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arXiv:1611.01150 · Physical Review Letters

Generalized Master Equations Leading to Completely Positive Dynamics

Bassano Vacchini

Published Nov 30, 2016• 74 citations
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Abstract

We provide a general construction of quantum generalized master equations with a memory kernel leading to well-defined, that is, completely positive and trace-preserving, time evolutions. The approach builds on an operator generalization of memory kernels appearing in the description of non-Markovian classical processes and puts into evidence the nonuniqueness of the relationship arising due to the typical quantum issue of operator ordering. The approach provides a physical interpretation of the structure of the kernels, and its connection with the classical viewpoint allows for a trajectory description of the dynamics. Previous apparently unrelated results are now connected in a unified framework, which further allows us to phenomenologically construct a large class of non-Markovian evolutions taking as the starting point collections of time-dependent maps and instantaneous transformations describing the microscopic interaction dynamics.

DOI
10.1103/physrevlett.117.230401

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We provide a general construction of quantum generalized master equations with a memory kernel leading to well-defined, that is, completely positive and trace-preserving, time evolutions. The approach builds on an operator generalization of memory kernels appearing in the description of non-Markovian classical processes and puts into evidence the nonuniqueness of the relationship arising due to the typical quantum issue of operator ordering. The approach provides a physical interpretation of the structure of the kernels, and its connection with the classical viewpoint allows for a trajectory description of the dynamics. Previous apparently unrelated results are now connected in a unified framework, which further allows us to phenomenologically construct a large class of non-Markovian evolutions taking as the starting point collections of time-dependent maps and instantaneous transformations describing the microscopic interaction dynamics.
We derive sufficient conditions for the memory-kernel governing nonlocal master equation which guarantee a legitimate (completely positive and trace-preserving) dynamical map. It turns out that these conditions provide natural parametrizations of the dynamical map being a generalization of the Markovian semigroup. This parametrization is defined by the so-called legitimate pair---monotonic quantum operation and completely positive map---and it is shown that such a class of maps covers almost all known examples from the Markovian semigroup, the semi-Markov evolution, up to collision models and their generalization.
We point to the connection between a recently introduced class of non-Markovian master equations and the general structure of quantum collisional models. The basic construction relies on three basic ingredients: a collection of time dependent completely positive maps, a completely positive trace preserving transformation and a waiting time distribution characterizing a renewal process. The relationship between this construction and a Lindblad dynamics is clarified by expressing the solution of a Lindblad master equation in terms of demixtures over different stochastic trajectories for the statistical operator weighted by suitable probabilities on the trajectory space.
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