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arXiv:1706.02636

How isolated is enough for an "isolated" system in statistical mechanics?

Hui Liang Dong, Da‐Wei Wang, M.B. Kim

Published Jun 8, 2017• 2 citations
arXivHTMLPDF

Abstract

Irreversible processes are frequently adopted to account for the entropy increase in classical thermodynamics. However, the corresponding physical origins are not always clear, e.g. in a free expansion process, a typical model in textbooks. In this letter, we study the entropy change during free expansion for a particle with the thermal de Broglie wavelength ($λ_{T}$) in a one-dimensional square trap with size $L$. By solely including quantum dephasing as an irreversible process, we recover classical result of entropy increase in the classical region ($L\ggλ_{T}$), while predict prominent discrepancies in the quantum region ($L\llλ_{T}$) because of non-equilibrium feature of trapped atoms after expansion. It is interesting to notice that the dephasing, though absent in classical system, is critical to clarify mysteries in classical thermodynamics.

DOI
10.48550/arxiv.1706.02636

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Irreversible processes are frequently adopted to account for the entropy increase in classical thermodynamics. However, the corresponding physical origins are not always clear, e.g. in a free expansion process, a typical model in textbooks. In this letter, we study the entropy change during free expansion for a particle with the thermal de Broglie wavelength (λTλ_{T}λT​) in a one-dimensional square trap with size LLL. By solely including quantum dephasing as an irreversible process, we recover classical result of entropy increase in the classical region (L≫λTL\ggλ_{T}L≫λT​), while predict prominent discrepancies in the quantum region (L≪λTL\llλ_{T}L≪λT​) because of non-equilibrium feature of trapped atoms after expansion. It is interesting to notice that the dephasing, though absent in classical system, is critical to clarify mysteries in classical thermodynamics.
The irreversible entropy increase described by the second law of thermodynamics is fundamentally tied to thermalization and the emergence of equilibrium. In the first part of our work (Ref: arXiv.2503.04152), we constructed an isolated gas system model and numerically demonstrated irreversible growth of entanglement entropy caused by erasure of spread non-equilibrium state information. Here, we mathematically prove that for a typical macroscopic system in a non-equilibrium state ∣ϕ0⟩|ϕ_0\rangle∣ϕ0​⟩, the quantum state ∣ϕ0′⟩=O^(t)∣ϕ0⟩|ϕ'_0\rangle = \hat{O}(t)|ϕ_0\rangle∣ϕ0′​⟩=O^(t)∣ϕ0​⟩ will inevitably evolve toward equilibrium. Our work demonstrates that the second law of thermodynamics, and consequently the ergodic hypothesis in statistical physics, can be understood and proven from a quantum information perspective. From this perspective, the second law can be stated as: In typical macroscopic physical systems, the spreading and erasure of non-equilibrium information is inevitable.
The law of increase of entropy is one of the most important laws in science but no exact explanation has been given to the origin of it. Statistical thermodynamics only explains it by using Boltzmann’s statistical interpretation together with not sufficiently verified assumptions. This paper shows that the increase of entropy in an isolated macroscopic system can be reasonably explained with no assumption based on quantum mechanics if we take into account that microscopic particles such as electrons and atomic nuclei not only move in space but also have the basic quality of spontaneously spreading into every possible spatial position. The present work allows us to give a plausible definition to the entropy of an isolated system by using the Hamiltonian operator and a wave function of it and provides a firm basis for thermodynamics. It also gives a new physical meaning of entropy effective for further studies of irreversible processes in nature.
Thermodynamics is a phenomenological theory describing the energy conversion of work and heat. At its origins thermodynamics was developed in order to understand and improve heat engines. In conventional thermodynamics, however, only such processes are completely describable which are slow enough to keep the system of interest in an equilibrium state with its thermal environment at all times. On the contrary, all real physical processes are accompanied by non-equilibrium phenomena. These are mathematically described with the help of the irreversible entropy production, i.e. the dissipated work divided by the temperature of the bath. The second law of thermodynamics merely states that the irreversible entropy production is on average always positive. The modern trend of miniaturization, however, leads to smaller and smaller devices. On short length scales thermal noise as well as quantum fluctuations become important. Thus, usual thermodynamic quantities as work and heat acquire stochastic nature. Moreover, in the quantum regime a completely new theory had to be invented, since classical notions of work and heat are no longer valid. The present dissertation contributes to this prevailing field by the derivation of analytical expressions for the entropy production in open and closed quantum system far from thermal equilibrium. The theoretical treatment is motivated by an experimental point of view. The obtained results were derived from the reduced dynamics of the quantum mechanical system, which may be coupled to a thermal bath. To this end, it was dealt with methods and approaches of statistical physics, conventional thermodynamics, quantum information