalization, we determine the time evolution of the fermionic momentum distribution after a quench from non-interacting to interacting fermions. For this quench scenario, the step in the Fermi distribution at the Fermi momentum
ksubF decays to zero algebraically in the absence of a non-linearity but as a stretched exponential (the exponent being proportional to the non-linearity) in the presence of a finite non-linearity. This can serve as a proof for the presence or absence of the non-linearity even on time-scales for which thermalization can not yet be observed. Finally, we consider a bosonic quantum fluid, which is driven away from equilibrium by permanent heating. The origin of the heating is atomic spontaneous emission of laser photons, which are used to create a coherent lattice potential in optical lattice experiments. This process preserves the system\'s
U(1)-invariance, i.e. conserves the global particle number, and the corresponding long-wavelength description is a heated, interacting Luttinger Liquid, for which phonon modes are continuously populated with a momentum dependent rate
partialtnqsimgamma∣q∣. In the dynamics, we identify a quasi-thermal regime for large momenta, featuring an increasing time-dependent effective temperature. In this regime, due to fast phonon-phonon scattering, detailed balance has been achieved and is expressed by a time-local, increasing temperature. The thermal region emerges locally and spreads in space sub-ballistically according to
xtsimt4/5. For larger distances, the system is described by an non-equilibrium phonon distribution
nqsim∣q∣, which leads to a new, non-equilibrium behavior of large distance observables. For instance, the phonon decay rate scales universally as
gammaqsim∣q∣5/3, with a new non-equilibrium exponent
eta=5/3, which differs from equilibrium. This new, universal behavior is guaranteed by the
U(1) invariant dynamics of the system and is insensitive to further subleading perturbations. The non-equilibrium long-distance behavior can be determined experimentally by measuring the static and dynamic structure factor, both of which clearly indicate the exponents for phonon decay,
eta=5/3 and for the spreading of thermalization
etaT=4/5. Remarkably, even in the presence of this strong external drive, the interactions and their aim to achieve detailed balance are strong enough to establish a locally emerging and spatially spreading thermal region. The physical setups in this thesis do not only reveal interesting and new dynamical features in the out-of-equilibrium time evolution of interacting systems, but they also strongly underline the high degree of universality of thermalization for the classes of models studied here. May it be a system of coupled spins and photons, where the photons are pulled away from a thermal state by Markovian photon d
One of the distinguishing achievements of physics has been the ability to describe the Universe based upon underlying microscopic principles. When there are many participating objects being governed by these microscopic principles, the resultant behavior often harbors emergent collective phenomena that may not be obviously related to the microscopic description. Phase transitions, quantum or classical, are a canonical example of such many-body phenomena that are understood in equilibrium through a framework of thermodynamic constraints, statistical ensembles, and a growth of system-wide correlations at the transition. However, a new class of quantum phase transitions has recently emerged for non-equilibrium systems with behavior that is not captured by this traditional framework. In the case of isolated quantum systems, these transitions occur among excited eigenstates and requires knowledge of the structure of these individual eigenstates in the quantum system. Understanding what drives such a phase transition requires a deeper microscopic knowledge of the role of correlations at the transition. \nThe use of ultracold atoms in optical lattices has paved the way for faithfully realizing quantum phase transitions. In particular, the advent of the quantum gas microscope realized an experimental platform that is highly controllable and provides microscopic access to the many-bodied wave functions. All experiments presented in this thesis use such a quantum gas microscope architecture where a quantum degenerate gas of Rb is used to probe the behavior of non-equilibrium quantum systems in one spatial dimension.\nThis thesis briefly discusses some studies of entanglement in equilibrium quantum phase transitions near the ground state of the system. In the first experiment, we directly measure the second-order R\\'enyi entanglement entropy that develops as a Bose-Hubbard system transitions from a Mott insulator to a superfluid. This is followed by a study of entanglement growth at the transition in the transverse Ising model. \nThese studies progress to the investigation of two particular non-equilibrium quantum phases and their transition into one another: quantum thermalization and many-body localization. We investigate the development of entanglement entropy that mimics thermodynamic entropy for an isolated quantum system which locally thermalizes under its own unitary dynamics. We then investigate the only known robust exception to this thermalizing behavior by studying the onset of many-body localization due to disorder. We observe the breakdown of thermalization in this phase and the logarithmically slow growth of entanglement throughout the system, which identifies the localized system to be an interacting one. Lastly, we investigate the role of correlations in the critical dynamics that emerge at high-orders where the system transitions from thermalizing behavior to many-body localization.