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arXiv:1412.0898 · New Journal of Physics

Nonequilibrium fluctuations in quantum heat engines: theory, example, and possible solid state experiments

Michele Campisi, Jukka Pekola, Rosario Fazio

Published Mar 20, 2015• 216 citations
arXivHTMLPDF

Abstract

We study stochastic energetic exchanges in quantum heat engines. Due to microreversibility, these obey a fluctuation relation, called the heat engine fluctuation relation, which implies the Carnot bound: no machine can have an efficiency greater than Carnot's efficiency. The stochastic thermodynamics of a quantum heat engine (including the joint statistics of heat and work and the statistics of efficiency) are illustrated by means of an optimal two-qubit heat engine, where each qubit is coupled to a thermal bath and a two-qubit gate determines energy exchanges between the two qubits. We discuss possible solid-state implementations with Cooper-pair boxes and flux qubits, quantum gate operations, and fast calorimetric on-chip measurements of single stochastic events.

DOI
10.1088/1367-2630/17/3/035012

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We study stochastic energetic exchanges in quantum heat engines. Due to microreversibility, these obey a fluctuation relation, called the heat engine fluctuation relation, which implies the Carnot bound: no machine can have an efficiency greater than Carnot's efficiency. The stochastic thermodynamics of a quantum heat engine (including the joint statistics of heat and work and the statistics of efficiency) are illustrated by means of an optimal two-qubit heat engine, where each qubit is coupled to a thermal bath and a two-qubit gate determines energy exchanges between the two qubits. We discuss possible solid-state implementations with Cooper-pair boxes and flux qubits, quantum gate operations, and fast calorimetric on-chip measurements of single stochastic events.
At the very foundation of the second law of thermodynamics lies the fact that no heat engine operating between two reservoirs of temperatures T C ⩽ T H can outperform the ideal Carnot engine: 〈 W 〉/〈 Q H 〉 ⩽ 1 − T C / T H . This inequality follows from an exact fluctuation relation involving the nonequilibrium work W and heat exchanged with the hot bath Q H . In a previous work (Sinitsyn 2011 J. Phys. A: Math. Theor. 44 405001) this fluctuation relation was obtained under the assumption that the heat engine undergoes a stochastic jump process. Here we provide the general quantum derivation, and also extend it to the case of refrigerators, in which case Carnot's statement reads 〈 Q C 〉/|〈 W 〉| ⩽ ( T H / T C − 1) −1 .
Abstract The thermodynamic properties of quantum heat engines are stochastic owing to the presence of thermal and quantum fluctuations. We here experimentally investigate the efficiency and nonequilibrium entropy production statistics of a spin-1/2 quantum Otto cycle in a nuclear magnetic resonance setup. We first study the correlations between work and heat within a cycle by extracting their joint distribution for different driving times. We show that near perfect correlation, corresponding to the tight-coupling condition between work and heat, can be achieved. In this limit, the reconstructed efficiency distribution is peaked at the deterministic thermodynamic efficiency, and fluctuations are strongly suppressed. We further successfully test the second law in the form of a joint fluctuation relation for work and heat in the quantum cycle. Our results characterize the statistical features of a small-scale thermal machine in the quantum domain, and provide means to control them.
We study energetic exchanges and fluctuations in two-stroke quantum thermodynamic engines where the working fluid is represented by two multilevel quantum systems, i.e., qudits, the heat flow is allowed by relaxation with two thermal reservoirs at different temperatures, and the work exchange is operated by a partial-swap unitary interaction. We identify three regimes of operation (heat engine, refrigerator, and thermal accelerator), present the thermodynamic uncertainty relations between the entropy production and the signal-to-noise ratio of work and heat, and derive the full joint probability of the stochastic work and heat. Our results bridge the gap between two-qubit and two-mode bosonic swap engines, and show which properties are maintained (e.g., a nonfluctuating Otto efficiency) and which are lost for increasing dimension (e.g., small violations of the standard thermodynamic uncertainty relations or the possibility of beating the Curzon-Ahlborn efficiency).
Inspired by the idea that quantum computers can be useful in advancing basic science, we use a quantum processor to experimentally validate a number of theoretical results in non-equilibrium quantum thermodynamics, that were not (or were very little) corroborated so far.In order to do so, we first put forward a novel method to implement the so called two-point measurement scheme, which is at the basis of the study of nonequilibrium energetic exchanges in quantum systems.Like previously established methods, our method uses an ancillary system, but at variance with them, it provides direct access to the energy exchange statistics, and is, accordingly more effective, at least when applied to small quantum systems.Using a quantum computer as a remotely programmable experimental platform, we first validate our ancilla-assisted two-point measurement scheme, and then apply it to (i) experimentally verify that fluctuation theorems are robust against projective measurements, a theoretical prediction, which was not validated so far; (ii) experimentally verify the so-called heat-engine fluctuation relation, by implementing a SWAP quantum heat engine; (iii) experimentally verify that the heat-engine fluctuation relation holds for measurement-fueled quantum heat engines, by implementing the design at the basis of the so-called quantum-measurement-cooling concept.For both engines, we report the measured average heat and work exchanged and single out their operation mode.Our experiments constitute an experimental basis for the understanding of the nonequilibrium energetics of quantum computation and for the implementation of energy-management devices on quantum processors.
Modern technologies could soon make it possible to investigate the operation cycles of quantum heat engines by counting the photons that are emitted and absorbed by their working systems.Using the quantum jump approach to open-system dynamics, we show that such experiments would give access to a set of observables that determine the trade-off between power and efficiency in finite-time engine cycles.By analyzing the single-jump statistics of thermodynamic fluxes such as heat and entropy production, we obtain a family of general bounds on the power of microscopic heat engines.Our new bounds unify two earlier results and admit a transparent physical interpretation in terms of single-photon measurements.In addition, these bounds confirm that driving-induced coherence leads to an increase in dissipation that suppresses the efficiency of slowly driven quantum engines in the weak-coupling regime.A nanoscale heat engine based on a superconducting qubit serves as an experimentally relevant example and a guiding paradigm for the development of our theory.
Abstract A heat engine operating in the one-shot finite-size regime, where systems composed of a small number of quantum particles interact with hot and cold baths and are restricted to one-shot measurements, delivers fluctuating work. Further, engines with lesser fluctuation produce a lesser amount of deterministic work. Hence, the heat-to-work conversion efficiency stays well below the Carnot efficiency. Here we overcome this limitation and attain Carnot efficiency in the one-shot finite-size regime, where the engines allow the working systems to simultaneously interact with two baths via the semi-local thermal operations and reversibly operate in a one-step cycle. These engines are superior to the ones considered earlier in work extraction efficiency, and, even, are capable of converting heat into work by exclusively utilizing inter-system correlations. We formulate a resource theory for quantum heat engines to prove the results.