theory and the theory of open quantum systems. In this dissertation the most important physical systems are treated. First, an isolated system is considered before later on a heat bath is included. The limit of weak as well as of strong coupling are analyzed in detail. For isolated systems it turns out that a geometric approach is able to capture the thermodynamic properties, completely. To this end, the irreversible entropy production is sharply estimated from below by the angle between the real non-equilibrium state and the corresponding equilibrium one. Further, it is shown that the Heisenberg uncertainty relation for energy and time can be formulated more precisely in terms of that angle. As experimental system cold ion traps are introduced, in which the theoretical predictions can be verified. For weakly coupled systems, then, the irreversible entropy production is identified and a fluctuation theorem is derived by merely thermodynamic arguments. As experimental system we, again, propose the cold ion traps, where the heat bath can be simulated with the help of LASER light. In the limit of strong coupling a semiclassical description of the reduced quantum system is discussed. Again, an analytically exact expression for the entropy production and the corresponding fluctuation theorem is derived. A physical system, in which strong coupling to the environment can be analyzed, is given by Josephson junctions. This dissertation discusses the entropy production for isolated, weakly coupled, and overdamped quantum systems. For these physical regimes analytical relation are derived and experimental systems proposed, with which the predictions can be verified.
The irreversibility and thermalization of many-body systems can be attributed to the erasure of spread non-equilibrium state information by local operations. This thermalization mechanism can be demonstrated by the sequence of O^i(ti)\hat{O}_i(t_i)O^i​(ti​), where Oi^\hat{O_i}Oi​^​ is a local operator, Oi^(ti)=eiH^tiOi^e−iH^ti\hat{O_i}(t_i) = e^{i\hat{H}t_i} \hat{O_i} e^{-i\hat{H}t_i}Oi​^​(ti​)=eiH^ti​Oi​^​e−iH^ti​, H^\hat{H}H^ is the system Hamiltonian, tit_iti​ can take positive, negative, or zero values, and the sequence is arranged according to the subscript iii. We numerically demonstrate the information erasure of initial non-equilibrium quantum states through such sequence in a one-dimensional Hubbard model. During this process, the system's entanglement entropy increases monotonically toward a stable value. By incorporating this information erasure mechanism into an isolated system, our numerical simulations reveal that in this completely isolated system, a thermalization process emerges.
The second law of thermodynamics states that the entropy of an isolated system can only increase over time. This appears to conflict with the reversible evolution of isolated quantum systems under the Schrödinger equation, which preserves the von Neumann entropy. Nonetheless, one finds that with respect to many observables, expectation values approach a fixed value—their equilibrium value. This ultimately raises the question: ? For classical systems, one introduces the assumption of a low-entropy initial state along with the concept of ignorance about the microscopic details of the physical system, leading to a statistical interpretation of the second law. By considering the observables through which we examine quantum systems, both these assumptions can be incorporated, building upon recent studies of the of observables. While the statistical behavior of observable expectation values is well established, a quantitative connection to entropy increase has been lacking so far. In deriving novel bounds for the equilibration of observables, and considering the entropy of the system relative to observables, we recover a variant of the second law: the entropy with respect to a given observable tends toward its equilibrium value in the course of the system’s unitary evolution. These results also support recent findings that question the necessity of nonintegrability for equilibration in quantum systems. We further illustrate our bounds using numerical results from the paradigmatic example of a quantum Ising model on a chain of spins. There, we observe entropy increasing up to equilibrium values, as well as fluctuations, which expose the underlying reversible evolution in accordance with the derived bounds.
The problem of time’s arrow is (roughly) to understand why macroscopic physical processes typically evolve in a specific direction (the one we call “the future”) even though the underlying laws of physics describing the individual microscopic systems are time-reversal invariant. The standard answer to this problem is given by Boltzmann’s explanation of the II law of thermodynamics: a classical system starting in a non-equilibrium state spontaneously (i.e. with a high level of probability) tends towards equilibrium, thus implementing an irreversible process. However, this explanation has two drawbacks: 1. it needs a further assumption on the entropy of the initial state of the universe (past hypothesis); 2. microscopic systems (e.g. molecules in a box) should be represented as quantum states and not classical states. In this talk, I want to propose a different hypothesis to explain the origin of time’s arrow, based on quantum mechanics, specifically on decoherence theory. Differently from isolated systems, open quantum systems described by decoherence theory showirreversible behavior, as they evolve towards decoherence and von Neumann entropy increase. Is this behavior a sign of genuine irreversibility? And, if so, can this be linked to thermodynamic irreversibility?