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arXiv:1603.00966 · Symmetry

Classical and Quantum Spherical Pendulum

Richard H. Cushman, Jędrzej Śniatycki

Published Feb 28, 2022• 4 citations

Abstract

The seminal paper by Niels Bohr followed by a paper by Arnold Sommerfeld led to a revolutionary Bohr–Sommerfeld theory of atomic spectra. We are interested in the information about the structure of quantum mechanics encoded in this theory. In particular, we want to extend Bohr–Sommerfeld theory to a full quantum theory of completely integrable Hamiltonian systems, which is compatible with geometric quantization. In the general case, we use geometric quantization to prove analogues of the Bohr–Sommerfeld quantization conditions for the prequantum operators Pf. If a prequantum operator Pf satisfies the Bohr–Sommerfeld conditions and if it restricts to a directly quantized operator Qf in the representation corresponding to the polarization F, then Qf also satisfies the Bohr–Sommerfeld conditions. The proof that the quantum spherical pendulum is a quantum system of the type we are looking for requires a new treatment of the classical action functions and their properties. For the sake of completeness we have provided an extensive presentation of the classical spherical pendulum. In our approach to Bohr–Sommerfeld theory, which we call Bohr–Sommerfeld–Heisenberg quantization, we define shifting operators that provide transitions between different quantum states. Moreover, we relate these shifting operators to quantization of functions on the phase space of the theory. We use Bohr–Sommerfeld–Heisenberg theory to study the properties of the quantum spherical pendulum, in particular, the boundary conditions for the shifting operators and quantum monodromy.

DOI: 10.3390/sym14030496

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The seminal paper by Niels Bohr followed by a paper by Arnold Sommerfeld led to a revolutionary Bohr–Sommerfeld theory of atomic spectra. We are interested in the information about the structure of quantum mechanics encoded in this theory. In particular, we want to extend Bohr–Sommerfeld theory to a full quantum theory of completely integrable Hamiltonian systems, which is compatible with geometric quantization. In the general case, we use geometric quantization to prove analogues of the Bohr–Sommerfeld quantization conditions for the prequantum operators Pf. If a prequantum operator Pf satisfies the Bohr–Sommerfeld conditions and if it restricts to a directly quantized operator Qf in the representation corresponding to the polarization F, then Qf also satisfies the Bohr–Sommerfeld conditions. The proof that the quantum spherical pendulum is a quantum system of the type we are looking for requires a new treatment of the classical action functions and their properties. For the sake of completeness we have provided an extensive presentation of the classical spherical pendulum. In our approach to Bohr–Sommerfeld theory, which we call Bohr–Sommerfeld–Heisenberg quantization, we define shifting operators that provide transitions between different quantum states. Moreover, we relate these shifting operators to quantization of functions on the phase space of the theory. We use Bohr–Sommerfeld–Heisenberg theory to study the properties of the quantum spherical pendulum, in particular, the boundary conditions for the shifting operators and quantum monodromy.

In the framework of geometric quantization we extend the Bohr-Sommerfeld rules to a full quantization theory which resembles Heisenberg's matrix theory. This extension is possible because Bohr-Sommerfeld rules not only provide an orthogonal basis in the space of quantum states, but also give a lattice structure to this basis. This permits the definition of appropriate shifting operators. As examples, we discuss the 1-dimensional harmonic oscillator and the coadjoint orbits of the rotation group.

Abstract We review the Bohr atomic model, where certain conditions (quantum conditions) were used to select certain “allowed” circular orbits for the electrons in an atom. Sommerfeld realized that a more generalized condition, applied to the action variables, would be consistent with the Bohr condition and also allow elliptical orbits. This condition amounted to the quantization of the phase space occupied by an orbit. This had independently been suggested by Planck. We also discuss the similarities between classical mechanics and the geometric optics limit of a wave theory.

Bohr's atomic theory is widely viewed as remarkable, both for its accuracy in predicting the observed optical transitions of one-electron atoms and for its failure to fully correspond with current electronic structure theory. What is not generally appreciated is that Bohr's original semiclassical conception differed significantly from the Bohr-Sommerfeld theory and offers an alternative semiclassical approximation scheme with remarkable attributes. More specifically, Bohr's original method did not impose action quantization constraints but rather obtained these as predictions by simply matching photon and classical orbital frequencies. In other words, the hydrogen atom was treated entirely classically and orbital quantized emerged directly from the Planck-Einstein photon quantization condition, E = h nu. Here, we revisit this early history of quantum theory and demonstrate the application of Bohr's original strategy to the three quintessential quantum systems: an electron in a box, an electron in a ring, and a dipolar harmonic oscillator. The usual energy-level spectra, and optical selection rules, emerge by solving an algebraic (quadratic) equation, rather than a Bohr-Sommerfeld integral (or Schroedinger) equation. However, the new predictions include a frozen (zero-kinetic-energy) state which in some (but not all) cases lies below the usual zero-point energy. In addition to raising provocative questions concerning the origin of quantum-chemical phenomena, the results may prove to be of pedagogical value in introducing students to quantum mechanics.

We consider the description of classical oscillatory motion in ZM theory, and explore the relationship of ZM theory to semi-classical Bohr-Sommerfeld quantization. The treatment illustrates some features of ZM theory, especially the inadequacies of classical and semi-classical treatments due to non-analyticity of the mapping of classical trajectories onto the ZM clock field. While the more complete ZM formalism is not developed here, the non-analyticities in the classical treatment resemble issues in the comparison of classical and quantum formalisms. We also show that semi-classical quantization is valid for a periodic manifold in ZM theory, though the quantum number

n=0

is allowed, as it would be in quantum mechanics for a periodic manifold. Still, this suggests a connection to the first-order success of Bohr theory in describing the phenomenology of atomic quantum states. The approximate nature of the semi-classical treatment of three dimensional atomic orbits is, however, also apparent in relation to ZM theory. These observations are preliminary to a discussion of ZM theory in relation to quantum mechanics and quantum field theory in subsequent papers.

We review Bohr's atomic model and its extension by Sommerfeld from a mathematical perspective of wave mechanics.The derivation of quantization rules and energy levels is revisited using semiclassical methods.Sommerfeld-type integrals are evaluated by elementary techniques, and connections with the Schr odinger and Dirac equations are established.Historical developments and key transitions from classical to quantum theory are discussed to clarify the structure and significance of the old quantum mechanics.