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arXiv:1705.10288 · Physical Review Letters

Radio Frequency Magneto-Optical Trapping of CaF with High Density

Loïc Anderegg, Benjamin L. Augenbraun, Eunmi Chae, Boerge Hemmerling, Nicholas R. Hutzler, Aakash Ravi, Alejandra Collopy, Jun Ye, Wolfgang Ketterle, John M. Doyle

Published Sep 6, 2017• 243 citations
arXivHTMLPDF

Abstract

We demonstrate significantly improved magneto-optical trapping of molecules using a very slow cryogenic beam source and either rf modulated or dc magnetic fields. The rf magneto-optical trap (MOT) confines 1.0(3)×10^{5} CaF molecules at a density of 7(3)×10^{6} cm^{-3}, which is an order of magnitude greater than previous molecular MOTs. Near Doppler-limited temperatures of 340(20) μK are attained. The achieved density enables future work to directly load optical tweezers and create optical arrays for quantum simulation.

DOI
10.1103/physrevlett.119.103201

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ChemPhysChem•Nov 8, 2016•46 citations
We demonstrate significantly improved magneto-optical trapping of molecules using a very slow cryogenic beam source and either rf modulated or dc magnetic fields. The rf magneto-optical trap (MOT) confines 1.0(3)×10^{5} CaF molecules at a density of 7(3)×10^{6} cm^{-3}, which is an order of magnitude greater than previous molecular MOTs. Near Doppler-limited temperatures of 340(20) μK are attained. The achieved density enables future work to directly load optical tweezers and create optical arrays for quantum simulation.
A key method to produce trapped and laser-cooled molecules is the magneto-optical trap (MOT), which is conventionally created using light red detuned from an optical transition. In this work, we report a MOT for CaF molecules created using blue-detuned light. The blue-detuned MOT (BDM) achieves temperatures well below the Doppler limit and provides the highest densities and phase-space densities reported to date in CaF MOTs. Our results suggest that BDMs are likely achievable in many relatively light molecules including polyatomic ones, but our measurements suggest that BDMs will be challenging to realize in substantially heavier molecules due to sub-mK trap depths. In addition to record temperatures and densities, we find that the BDM substantially simplifies and enhances the loading of molecules into optical tweezer arrays, which are a promising platform for quantum simulation and quantum information processing. Notably, the BDM reduces molecular number requirements ninefold compared to a conventional red-detuned MOT, while not requiring additional hardware. Our work therefore substantially simplifies preparing large-scale molecular tweezer arrays, which are a novel platform for simulation of quantum many-body dynamics and quantum information processing with molecular qubits.
Direct laser cooling and trapping of molecules to temperature below the Doppler limit and density exceeding 108{10}^{8}108 are challenging due to the sub-Doppler heating effects of a molecular magneto-optical trap (MOT). In our previous paper [S. Xu et al., Phys. Rev. Res. 4, L042036 (2022)], we presented a general approach to engineering the sub-Doppler force by tuning the AC Stark shift with the addition of a blue-detuned laser. Here, by employing the Bayesian optimization method to optical Bloch equations, we have identified multiple blue-detuned MOT schemes for the CaF molecule. From the three-dimensional Monte Carlo simulation, we obtained a MOT temperature and density of 14 $\textmu{}\mathrm{K}$ and $4.5\ifmmode\times\else\texttimes\fi{}{10}^{8} {\mathrm{cm}}^{\ensuremath{-}3}$, respectively. Our findings present a potential avenue for directly loading molecular MOTs into conservative traps, which can capitalize on the high density and low temperature of the MOTs.
Laser cooling and trapping in a magneto-optical trap (MOT) have been essential to the success of cold atom physics in the last decades. Recently, the application of the same techniques to molecules has begun. The complexity of even a simple diatomic molecule makes laser cooling difficult, but promises new applications in many areas of research. In this thesis I describe the development of the first three-dimensional MOT of calcium fluoride (CaF) molecules. First, a cryogenic buffer gas source was set up, producing a pulsed beam of 9.3*10^10 molecules per steradian per pulse with forward velocities around 170 m/s. A similar source for very large molecules was set up during a 5 month internship at the University of Vienna. Next, the molecular pulse was slowed down to the capture velocity of a MOT using chirped laser slowing, resulting in about 7*10^5 CaF molecules passing through the typical MOT volume of 1 cm^3 at velocities of 15+-5 m/s. A new deceleration method, called Zeeman-Sisyphus deceleration, was also investigated. In this method molecules move through a spatially varying magnetic field and are optically pumped between low- and high-field seeking states in such as a way that they are always losing kinetic energy. The method promises to deliver more slow molecules because the molecules are guided transversely as they are decelerated. A small prototype was built and the optical pumping step was tested successfully. Finally, 7.6*10^3 CaF molecules were trapped in a MOT and cooled to a temperature of 8.5 mK. The radial trap frequency is 2 pi*130 Hz and the damping constant is beta=9.5*10^2 s^-1. The lifetime is about 100 ms and depends strongly on the scattering rate. This MOT is an an ideal starting point for a wide range of new experiments with ultracold molecules.
Molecular magneto-optical traps (MOTs) typically capture orders of magnitude fewer particles than their atomic counterparts due in part to their significantly lower capture velocities. Here, we employ a Stochastic Schrödinger Equation Monte Carlo approach to model a CaF DC MOT to understand the factors limiting capture velocity. We provide physical intuition into the mechanisms that affect capture velocity and identify important parameters and general strategies to improve it. In addition, we point out a loss mechanism intrinsic to molecular MOTs and determine parameter regimes that should be avoided experimentally. We benchmark our simulations against a CaF DC MOT and experimentally implement the improvements predicted by our model. In doing so, we demonstrate a molecular MOT with 1.5 million trapped molecules. This represents an eight-fold improvement and is an important step toward achieving quantum degeneracy with laser cooled molecules.
Abstract We report the production of ultracold, trapped strontium monofluoride (SrF) molecules with number density and phase‐space density significantly higher than previously achieved. These improvements are enabled by three distinct changes to our recently‐demonstrated scheme for radio‐frequency magneto‐optical trapping of SrF: modification of the slowing laser beam geometry, addition of an optical pumping laser, and incorporation of a compression stage to the magneto‐optical trap. With these improvements, we observe a trapped sample of SrF molecules at density 2.5×105 cm−3 and phase‐space density 6×10−14, each a factor of 4 greater than in previous work. Under different experimental conditions, we observe trapping of up to 104 molecules, a factor of 5 greater than in previous work. Finally, by reducing the intensity of the applied trapping light, we observe molecular temperatures as low as 250 μK.