Experimental Demonstration of Quantum Effects in the Operation of Microscopic Heat Engines
James Klatzow, Jonas N. Becker, Patrick M. Ledingham, Christian Weinzetl, K. T. Kaczmarek, D. J. Saunders, Joshua Nunn, Ian A. Walmsley, Raam Uzdin, Eilon Poem
The ability of the internal states of a working fluid to be in a coherent superposition is one of the basic properties of a quantum heat engine. It was recently predicted that in the regime of small engine action, this ability can enable a quantum heat engine to produce more power than any equivalent classical heat engine. It was also predicted that in the same regime, the presence of such internal coherence causes different types of quantum heat engines to become thermodynamically equivalent. Here, we use an ensemble of nitrogen vacancy centers in diamond for implementing two types of quantum heat engines, and experimentally observe both effects.
The ability of the internal states of a working fluid to be in a coherent superposition is one of the basic properties of a quantum heat engine. It was recently predicted that in the regime of small engine action, this ability can enable a quantum heat engine to produce more power than any equivalent classical heat engine. It was also predicted that in the same regime, the presence of such internal coherence causes different types of quantum heat engines to become thermodynamically equivalent. Here, we use an ensemble of nitrogen vacancy centers in diamond for implementing two types of quantum heat engines, and experimentally observe both effects.
Quantum heat engines (QHE) are thermal machines where the working substance is quantum. In the extreme case the working medium can be a single particle or a few level quantum system. The study of QHE has shown a remarkable similarity with the standard thermodynamical models, thus raising the issue what is quantum in quantum thermodynamics. Our main result is thermodynamical equivalence of all engine type in the quantum regime of small action. They have the same power, the same heat, the same efficiency, and they even have the same relaxation rates and relaxation modes. Furthermore, it is shown that QHE have quantum-thermodynamic signature, i.e thermodynamic measurements can confirm the presence of quantum coherence in the device. The coherent work extraction mechanism enables power outputs that greatly exceed the power of stochastic (dephased) engines.
Quantum heat engines provide attractive means in quantum thermodynamics for studying the fundamentals of the flow of heat and work. Previous experimental implementations of heat engines operating at the level of a few excitation quanta have utilized external driving, which has made the observation of the produced work challenging. Conversely, autonomous quantum heat engines only require a flow of heat to operate and generate work. However, autonomous quantum heat engines have not yet been experimentally demonstrated in any system despite numerous theoretical investigations. Here, we experimentally realize an autonomous quantum heat engine based on superconducting circuits. We construct the engine circuit implementing an approximate Otto cycle by coupling two superconducting resonators with a superconducting quantum interference device, and coupling this system to spectrally filtered hot and cold reservoirs. By varying the experimental conditions, we observe coherent microwave power generation arising from the internal dynamics of the system driven only by the thermal reservoirs. Our results validate previous theoretical predictions for this circuit and pave the way for detailed studies of quantum effects in heat engines and for using heat-generated coherent microwaves in circuit quantum electrodynamics.
Recent predictions for quantum-mechanical enhancements in the operation of small heat engines have raised renewed interest in their study both from a fundamental perspective and in view of applications. One essential question is whether collective effects may help to carry enhancements over larger scales, when increasing the number of systems composing the working substance of the engine. Such enhancements may consider not only power and efficiency, that is, its performance, but, additionally, its constancy, that is, the stability of the engine with respect to unavoidable environmental fluctuations. We explore this issue by introducing a many-body quantum heat engine model composed by spin pairs working in continuous operation. We study how power, efficiency, and constancy scale with the number of spins composing the engine and introduce a well-defined macroscopic limit where analytical expressions are obtained. Our results predict power enhancements, in both finite-size and macroscopic cases, for a broad range of system parameters and temperatures, without compromising the engine efficiency, accompanied by coherence-enhanced constancy for finite sizes. We discuss these quantities in connection to thermodynamic uncertainty relations.
Conventional heat engines convert thermal energy into mechanical work by using a working medium such as steam or gas that operates between a hot and a cold reservoir. The medium absorbs heat from the hot reservoir, produces work, then releases some heat to the cold reservoir and returns to the initial state. With the advancement of quantum technologies, researchers strive to understand whether quantum media, such as atoms, spins, superconducting circuits and semiconductor quantum dots, can be used in quantum counterparts of the classical heat engines. After a recap of the basics of classical heat engines, this review explores the theoretical foundations and advancements of quantum heat engines, focusing on the proposed two- and multilevel systems used as the working medium for the quantum Otto cycle, which is the ideal thermodynamic cycle that describes the operation of a spark-ignition internal combustion engine. The review compares the efficiency and the work extraction of these systems, discussing their performance in the high- and low-temperature limits. Alternative cycles and engines are also presented to establish the adaptability of the working media when operating under different processes and non-equilibrium conditions. In conclusion, the review offers possible applications and future developments of quantum heat engines.
Modern technologies could soon make it possible to investigate the operation cycles of quantum heat engines by counting the photons that are emitted and absorbed by their working systems.Using the quantum jump approach to open-system dynamics, we show that such experiments would give access to a set of observables that determine the trade-off between power and efficiency in finite-time engine cycles.By analyzing the single-jump statistics of thermodynamic fluxes such as heat and entropy production, we obtain a family of general bounds on the power of microscopic heat engines.Our new bounds unify two earlier results and admit a transparent physical interpretation in terms of single-photon measurements.In addition, these bounds confirm that driving-induced coherence leads to an increase in dissipation that suppresses the efficiency of slowly driven quantum engines in the weak-coupling regime.A nanoscale heat engine based on a superconducting qubit serves as an experimentally relevant example and a guiding paradigm for the development of our theory.
We investigate, in an analytical fashion, quantum Carnot cycles of a microscopic heat engine coupled to two nite heat reservoirs, whose internal cycles could own higher e ciency than the standard Carnot limit without consuming extra quantum resources, e.g., coherence or squeezing properties. The engine runs time-dependently, involving both the internal and external cycles to collaboratively accomplish a complete Carnot cycle, and the e ciency of the engine depends on the reservoirs heat capacities and the working substance. Our analytical results of the maximum efficiency and the maximum power output clarify the mechanism behind the high performance of the microscopic engines, displaying the key roles played by the nite-sized heat reservoirs. Our proposal is generally valid for any microscopic thermodynamic system and fully feasible under current laboratory conditions.