A system of sites weakly coupled to each other and to one or more reservoirs (open quantum network) is considered. A new quantum master equation which improves shortcomings of the master equation known in the so-called local approach is derived. The usual quantum master equation describing the weak coupling of the system with reservoir requires the knowledge of eigenvalues and eigenvectors of the Hamiltonian of the system, so it often becomes impractical. By this reason, when the inter-site couplings are weak, the local approach, which neglects the influence of the inter-site couplings on the system-reservoir couplings, is often used. However, recently, it was reported that the local approach master equation leads to the violation of the second law of thermodynamics. We develop a systematic perturbation expansion to derive corrections to the local approach master equation. Using this improvement of the local approach, we derive an expression for the heat flux for a particular model and show that it does not violate the second law of thermodynamics.
A system of sites weakly coupled to each other and to one or more reservoirs (open quantum network) is considered. A new quantum master equation which improves shortcomings of the master equation known in the so-called local approach is derived. The usual quantum master equation describing the weak coupling of the system with reservoir requires the knowledge of eigenvalues and eigenvectors of the Hamiltonian of the system, so it often becomes impractical. By this reason, when the inter-site couplings are weak, the local approach, which neglects the influence of the inter-site couplings on the system-reservoir couplings, is often used. However, recently, it was reported that the local approach master equation leads to the violation of the second law of thermodynamics. We develop a systematic perturbation expansion to derive corrections to the local approach master equation. Using this improvement of the local approach, we derive an expression for the heat flux for a particular model and show that it does not violate the second law of thermodynamics.
We develop a general theory describing the thermodynamical behavior of open quantum systems coupled to thermal baths beyond perturbation theory. Our approach is based on the exact time-local quantum master equation for the reduced open system states, and on a principle of minimal dissipation. This principle leads to a unique prescription for the decomposition of the master equation into a Hamiltonian part representing coherent time evolution and a dissipator part describing dissipation and decoherence. Employing this decomposition we demonstrate how to define work, heat and entropy production, formulate the first and second law of thermodynamics, and establish the connection between violations of the second law and quantum non-Markovianity.
Master equations under appropriate assumptions are efficient tools for the study of open quantum systems. For many-body systems, subsystems of which locally couple to thermal baths and weakly interact with each other, the local approach provides a more convenient description than the global approach. However, these local master equations are believed to generate inconsistencies with the laws of thermodynamics when intersubsystem interactions exist. Here we develop an alternative local master equation by virtue of similar approximations used in deriving the traditional Gorini-Kossakowski-Lindblad-Sudarshan master equation. In particular, we stick to using eigenstates of each subsystem to construct quantum jump operators, and the secular approximation is also employed to modify the intersubsystem interactions. Our results show that violations of thermodynamic laws will be avoided after correcting intersubsystem interactions. Finally, we study a two-qubit heat transfer model and this further shows the validity of our modified master equation.
We develop a general theory describing the thermodynamical behavior of open quantum systems coupled to thermal baths beyond perturbation theory. Our approach is based on the exact time-local quantum master equation for the reduced open-system states, and on a principle of minimal dissipation. This principle leads to a unique prescription for the decomposition of the master equation into a Hamiltonian part representing coherent time evolution and a dissipator part describing dissipation and decoherence. Employing this decomposition we demonstrate how to define work, heat, and entropy production, formulate the first and second laws of thermodynamics, and establish the connection between violations of the second law and quantum non-Markovianity.
Advances in experimental techniques have opened new routes for harnessing non-equilibrium dynamics in mesoscopic quantum systems. In this context, we study the impact of on-site interactions on the transport properties of a continuous quantum thermal machine composed of two coupled oscillators connected to two thermal reservoirs. In the weak system-reservoir coupling regime, where a long-standing debate concerns which reduced description should be preferred, we first show that the Redfield master equation (RME) provides an accurate and unifying framework that interpolates between two well-known limits: the \textit{local} and \textit{global} master equations. By relying on the Hierarchy of Pure States (HOPS), a numerically exact stochastic method, we then explore the full parameter space and show that interactions can be leveraged to tune the efficiency of the thermal machine at high temperatures (while leaving it essentially unchanged at low temperatures), induce non-reciprocal transport under asymmetric reservoir couplings, and generate steady-state entanglement within the junction. We derive expressions for system-bath correlators, such as heat and particle currents, consistently across different frameworks. Our work features on-site interactions to enhance the versatility of quantum thermodynamic junctions and clarifies the role of non-Markovianity and non-linearities in quantum transport.
Local master equations are a widespread tool to model open quantum systems, especially in the context of many-body systems.These equations, however, are believed to lead to thermodynamic anomalies and violation of the laws of thermodynamics.In contrast, here we rigorously prove that local master equations are consistent with thermodynamics and its laws without resorting to a microscopic model, as done in previous works.In particular, we consider a quantum system in contact with multiple baths and identify the relevant contributions to the total energy, heat currents, and entropy production rate.We show that the second law of thermodynamics holds when one considers the proper expression we derive for the heat currents.We confirm the results for the quantum heat currents by using a heuristic argument that connects the quantum probability currents with the energy currents, using an analogous approach as in classical stochastic thermodynamics.We finally use our results to investigate the thermodynamic properties of a set of quantum rotors operating as thermal devices and show that a suitable design of three rotors can work as an absorption refrigerator or a thermal rectifier.For the machines considered here, we also perform an optimization of the system parameters using an algorithm of reinforcement learning.
When deriving a master equation for a multipartite weakly-interacting open quantum systems, dissipation is often addressed locally on each component, i.e. ignoring the coherent couplings, which are later added ‘by hand’. Although simple, the resulting local master equation (LME) is known to be thermodynamically inconsistent. Otherwise, one may always obtain a consistent global master equation (GME) by working on the energy basis of the full interacting Hamiltonian. Here, we consider a two-node ‘quantum wire’ connected to two heat baths. The stationary solution of the LME and GME are obtained and benchmarked against the exact result. Importantly, in our model, the validity of the GME is constrained by the underlying secular approximation. Whenever this breaks down (for resonant weakly-coupled nodes), we observe that the LME, in spite of being thermodynamically flawed: (a) predicts the correct steady state, (b) yields with the exact asymptotic heat currents, and (c) reliably reflects the correlations between the nodes. In contrast, the GME fails at all three tasks. Nonetheless, as the inter-node coupling grows, the LME breaks down whilst the GME becomes correct. Hence, the global and local approach may be viewed as complementary tools, best suited to different parameter regimes.