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arXiv:1604.07583 · Journal of Experimental and Theoretical Physics Letters

Unconventional superconductivity in low density electron systems and conventional superconductivity in hydrogen metallic alloys

M. Yu. Kagan

Published Jun 1, 2016• 21 citations
arXivHTMLPDF

Abstract

In this short review, we first discuss the results, which are mainly devoted to the generalizations of the famous Kohn–Luttinger mechanism of superconductivity in purely repulsive fermion systems at low electron densities. In the context of repulsive-U Hubbard model and Shubin–Vonsovsky model we consider briefly the superconducting phase diagrams and the symmetries of the order parameter in novel strongly correlated electron systems including idealized monolayer and bilayer graphene. We stress that purely repulsive fermion systems are mainly the subject of unconventional low-temperature superconductivity. To get the high temperature superconductivity in cuprates (with T C of the order of 100 K) we should proceed to the t–J model with the van der Waals interaction potential and the competition between short-range repulsion and long-range attraction. Finally we note that to describe superconductivity in metallic hydrogen alloys under pressure (with T C of the order of 200 K) it is reasonable to reexamine more conventional mechanisms connected with electron–phonon interaction. These mechanisms arise in the attractive-U Hubbard model with static onsite or intersite attractive potential or in more realistic theories (which include retardation effects) such as Migdal–Eliashberg strong coupling theory or even Fermi–Bose mixture theory of Ranninger et al. and its generalizations.

