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arXiv:1604.08094 · Scientific Reports

Optimal processes for probabilistic work extraction beyond the second law

Vasco Cavina, Andrea Mari, Vittorio Giovannetti

Published Jul 5, 2016• 21 citations
arXivHTMLPDF

Abstract

According to the second law of thermodynamics, for every transformation performed on a system which is in contact with an environment of fixed temperature, the average extracted work is bounded by the decrease of the free energy of the system. However, in a single realization of a generic process, the extracted work is subject to statistical fluctuations which may allow for probabilistic violations of the previous bound. We are interested in enhancing this effect, i.e. we look for thermodynamic processes that maximize the probability of extracting work above a given arbitrary threshold. For any process obeying the Jarzynski identity, we determine an upper bound for the work extraction probability that depends also on the minimum amount of work that we are willing to extract in case of failure, or on the average work we wish to extract from the system. Then we show that this bound can be saturated within the thermodynamic formalism of quantum discrete processes composed by sequences of unitary quenches and complete thermalizations. We explicitly determine the optimal protocol which is given by two quasi-static isothermal transformations separated by a finite unitary quench.

DOI
10.1038/srep29282

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According to the second law of thermodynamics, for every transformation performed on a system which is in contact with an environment of fixed temperature, the average extracted work is bounded by the decrease of the free energy of the system. However, in a single realization of a generic process, the extracted work is subject to statistical fluctuations which may allow for probabilistic violations of the previous bound. We are interested in enhancing this effect, i.e. we look for thermodynamic processes that maximize the probability of extracting work above a given arbitrary threshold. For any process obeying the Jarzynski identity, we determine an upper bound for the work extraction probability that depends also on the minimum amount of work that we are willing to extract in case of failure, or on the average work we wish to extract from the system. Then we show that this bound can be saturated within the thermodynamic formalism of quantum discrete processes composed by sequences of unitary quenches and complete thermalizations. We explicitly determine the optimal protocol which is given by two quasi-static isothermal transformations separated by a finite unitary quench.
We consider the task of extracting work from quantum systems in the resource theory perspective of thermodynamics, where free states are arbitrary thermal states, and allowed operations are energy conserving unitary transformations. Taking as our work storage system a 'weight' we prove the second law and then present simple protocols which extract average work equal to the free energy change of the system - the same amount as in classical thermodynamics. Crucially, for systems in 'classical' states (mixtures of energy eigenstates) our protocol works on a single copy of the system. This is in sharp contrast to previous results, which showed that in case of almost-deterministic work extraction, collective actions on multiple copies are necessary to extract the free energy. This establishes the fact that free energy is a meaningful notion even for individual systems in classical states. However, for non-classical states, where coherences between energy levels exist, we prove that collective actions are necessary, so long as no external sources of coherence are used.
Free energy fixes the maximum work of a thermodynamic process once the state and Hamiltonian are specified. A work-extraction task asks a different question: how much average work can a single device realize across several preparations and Hamiltonian settings? A classical work device is one whose Hamiltonian settings are mutually commuting. We place every branch at its best free-energy-limited work envelope and derive the corresponding classical limit on the task average. For pure preparations, the source is specified only by pairwise maximal-energy constraints: for each pair, the intrinsic maximal average energy under one common normalized Hamiltonian is bounded as part of the task data, while the work device is otherwise microscopically unrestricted. The benchmark is optimized over arbitrary-dimensional classical implementations. Incompatible Hamiltonian settings exceed this limit, even though every branch remains bounded by its own free-energy maximum. The advantage therefore does not arise in any single process, but in the average work of the task: incompatible Hamiltonians realize a value that no classical work device can attain. Hamiltonian incompatibility is thus a thermodynamic resource for work extraction.
