Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

arXiv:1606.05532 · New Journal of Physics

Surpassing the Carnot efficiency by extracting imperfect work

Nelly Huei Ying Ng, Mischa P. Woods, Stephanie Wehner

Published Sep 15, 2017• 32 citations
arXivHTMLPDF

Abstract

A suitable way of quantifying work for microscopic quantum systems has been constantly debated in the field of quantum thermodynamics. One natural approach is to measure the average increase in energy of an ancillary system, called the battery, after a work extraction protocol. The quality of energy extracted is usually argued to be good by quantifying higher moments of the energy distribution, or by restricting the amount of entropy to be low. This limits the amount of heat contribution to the energy extracted, but does not completely prevent it. We show that the definition of 'work' is crucial. If one allows for a definition of work that tolerates a non-negligible entropy increase in the battery, then a small scale heat engine can possibly exceed the Carnot efficiency. This can be done without using any additional resources such as coherence or correlations, and furthermore can be achieved even when one of the heat baths is finite in size.

DOI
10.1088/1367-2630/aa8ced

Related papers

Attaining Carnot efficiency with quantum and nanoscale heat engines

Mohit Lal Bera, Maciej Lewenstein, Manabendra Nath Bera

Abstract A heat engine operating in the one-shot finite-size regime, where systems composed of a small number of quantum particles interact with hot and cold baths and are restricted to one-shot measurements, delivers fluctuating work. Further, engines with lesser fluctuation produce a lesser amount of deterministic work. Hence, the heat-to-work conversion efficiency stays well below the Carnot efficiency. Here we overcome this limitation and attain Carnot efficiency in the one-shot finite-size regime, where the engines allow the working systems to simultaneously interact with two baths via the semi-local thermal operations and reversibly operate in a one-step cycle. These engines are superior to the ones considered earlier in work extraction efficiency, and, even, are capable of converting heat into work by exclusively utilizing inter-system correlations. We formulate a resource theory for quantum heat engines to prove the results.

arXiv:1911.07003•npj Quantum Information•Feb 12, 2021•24 citations

Quantum Heat Machines Equivalence, Work Extraction beyond Markovianity, and Strong Coupling via Heat Exchangers

Raam Uzdin, Amikam Levy, Ronnie Kosloff

Various engine types are thermodynamically equivalent in the quantum limit of small “engine action”. Our previous derivation of the equivalence is restricted to Markovian heat baths and to implicit classical work repository (e.g., laser light in the semi-classical approximation). In this paper, all the components, baths, batteries, and engines, are explicitly taken into account. To neatly treat non-Markovian dynamics, we use mediating particles that function as a heat exchanger. We find that, on top of the previously observed equivalence, there is a higher degree of equivalence that cannot be achieved in the Markovian regime. Next, we focus on the quality of the battery charging process. A condition for positive energy increase and zero entropy increase (work) is given. Moreover, it is shown that, in the strong coupling regime, it is possible to super-charge a battery. With super-charging, the energy of the battery is increased while its entropy is being reduced at the same time.

arXiv:1602.04925•Entropy•Apr 6, 2016•71 citations

Measurement-based Formulation of Quantum Heat Engine and Optimal Efficiency with Finite-Size Effect

Hiroyasu Tajima, Masahito Hayashi

There exist two formulations for quantum heat engine. One is semi-classical scenario, and the other is full quantum scenario. The former is formulated as a unitary evolution for the internal system (working body and heat baths), and is adopted by the community of statistical mechanics. The latter is formulated as a unitary for the work storage and the internal system. It is adopted by the community of quantum information. However, these formulations do not consider measurement process. In this paper, we formulate the quantum heat engine based on the quantum measurement theory, because the amount of extracted work should be observed in a practical situation. With using our formulation, we derive two trade-off relations that show the semi-classical scenario does not work when the amount of extracted work is observed, i.e., we can hardly know the amount of the extracted work when the time evolution of the internal system is close to unitary. Next, based on our formulation, we derive the optimal efficiency of quantum heat engines with the finite-size heat baths, without assuming the existence of quasi-static processes. Using the strong large deviation theory, we asymptotically expand the optimal efficiency up to the third order. The first term is shown to be Carnot efficiency, and the higher order terms are shown to be the finite-size effects of the heat baths. We can construct the optimal work extraction as an energy-preserving unitary evolution among the internal system and the work storage. During the optimal work extraction, the entropy gain of the work storage is so negligibly small as compared with the energy gain of the work storage.

•Apr 23, 2015•0 citations

Work extraction from quantum systems with bounded fluctuations in work

Jonathan G. Richens, Lluís Masanes

In the standard framework of thermodynamics, work is a random variable whose average is bounded by the change in free energy of the system. This average work is calculated without regard for the size of its fluctuations. Here we show that for some processes, such as reversible cooling, the fluctuations in work diverge. Realistic thermal machines may be unable to cope with arbitrarily large fluctuations. Hence, it is important to understand how thermodynamic efficiency rates are modified by bounding fluctuations. We quantify the work content and work of formation of arbitrary finite dimensional quantum states when the fluctuations in work are bounded by a given amount c. By varying c we interpolate between the standard and minimum free energies. We derive fundamental trade-offs between the magnitude of work and its fluctuations. As one application of these results, we derive the corrected Carnot efficiency of a qubit heat engine with bounded fluctuations.

arXiv:1603.02417•Nature Communications•Nov 25, 2016•33 citations

Works with quantum resource of coherence

Yuhan Ma, Liu, C. L., C. P. Sun

We study the modification of the second law of thermodynamics for a quantum system interacting with a reservoir regarding quantum coherence. The whole system is isolated so that neither energy nor information is lost. It is discovered that the coherence of the reservoir can serves as a useful resource allowing the system extract more energy from the reservoir; among the coherence measures, only is the relative entropy of coherence feasible to quantitatively characterize energy exchange. We demonstrate that a thermodynamic cycle between two coherent reservoirs can output more work than its classical counterpart. The efficiency of such cycle surpasses the Carnot efficiency, which is the upper bound of heat engine efficiency in classical regime.

arXiv:2110.04550•Oct 9, 2021•2 citations

How much work can a quantum device extract from a heat engine?