DOI
10.1134/s0021364016110059

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In this short review, we first discuss the results, which are mainly devoted to the generalizations of the famous Kohn–Luttinger mechanism of superconductivity in purely repulsive fermion systems at low electron densities. In the context of repulsive-U Hubbard model and Shubin–Vonsovsky model we consider briefly the superconducting phase diagrams and the symmetries of the order parameter in novel strongly correlated electron systems including idealized monolayer and bilayer graphene. We stress that purely repulsive fermion systems are mainly the subject of unconventional low-temperature superconductivity. To get the high temperature superconductivity in cuprates (with T C of the order of 100 K) we should proceed to the t–J model with the van der Waals interaction potential and the competition between short-range repulsion and long-range attraction. Finally we note that to describe superconductivity in metallic hydrogen alloys under pressure (with T C of the order of 200 K) it is reasonable to reexamine more conventional mechanisms connected with electron–phonon interaction. These mechanisms arise in the attractive-U Hubbard model with static onsite or intersite attractive potential or in more realistic theories (which include retardation effects) such as Migdal–Eliashberg strong coupling theory or even Fermi–Bose mixture theory of Ranninger et al. and its generalizations.
We discuss the mechanisms of unconventional superconductivity and superfluidity in 3D and 2D fermionic systems with purely repulsive interaction at low densities. We construct phase diagrams of these systems and find the areas of the superconducting state in free space, as well as on the lattice in the framework of the Fermi-gas model with hard-core repulsion, the Hubbard model, the Shubin-Vonsovsky model, and the t−Jt-Jt−J model. We demonstrate that the critical superconducting temperature can be greatly increased in the spin-polarized case or in a two-band situation already at low densities. The proposed theory is based on the Kohn-Luttinger mechanism or its generalizations and explains or predicts anomalous ppp-, ddd-, and fff-wave pairing in various materials, such as high-temperature superconductors, the idealized monolayer and bilayer of doped graphene, heavy-fermion systems, layered organic superconductors, superfluid 3^33He, spin-polarized 3^33He mixtures in 4^44He, ultracold quantum gases in magnetic traps, and optical lattices.
We present a review of theoretical investigations into the Kohn-Luttinger nonphonon superconductivity mechanism in various 3D and 2D repulsive electron systems described by the Fermi-gas, Hubbard, and Shubin-Vonsovsky models. Phase diagrams of the superconducting state are considered, including regions of anomalous s-, p-, and d-wave pairing. The possibility of a strong increase in the superconducting transition temperature T c even for a low electron density is demonstrated by analyzing the spin-polarized case or the two-band situation. The Kohn-Luttinger theory explains or predicts superconductivity in various materials such as heterostructures and semimetals, superlattices and dichalcogenides, high-T c superconductors and heavy-fermion systems, layered organic superconductors, and ultracold Fermi gases in magnetic traps. This theory also describes the anomalous electron transport and peculiar polaron effects in the normal state of these systems. The theory can be useful for explaining the origin of superconductivity and orbital currents (chiral anomaly) in systems with the Dirac spectrum of electrons, including superfluid 3He-A, doped graphene, and topological superconductors.
We demonstrate the possibility of triplet p-wave pairing at low electron density a large number of models such as 3D and 2D Fermi-gas models with hard-core repulsion, 3D and 2D Hubbard models, and the Shubin-Vonsovsky model. The critical temperature for p-wave pairing can be considerably higher in the spin-polarized case or even in a two-band situation at low density and can reach experimentally observable values of 1–5 K. We also discuss briefly the d-wave pairing and high-Tc superconductivity with Tc ∼ 100 K which arise in the extended Hubbard model and in the generalized t-J model when close to half-filling.
In this review article we consider theoretically and give experimental support to the models of the Fermi-Bose mixtures and the BCS-BEC (Bardeen Cooper Schrieffer–Bose Einstein) crossover compared with the strong-coupling approach, which can serve as the cornerstones on the way from high-temperature to room-temperature superconductivity in pressurized metallic hydrides. We discuss some key theoretical ideas and mechanisms proposed for unconventional superconductors (cuprates, pnictides, chalcogenides, bismuthates, diborides, heavy-fermions, organics, bilayer graphene, twisted graphene, oxide hetero-structures), superfluids and balanced or imbalanced ultracold Fermi gases in magnetic traps. We build a bridge between unconventional superconductors and recently discovered pressurized hydrides superconductors H3S and LaH10 with the critical temperature close to room temperature. We discuss systems with a line of nodal Dirac points close to the Fermi surface and superconducting shape resonances, and hyperbolic superconducting networks which are very important for the development of novel topological superconductors, for the energetics, for the applications in nano-electronics and quantum computations.
Motivation With few exceptions [131] it is widely accepted that the conventional Bardeen–Cooper–Schrieffer (BCS) theory [12] and its intermediate-coupling Eliashberg extension [14] do not suffice to explain high-temperature superconductivity. As shown in the preceding chapters the true origin of high-temperature superconductivity could be found in a proper combination of the bare Coulomb repulsion with the bare electron–phonon interaction in the framework of the many-body polaron theory [51] beyond the BCS–Eliashberg approximation. Nevertheless some researchers have maintained that the repulsive electron–electron interaction alone should provide pairing at high temperatures without phonons despite substantial experimental evidence that the EPI is an important player and needs to be included in the successful theory of high- T c superconductivity. Following the original proposal by P. W. Anderson, many authors [22, 74] argued that the electron–electron interaction in high-temperature superconductors was strong but repulsive providing high T c without phonons via superexchange and/or spin fluctuations in the d -wave pairing channel ( l = 2). A motivation for this concept can be found in the earlier works by Kohn and Luttinger (KL) [132, 133] who showed that the Cooper pairing of fermions with any weak repulsion was possible since the two-particle interaction induced by many-body effects is attractive for pairs with large orbital momenta, l ≫ 1.
The understanding of the mechanisms responsible for superconductivity in strongly correlated systems is an interesting and important subject in condensed matter physics. Several theoretical proposals were considered for these systems. The Coulomb interaction between electrons allow a new approach to study this problem. In this paper, we use a usual Hubbard model with a local repulsive interaction to describe a 2D system. The system of equations are solved using the Green's functions method, within a Hubbard-I mean field approximation, which allows to treat the strong interaction limit. We consider both cases of attractive and repulsive interactions and obtain the zero temperature phase diagram of the model. Our results show, in the repulsive case, the existence of a superconducting ground state mediated by the kinetic electronic energy and described by a non-local order parameter. A minimum value of the repulsive interaction UminU_{min}Umin​ is required to create a pairing state. At finite temperatures, for strong interactions, the critical temperature TcT_cTc​ shows a saturation similar to the Bose-Einstein condensation observed for strong attractive interactions.