In the standard framework of thermodynamics, work is a random variable whose average is bounded by the change in free energy of the system. This average work is calculated without regard for the size of its fluctuations. Here we show that for some processes, such as reversible cooling, the fluctuations in work diverge. Realistic thermal machines may be unable to cope with arbitrarily large fluctuations. Hence, it is important to understand how thermodynamic efficiency rates are modified by bounding fluctuations. We quantify the work content and work of formation of arbitrary finite dimensional quantum states when the fluctuations in work are bounded by a given amount c. By varying c we interpolate between the standard and minimum free energies. We derive fundamental trade-offs between the magnitude of work and its fluctuations. As one application of these results, we derive the corrected Carnot efficiency of a qubit heat engine with bounded fluctuations.
Recent developments of the analysis of the second law of thermodynamics by using the information theoretic quantities has led to the discovery of the so-called nonequilibrium free energy and has allowed us to formulate thermodynamic relations for arbitrary nonequilibrium initial and final states.By using the nonequilibrium free energies, we can quantify thermodynamic costs of information encoding and erasure processes as well as to quantify the extractable work from information heat engines in a unified way.In those general situations, reducing dissipation allows us to increase the extractable work from the system (or to reduce the work cost), and reducing work fluctuation allows us to narrow the work probability distribution and to extract a fluctuation-free work from the system.Suppressing both work fluctuation and dissipation as much as possible is vital to control mesoscopic and nano systems that work at the level of thermal fluctuations.Previous studies have searched for a vanishing work fluctuation protocol by using techniques of quantum information theory, known as the single-shot statistical mechanics (and sometimes called the deterministic work extraction protocol) and the vanishing dissipation protocol, known as the thermodynamically reversible protocol by using the second law of thermodynamics.In this thesis, we address issues concerning a method to control nonequilibrium systems by using fluctuation theorems and trade-off relation between work fluctuation and fluctuation in dissipation.We derive quantum fluctuation theorems under measurement and feedback control, which allow us to study how to suppress dissipation during a general quantum measurement and a feedback control.We then consider a method to suppress work fluctuation and fluctuation in dissipation simultaneously as much as possible by showing the trade-off relation between work and dissipation in terms of their standard deviations and derive an explicit protocol that achieves the lower bound of the trade-off relation.We show that the explicit protocol reproduces the deterministic work extraction protocol in the limit of vanishing work fluctuation and the thermodynamically reversible protocol in the limit of vanishing fluctuation in dissipation.
The second law of thermodynamics, formulated as an ultimate bound on the maximum extractable work, has been rigorously derived in multiple scenarios. However, the unavoidable limitations that emerge due to the lack of control on small systems are often disregarded when deriving such bounds, which is specifically important in the context of quantum thermodynamics. Here we study the maximum extractable work with limited control over the working system and its interaction with the heat bath. We derive a general second law when the set of accessible Hamiltonians of the working system is arbitrarily restricted. We then apply our bound to particular scenarios that are important in realistic implementations: limitations on the maximum energy gap and local control over many-body systems. We hence demonstrate in what precise way the lack of control affects the second law. In particular, contrary to the unrestricted case, we show that the optimal work extraction is not achieved by simple thermal contacts. Our results not only generalize the second law to scenarios of practical relevance, but also take first steps in the direction of local thermodynamics.
There has been an increasing interest in the quantification of nearly deterministic work extraction from a finite number of copies of microscopic particles in finite time. This paradigm, the so-called single-shot $\ensuremath{\epsilon}$-deterministic work extraction, considers processes with small failure probabilities. However, the resulting fluctuations in the extracted work entailed by this failure probability have yet to be studied. In the standard thermodynamics, paradigm fluctuation theorems are powerful tools to study fluctuating quantities. Given that standard fluctuation theorems are inadequate for a single-shot scenario, here we formulate and prove a fluctuation relation specific to the single-shot $\ensuremath{\epsilon}$-deterministic work extraction to bridge this gap. Our results are general in the sense that we allow the system to be in contact with the heat bath at all times. As a corollary of our theorem, we derive the known bounds on the $\ensuremath{\epsilon}$-deterministic work.