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arXiv:1708.07096 · Physical Review A

Entropy of the Bose-Einstein-condensate ground state: Correlation versus ground-state entropy

Moochan B. Kim, Anatoly A. Svidzinsky, G. S. Agarwal, Marlan O. Scully

Published Jan 5, 2018• 8 citations
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Abstract

Calculation of the entropy of an ideal Bose-Einstein condensate (BEC) in a three-dimensional trap reveals unusual, previously unrecognized, features of the canonical ensemble. It is found that, for any temperature, the entropy of the Bose gas is equal to the entropy of the excited particles although the entropy of the particles in the ground state is nonzero. We explain this by considering the correlations between the ground-state particles and particles in the excited states. These correlations lead to a correlation entropy which is exactly equal to the contribution from the ground state. The correlations themselves arise from the fact that we have a fixed number of particles obeying quantum statistics. We present results for correlation functions between the ground and excited states in a Bose gas, so as to clarify the role of fluctuations in the system. We also report the sub-Poissonian nature of the ground-state fluctuations.

DOI
10.1103/physreva.97.013605

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Mesoscopic Effects in Bose-Einstein Condensate Fluctuations of an Ideal Gas in a Box

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The mesoscopic effects in the quantum trapped gases of the Bose atoms constitute\nthe main subject of the present thesis. These effects are the most difficult for\nthe theoretical analysis in the quantum statistical physics since they can’t be seen by\nneither a standard quantum mechanics of the simple microscopic systems of one or\nvery few atoms nor a standard statistical physics of the macroscopic systems that are\ninfinite in the bulk (thermodynamic) limit.\nMost of the experiments on the cold quantum gases performed in the last decade,\nstarting from the first demonstration of BEC in 1995, involve the mesoscopic systems\nof a finite number of atoms. The mesoscopic effects should manifest themselves most\nclearly and easily near a critical temperature of BEC; however, they could be observed\nalso above and below the critical temperature.\nHere I study the quantum and thermal fluctuations of the Bose-Einstein condensate\n(BEC) in a box with the periodic boundary conditions under a particle-number\nconstraint. The above constraint is the only reason for the BEC and is crucial for the\nmesoscopic effects in the BEC fluctuations, especially in the vicinity of the critical\ntemperature in the Bose gas.\nI employ the particle-number conserving operator formalism of Girardeau and\nArnowitt introduced in 1959 to analyze the canonical ensemble fluctuations. I present\nanalytical formulas and numerical calculations for the central moments of the ground\nstate occupation fluctuations in an ideal Bose gas in a box with a mesoscopic number of particles.\nI present the analysis of the BEC statistics both on a temperature at a fixed\nnumber of particles and on a number of particles at a fixed temperature. Both analyses\nare valid for the purpose of understanding the important mesoscopic effects near the\ncritical temperature. I emphasize the non-Gaussian nature of the fluctuations.\nThe presented formalism can be generalized to the case of a weakly interacting\nBose gas in a box in the framework of the Bogoliubov approximation. The work in\nthis direction is in progress but is not included in the present thesis.

