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arXiv:1605.05760 · Journal of Physics B Atomic Molecular and Optical Physics

The molecular Aharonov–Bohm effect redux

Bernard Zygelman

Published Dec 29, 2016• 7 citations
arXivHTMLPDF

Abstract

Abstract A solvable molecular collision model that predicts Aharonov–Bohm (AB) like scattering in the adiabatic approximation is introduced. For it, we propagate coupled channel wave packets without resorting to a Born–Oppenheimer (BO) approximation. In those, exact, solutions we find evidence of topological phase dislocation lines that are independent of the collision energy and provide definitive signatures of AB-like scattering. The results of these simulations contrast with the conclusions of a recent study that suggests survival of the molecular Aharonov–Bohm effect only in the adiabatic limit in which the nuclear reduced mass μ → ∞ . We discuss generalizations of this model and consider possible screening of the Mead–Truhlar vector potential by the presence of multiple conical intersections (CI). We demonstrate that the Wilson loop phase integral has the value −1 if it encloses an odd-number of CI's, and takes the value +1 for an even number. Within the scope of this model, we investigate the ultra-cold limit of scattering solutions in the presence of a conical intersection and comment on the relevance of Wigner threshold behavior for s-wave scattering.

DOI
10.1088/1361-6455/50/2/025102

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Abstract A solvable molecular collision model that predicts Aharonov–Bohm (AB) like scattering in the adiabatic approximation is introduced. For it, we propagate coupled channel wave packets without resorting to a Born–Oppenheimer (BO) approximation. In those, exact, solutions we find evidence of topological phase dislocation lines that are independent of the collision energy and provide definitive signatures of AB-like scattering. The results of these simulations contrast with the conclusions of a recent study that suggests survival of the molecular Aharonov–Bohm effect only in the adiabatic limit in which the nuclear reduced mass μ → ∞ . We discuss generalizations of this model and consider possible screening of the Mead–Truhlar vector potential by the presence of multiple conical intersections (CI). We demonstrate that the Wilson loop phase integral has the value −1 if it encloses an odd-number of CI's, and takes the value +1 for an even number. Within the scope of this model, we investigate the ultra-cold limit of scattering solutions in the presence of a conical intersection and comment on the relevance of Wigner threshold behavior for s-wave scattering.
Writing about what is usually termed the Aharonov-Bohm (AB) effect, Peter Sturrock and Timothy Groves argue (Physics Today, April 2010, page 8) that the same physics was discovered a decade earlier 1 1. W. Ehrenberg, R. E. Siday, Proc. Phys. Soc. B 62, 8 (1949). and should rightly be called the Ehrenberg-Siday effect. I agree that Werner Ehrenberg and Raymond Siday deserve recognition for their anticipation of AB. Indeed, in recent talks celebrating the 50th anniversary of AB, I began by describing the unfairly neglected paper by Ehrenberg and Siday. Nevertheless, I have come to a different conclusion from Sturrock and Groves: The expression “Aharonov-Bohm effect” is justified, for two reasons.First, although there is no doubt that the work by Ehrenberg and Siday anticipated how inaccessible magnetic flux can influence electron interference, that was as a curiosity, at the end of a paper whose main emphasis was the Hamiltonian analysis of electron optics. By contrast, Yakir Aharonov and David Bohm emphasized from the start, as an essential and general aspect of quantum mechanics, the physical influence of inaccessible fields that act nonlocally through the vector potential.Second, Ehrenberg and Siday’s semi-classical approximation—essentially applying the Dirac magnetic phase factor to electrons traveling on either side of the flux—implies a wavefunction that is multivalued and therefore not the correct solution of Schrödinger’s equation. The lack of a single-valued wavefunction leaves their prediction open to doubt. By contrast, Aharonov and Bohm derived the exact single-valued solution for waves scattered by a flux line. Recently, it was shown that the Ehrenberg-Siday approximation corresponds to the first terms in a “many-whirls” representation that treats the exact AB wavefunction as a topological sum over paths circling the flux. 2 2. M. V. Berry, J. Phys. A (in press). Attribution of credit is a delicate matter. It tends to excite strong feelings, and I write about it reluctantly. But the Ehrenberg-Siday paper does seem to exemplify the unfortunate phenomenon identified by Alfred North White-head in a 1916 address to the British Association for the Advancement of Science: “Everything of importance has been said before, by someone who did not discover it.”In a companion letter in the April 2010 issue, Alexander Ershkovich correctly points out that the AB effect is present in classical Hamiltonian mechanics, even though remote magnetic fields cannot influence Newtonian trajectories. He advocates a “search for experiments that might prove … a classical analogue of the Aharonov-Bohm effect.” Such an experiment exists already. In the classical physics of waves on a moving medium, the flow velocity acts like the vector potential in quantum mechanics, so the flow vorticity acts like the magnetic field; the analogy is precise. Fine details of the AB wavefunction were observed in ripples on the surface of water swirling irrotationally into a bathtub vortex, 3 3. M. V. Berry, R. G. Chambers, M. D. Large, C. Upstill, J. C. Walmsley, Eur. J. Phys. 1, 154 (1980). whose core is the analogue of inaccessible magnetic flux. REFERENCESSection:ChooseTop of pageREFERENCES <<CITING ARTICLES1. W. Ehrenberg, R. E. Siday, Proc. Phys. Soc. B 62, 8 (1949). Google ScholarCrossref2. M. V. Berry, J. Phys. A (in press). Google Scholar3. M. V. Berry, R. G. Chambers, M. D. Large, C. Upstill, J. C. Walmsley, Eur. J. Phys. 1, 154 (1980). Google ScholarCrossref© 2010 American Institute of Physics.
Since the Aharonov-Bohm effect is the purely quantum effect that has no analogues in classical physics, its persistence in the quasiclassical limit seems to be hardly possible. Nevertheless, we show that the scattering Aharonov-Bohm effect does persist in the quasiclassical limit owing to the diffraction, i.e. the Fraunhofer diffraction in the case when space outside the enclosed magnetic flux is Euclidean, and the Fresnel diffraction in the case when the outer space is conical. Hence, the enclosed magnetic flux can serve as a gate for the propagation of short-wavelength, almost classical, particles. In the case of conical space, this quasiclassical effect which is in principle detectable depends on the particle spin.
Abstract In this paper we review some aspects of the scattering Aharonov–Bohm effect and Berry’s phase. Specifically, the problem of scattering of free 2d electrons on the system of an arbitrary number of parallel, infinitely thin and infinitely long coils (non-interacting, point magnetic fluxes) is modeled as free semi-classical particle propagation on a topologically non-trivial background. We show that in this case it is possible to obtain Berry’s phase by integration. First the case of a single coil is analyzed, upon which a particular solution for the case of scattering on an arbitrary number of coils is found. Considering the solution in the momentum representation, an analytic continuation of the angle coordinate in the momentum space is introduced, in accord with the non-trivial geometry of the configuration space. Finally, some simple experiments with possible applications for quantum computing are proposed.
By analyzing an exactly solvable model in the second quantized formulation which allows a unified treatment of adiabatic and non-adiabatic geometric phases, it is shown that the topology of the adiabatic Berry's phase, which is characterized by the singularity associated with possible level crossing, is trivial in a precise sense. This topology of the geometric phase is quite different from the topology of the Aharonov-Bohm effect, where the topology is specified by the external local gauge field and it is exact for the slow as well as for the fast motion of the electron.