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arXiv:1601.06402 · Physical review. E

Stability of quantum statistical ensembles with respect to local measurements

Walter Hahn, Boris V. Fine

Published Dec 5, 2016• 7 citations
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Abstract

We introduce a stability criterion for quantum statistical ensembles describing macroscopic systems. An ensemble is called "stable" when a small number of local measurements cannot significantly modify the probability distribution of the total energy of the system. We apply this criterion to lattices of spins-1/2, thereby showing that the canonical ensemble is nearly stable, whereas statistical ensembles with much broader energy distributions are not stable. In the context of the foundations of quantum statistical physics, this result justifies the use of statistical ensembles with narrow energy distributions such as canonical or microcanonical ensembles.

DOI
10.1103/physreve.94.062106

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We introduce a stability criterion for quantum statistical ensembles describing macroscopic systems. An ensemble is called "stable" when a small number of local measurements cannot significantly modify the probability distribution of the total energy of the system. We apply this criterion to lattices of spins-1/2, thereby showing that the canonical ensemble is nearly stable, whereas statistical ensembles with much broader energy distributions are not stable. In the context of the foundations of quantum statistical physics, this result justifies the use of statistical ensembles with narrow energy distributions such as canonical or microcanonical ensembles.
Abstract We investigate different measures of stability of quantum statistical ensembles with respect to local measurements. We call a quantum statistical ensemble ‘stable’ if a small number of local measurements cannot significantly modify the total-energy distribution representing the ensemble. First, we numerically calculate the evolution of the stability measure introduced in our previous work Hahn and Fine (2016 Phys. Rev . E 94 062106) for an ensemble representing a mixture of two canonical ensembles with very different temperatures in a periodic chain of interacting spins- 1 2 . Second, we propose other possible stability measures and discuss their advantages and disadvantages. We also show that, for small system sizes available to numerical simulations of local measurements, finite-size effects are rather pronounced.
We propose a new approach to justify the use of the microcanonical ensemble for isolated macroscopic quantum systems. Since there are huge number of independent observables in a macroscopic system, we cannot see all of them. Actually what we observe can be written in a rather simple combination of local observables. Considering this limitation, we show that almost all states in a energy shell are practically indistinguishable from one another, and hence from the microcanonical ensemble. In particular, the expectation value of a macroscopic observable is very close to its microcanonical ensemble average for almost all states.
The infinite-volume limit of thermodynamic functions calculated in the quantum microcanonical ensemble is shown to exist for a fairly wide class of spin systems and quantum gases. The entropy is set equal to the logarithm of the number of eigenstates in an energy interval which increases linearly with the size of the system, but is otherwise arbitrary. The limiting entropy per unit volume agrees with that calculated in the canonical formalism, and possesses certain convexity properties required for thermodynamic stability. A precise criterion, in terms of the energy spectra of large systems, is given for determining the limit of the thermodynamic entropy as the temperature approaches zero. This is not determined by the degeneracy of the ground state, contrary to the discussion of the ``third law of thermodynamics'' found in some textbooks.
The capabilities of a new approach towards the foundations of Statistical Mechanics are explored. The approach is genuine quantum in the sense that statistical behavior is a consequence of objective quantum uncertainties due to entanglement and uncertainty relations. No additional randomness is added by hand and no assumptions about a priori probabilities are made, instead measure concentration results are used to justify the methods of Statistical Physics. The approach explains the applicability of the microcanonical and canonical ensemble and the tendency to equilibrate in a natural way. This work contains a pedagogical review of the existing literature and some new results. The most important of which are: i) A measure theoretic justification for the microcanonical ensemble. ii) Bounds on the subsystem equilibration time. iii) A proof that a generic weak interaction causes decoherence in the energy eigenbasis. iv) A proof of a quantum H-Theorem. v) New estimates of the average effective dimension for initial product states and states from the mean energy ensemble. vi) A proof that time and ensemble averages of observables are typically close to each other. vii) A bound on the fluctuations of the purity of a system coupled to a bath.
We show insurmountable contradictions which arise if statistical ensembles are considered a consequence of the influence of the environment of the physical systems. We regard the multiplicity of states with a definite energy value as a result of internal probabilistic processes in the macrosystem; these internal probabilistic processes are not taken into account by quantum mechanics. On a simple example it is demonstrated, that canonical distribution is not independent and equal to microcanonical one, but is a result of averaging by microcanonical ensemble.
We develop a regularization of the quantum microcanonical ensemble, called a Gaussian ensemble, which can be used for derivation of the canonical ensemble from microcanonical principles. The derivation differs from the usual methods by giving an explanation for the, at the first sight unreasonable, effectiveness of the canonical ensemble when applied to certain small, isolated, systems. This method also allows a direct identification between the parameters of the microcanonical and the canonical ensemble and it yields simple indicators and rigorous bounds for the effectiveness of the approximation. Finally, we derive an asymptotic expansion of the microcanonical corrections to the canonical ensemble for those systems, which are near, but not quite, at the thermodynamical limit and show how and why the canonical ensemble can be applied also for systems with an exponentially increasing density of states. The aim throughout the paper is to keep mathematical rigour intact while attempting to produce results which are both physically and practically interesting.