•May 15, 2009•0 citations
Calculation of the entropy of an ideal Bose-Einstein condensate (BEC) in a three-dimensional trap reveals unusual, previously unrecognized, features of the canonical ensemble. It is found that, for any temperature, the entropy of the Bose gas is equal to the entropy of the excited particles although the entropy of the particles in the ground state is nonzero. We explain this by considering the correlations between the ground-state particles and particles in the excited states. These correlations lead to a correlation entropy which is exactly equal to the contribution from the ground state. The correlations themselves arise from the fact that we have a fixed number of particles obeying quantum statistics. We present results for correlation functions between the ground and excited states in a Bose gas, so as to clarify the role of fluctuations in the system. We also report the sub-Poissonian nature of the ground-state fluctuations.
Constraint of a fixed total number of particles yields a correlation between the fluctuation of particles in different states in the canonical ensemble. Here we show that, below the temperature of Bose–Einstein condensation (BEC), the correlation part of the entropy of an ideal Bose gas is cancelled by the ground-state contribution. Thus, in the BEC region, the thermodynamic properties of the gas in the canonical ensemble can be described accurately in a simplified model which excludes the ground state and assumes no correlation between excited levels.
We consider equilibrium canonical-ensemble fluctuations of the Bose-Einstein condensate (BEC) in a trap using the particle-number conserving operator formalism of Girardeau and Arnowitt [Phys. Rev. 113, 755 (1959)] and the concept of the canonical-ensemble quasiparticles. We find explicit expressions for the characteristic function and all cumulants of the ground-state occupation statistics both for the dilute weakly interacting and ideal Bose gases. We present analytical formulas for the moments of the ground-state occupation fluctuations in the weakly interacting and ideal Bose gases in a box (``homogeneous gas'') as well as in the ideal Bose gas in an arbitrary power-law trap, in particular, in an arbitrary harmonic trap. We calculate the effect of Bogoliubov coupling between quasiparticles on suppression of the ground-state occupation fluctuations at moderate temperatures and their enhancement at very low temperatures. We clarify a crossover between ideal-gas and weakly interacting gas statistics, which is governed by a pair-correlation, squeezing mechanism. The important conclusion is that in most cases the ground-state occupation fluctuations are anomalously large and are not Gaussian even in the thermodynamic limit.
We question the validity of the grand canonical ensemble for the description of Bose-Einstein condensation of small ideal Bose gas samples in isolated harmonic traps. While the ground state fraction and the specific heat capacity can be well approximated with the help of the conventional grand canonical arguments, the calculation of the fluctuation of the number of particles contained in the condensate requires a microcanonical approach. Resorting to the theory of restricted partitions of integer numbers, we present analytical and numerical results for such fluctuations in one- and three-dimensional traps, and show that their magnitude is essentially independent of the total particle number.
This paper presents a study of the grand canonical Bose-Einstein (BE) statistics for a finite number of particles in an arbitrary quantum system. The thermodynamical quantities that identify BE condensation---namely, the fraction of particles in the ground state and the specific heat---are calculated here exactly in terms of temperature and fugacity. These calculations are complemented by a numerical calculation of fugacity in terms of the number of particles, without taking the thermodynamic limit. The main advantage of this approach is that it does not rely on approximations made in the vicinity of the usually defined critical temperature, rather it makes calculations with arbitrary precision possible, irrespective of temperature. Graphs for the calculated thermodynamical quantities are presented in comparison to the results previously obtained in the thermodynamic limit. In particular, it is observed that for the gas trapped in a three-dimensional box, the derivative of specific heat reaches smaller values than what was expected in the thermodynamic limit---here, this result is also verified with analytical calculations. This is an important result for understanding the role of the thermodynamic limit in phase transitions and makes possible to further study BE statistics without relying neither on the thermodynamic limit nor on approximations near critical temperature.
The calculation of the thermodynamic properties in the Bose-Einstein distribution is presented.The behaviour of the Bose-gas in the Bose-Einstein distribution is analysed based on high and low temperature dependence.At > all particles are in the excited state and the ground state is essentially occupied.But at B T T < particles gradually falls to the ground state and eventually contains all the particles in the system as .0 → TThe analytical expressions for some important parameters such as Bose-Einstein condensation of an ideal Bose gas, the population density of the excited and ground state particles are also presented.Heart capacity of an ideal Bose gas and total internal energy are also calculated and the results presented graphically.The results obtained are consistent with those found in the literatures.
The mesoscopic effects in the quantum trapped gases of the Bose atoms constitute\nthe main subject of the present thesis. These effects are the most difficult for\nthe theoretical analysis in the quantum statistical physics since they can’t be seen by\nneither a standard quantum mechanics of the simple microscopic systems of one or\nvery few atoms nor a standard statistical physics of the macroscopic systems that are\ninfinite in the bulk (thermodynamic) limit.\nMost of the experiments on the cold quantum gases performed in the last decade,\nstarting from the first demonstration of BEC in 1995, involve the mesoscopic systems\nof a finite number of atoms. The mesoscopic effects should manifest themselves most\nclearly and easily near a critical temperature of BEC; however, they could be observed\nalso above and below the critical temperature.\nHere I study the quantum and thermal fluctuations of the Bose-Einstein condensate\n(BEC) in a box with the periodic boundary conditions under a particle-number\nconstraint. The above constraint is the only reason for the BEC and is crucial for the\nmesoscopic effects in the BEC fluctuations, especially in the vicinity of the critical\ntemperature in the Bose gas.\nI employ the particle-number conserving operator formalism of Girardeau and\nArnowitt introduced in 1959 to analyze the canonical ensemble fluctuations. I present\nanalytical formulas and numerical calculations for the central moments of the ground\nstate occupation fluctuations in an ideal Bose gas in a box with a mesoscopic number of particles.\nI present the analysis of the BEC statistics both on a temperature at a fixed\nnumber of particles and on a number of particles at a fixed temperature. Both analyses\nare valid for the purpose of understanding the important mesoscopic effects near the\ncritical temperature. I emphasize the non-Gaussian nature of the fluctuations.\nThe presented formalism can be generalized to the case of a weakly interacting\nBose gas in a box in the framework of the Bogoliubov approximation. The work in\nthis direction is in progress but is not included in the present thesis.