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arXiv:1605.08521

Exact homogeneous master equation for open quantum systems incorporating initial correlations

Pei-Yun Yang, Wei-Min Zhang

Published May 27, 2016• 2 citations
arXivHTMLPDF

Abstract

We show that the exact master equation incorporating initial correlations for open quantum systems, within the Nakajima-Zwanzig operator-projection method, is a homegenous master equation for the reduced density matrix. We also derive explicitly the exact master equation for a large class of bosonic and fermionic open quantum systems incorporating initial correlations, the resulting master equation is homogenous. We find that the effects of the initial correlations can be fully embedded into the fluctuation dynamics through the exact homogenous master equation. Also a generalized nonequilibrium fluctuation-dissipation theorem incorporating the initial correlations is obtained.

DOI
10.48550/arxiv.1605.08521

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We show that the exact master equation incorporating initial correlations for open quantum systems, within the Nakajima-Zwanzig operator-projection method, is a homegenous master equation for the reduced density matrix. We also derive explicitly the exact master equation for a large class of bosonic and fermionic open quantum systems incorporating initial correlations, the resulting master equation is homogenous. We find that the effects of the initial correlations can be fully embedded into the fluctuation dynamics through the exact homogenous master equation. Also a generalized nonequilibrium fluctuation-dissipation theorem incorporating the initial correlations is obtained.
A novel approach to accounting for the influence of initial system-bath correlations on the dynamics of an open quantum system, based on the conventional projection operator technique, is suggested. To avoid the difficulties of treating the initial correlations, the conventional Nakajima-Zwanzig inhomogeneous generalized master equations (GMEs) for a system's reduced statistical operator and correlation function are exactly converted into the homogeneous GMEs (HGMEs), which take into account the initial correlations in the kernel governing the evolution of these HGMEs. In the second order (Born) approximation in the system-bath interaction, the obtained HGMEs are local in time and valid at all timescales. They are further specialized for a realistic equilibrium Gibbs initial (at t=t0t=t_0t=t0​) system+bath state (for a system reduced statistical operator an external force at t>t0t>t_0t>t0​ is applied) and then for a bath of oscillators (Boson field). As an example, the evolution of a selected quantum oscillator (a localized mode) interacting with a Boson field (Fano-like model) is considered at different timescales. It is shown explicitly how the initial correlations influence the oscillator evolution process. In particular, it is shown that the equilibrium system's correlation function acquires at the large timescale the additional constant phase factor conditioned by survived initial system-bath correlations.
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Exact and approximate master equations were derived by the projection operator method for the reduced statistical operator of a multi-level open quantum system with finite number NNN of quantum eigenstates interacting with arbitrary external deterministic fields and dissipative environment simultaneously. Unlike conventional master equations derived by the projection operator method for the quantum systems of this kind so far, these equations are homogeneous in the reduced statistical operator while, at the same time, taking into account initial correlations between the multi-level system and the environment. Consistent representation of the multi-level system evolution in terms of the SU(N)SU(N)SU(N) operator algebra facilitates efficient numerical analysis of these equations derived for various physically realistic quantum models.
The non-Markovian master equation for open quantum systems is obtained by generalization of the ordinary Zwanzig-Nakajima (ZN) projection technique. To this end, a coupled chain of equations for the reduced density matrices of the bath ϱB(t)\varrho_{B}(t)ϱB​(t) and the system ϱS(t)\varrho_{S}(t)ϱS​(t) are written down. A formal solution of the equation for ϱB(t)\varrho_{B}(t)ϱB​(t), having been inserted in the equation for the reduced density matrix of the system, in the 2-nd approximation in interaction yields a very specific extra term in the generalized master equation. This term, being nonlinear in ϱS(t)\varrho_{S}(t)ϱS​(t), is related to the intrinsic bath dynamics and vanishes in the Markovian limit. To verify the consistence and robustness of our approach, we applied the generalized ZN projection scheme to a simple dephasing model. It is shown that consideration of the lowest order in interaction is insufficient to describe time evolution of the system coherence adequately. We explain this fact by analyzing the exact and approximate forms of ϱB(t)\varrho_{B}(t)ϱB​(t) and give some hints how to take the dynamic correlations (which originate from the spin-bath coupling) into account.
We extend the Nakajima-Zwanzig projection operator technique to the determination of multitime correlation functions of open quantum systems. The correlation functions are expressed in terms of certain multitime homogeneous and inhomogeneous memory kernels for which suitable equations of motion are derived. We show that under the condition of finite memory times, these equations can be used to determine the memory kernels by employing an exact stochastic unraveling of the full system-environment dynamics. The approach thus allows us to combine exact stochastic methods, feasible for short times, with long-time master equation simulations. The applicability of the method is demonstrated by numerical simulations of two-dimensional spectra for a donor-acceptor model, and by comparison of the results with those obtained from the reduced hierarchy equations of motion. We further show that the formalism is also applicable to the time evolution of a periodically driven two-level system initially in equilibrium with its environment.
For a system of N≫1 spinless quantum particles, the projection operator is introduced, which, surprisingly, exactly transforms the inhomogeneous (with irrelevant initial correlations term) Nakajima-Zwanzig generalized master equation (GME) into completely closed (homogeneous) GME with initial correlations included into the kernel governing its evolution. The obtained equation is equivalent to the closed linear evolution equation for an S-particle (S<N) statistical operator, which holds for any initial condition and all timescales. Thus, the introduced projector implements the idea of the subdynamics in the subspace of S-particle complex. It also allows for precise treatment of the initial correlations on an equal footing with collisions. No "molecular chaos" -type approximation is used. The obtained homogeneous equation is further specialized in the linear approximation in the particles density n for the kernel and considered in detail for the one-particle statistical operator. The influence of both the quantum correlations, caused by the particles' statistics, and initial correlations, related to the interparticle interaction, is considered in detail and at different timescales. Connection of the linear equation for a one-particle statistical operator to the nonlinear quantum Boltzmann equation is shown.