David Gelbwaser-Klimovsky, Robert Alicki, Gershon Kurizki

Work extraction from a heat engine in a cycle by a quantum mechanical device (quantum "piston") is analyzed. The standard definition of work fails in the quantum domain. The correct extractable work and its efficiency bound are shown to crucially depend on the initial quantum state of the piston. The transient efficiency bound may exceed the standard Carnot bound, although it complies with the second law. Energy gain (e.g. in lasing) is shown to drastically differ from work gain.

arXiv:1302.3468•Feb 14, 2013•3 citations
A suitable way of quantifying work for microscopic quantum systems has been constantly debated in the field of quantum thermodynamics. One natural approach is to measure the average increase in energy of an ancillary system, called the battery, after a work extraction protocol. The quality of energy extracted is usually argued to be good by quantifying higher moments of the energy distribution, or by restricting the amount of entropy to be low. This limits the amount of heat contribution to the energy extracted, but does not completely prevent it. We show that the definition of 'work' is crucial. If one allows for a definition of work that tolerates a non-negligible entropy increase in the battery, then a small scale heat engine can possibly exceed the Carnot efficiency. This can be done without using any additional resources such as coherence or correlations, and furthermore can be achieved even when one of the heat baths is finite in size.
Abstract A heat engine operating in the one-shot finite-size regime, where systems composed of a small number of quantum particles interact with hot and cold baths and are restricted to one-shot measurements, delivers fluctuating work. Further, engines with lesser fluctuation produce a lesser amount of deterministic work. Hence, the heat-to-work conversion efficiency stays well below the Carnot efficiency. Here we overcome this limitation and attain Carnot efficiency in the one-shot finite-size regime, where the engines allow the working systems to simultaneously interact with two baths via the semi-local thermal operations and reversibly operate in a one-step cycle. These engines are superior to the ones considered earlier in work extraction efficiency, and, even, are capable of converting heat into work by exclusively utilizing inter-system correlations. We formulate a resource theory for quantum heat engines to prove the results.
Various engine types are thermodynamically equivalent in the quantum limit of small “engine action”. Our previous derivation of the equivalence is restricted to Markovian heat baths and to implicit classical work repository (e.g., laser light in the semi-classical approximation). In this paper, all the components, baths, batteries, and engines, are explicitly taken into account. To neatly treat non-Markovian dynamics, we use mediating particles that function as a heat exchanger. We find that, on top of the previously observed equivalence, there is a higher degree of equivalence that cannot be achieved in the Markovian regime. Next, we focus on the quality of the battery charging process. A condition for positive energy increase and zero entropy increase (work) is given. Moreover, it is shown that, in the strong coupling regime, it is possible to super-charge a battery. With super-charging, the energy of the battery is increased while its entropy is being reduced at the same time.
There exist two formulations for quantum heat engine. One is semi-classical scenario, and the other is full quantum scenario. The former is formulated as a unitary evolution for the internal system (working body and heat baths), and is adopted by the community of statistical mechanics. The latter is formulated as a unitary for the work storage and the internal system. It is adopted by the community of quantum information. However, these formulations do not consider measurement process. In this paper, we formulate the quantum heat engine based on the quantum measurement theory, because the amount of extracted work should be observed in a practical situation. With using our formulation, we derive two trade-off relations that show the semi-classical scenario does not work when the amount of extracted work is observed, i.e., we can hardly know the amount of the extracted work when the time evolution of the internal system is close to unitary. Next, based on our formulation, we derive the optimal efficiency of quantum heat engines with the finite-size heat baths, without assuming the existence of quasi-static processes. Using the strong large deviation theory, we asymptotically expand the optimal efficiency up to the third order. The first term is shown to be Carnot efficiency, and the higher order terms are shown to be the finite-size effects of the heat baths. We can construct the optimal work extraction as an energy-preserving unitary evolution among the internal system and the work storage. During the optimal work extraction, the entropy gain of the work storage is so negligibly small as compared with the energy gain of the work storage.
In the standard framework of thermodynamics, work is a random variable whose average is bounded by the change in free energy of the system. This average work is calculated without regard for the size of its fluctuations. Here we show that for some processes, such as reversible cooling, the fluctuations in work diverge. Realistic thermal machines may be unable to cope with arbitrarily large fluctuations. Hence, it is important to understand how thermodynamic efficiency rates are modified by bounding fluctuations. We quantify the work content and work of formation of arbitrary finite dimensional quantum states when the fluctuations in work are bounded by a given amount c. By varying c we interpolate between the standard and minimum free energies. We derive fundamental trade-offs between the magnitude of work and its fluctuations. As one application of these results, we derive the corrected Carnot efficiency of a qubit heat engine with bounded fluctuations.
We study the modification of the second law of thermodynamics for a quantum system interacting with a reservoir regarding quantum coherence. The whole system is isolated so that neither energy nor information is lost. It is discovered that the coherence of the reservoir can serves as a useful resource allowing the system extract more energy from the reservoir; among the coherence measures, only is the relative entropy of coherence feasible to quantitatively characterize energy exchange. We demonstrate that a thermodynamic cycle between two coherent reservoirs can output more work than its classical counterpart. The efficiency of such cycle surpasses the Carnot efficiency, which is the upper bound of heat engine efficiency in classical regime.