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arXiv:1411.1388 · Scientific Reports

Power enhancement of heat engines via correlated thermalization in a three-level “working fluid”

David Gelbwaser-Klimovsky, Wolfgang Niedenzu, Paul W. Brumer, Gershon Kurizki

Published Sep 23, 2015• 56 citations
arXivHTMLPDF

Abstract

We explore means of maximizing the power output of a heat engine based on a periodically-driven quantum system that is constantly coupled to hot and cold baths. It is shown that the maximal power output of such a heat engine whose "working fluid" is a degenerate V-type three-level system is that generated by two independent two-level systems. Hence, level degeneracy is a thermodynamic resource that may effectively double the power output. The efficiency, however, is not affected. We find that coherence is not an essential asset in such multilevel-based heat engines. The existence of two thermalization pathways sharing a common ground state suffices for power enhancement.

DOI
10.1038/srep14413

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We explore means of maximizing the power output of a heat engine based on a periodically-driven quantum system that is constantly coupled to hot and cold baths. It is shown that the maximal power output of such a heat engine whose "working fluid" is a degenerate V-type three-level system is that generated by two independent two-level systems. Hence, level degeneracy is a thermodynamic resource that may effectively double the power output. The efficiency, however, is not affected. We find that coherence is not an essential asset in such multilevel-based heat engines. The existence of two thermalization pathways sharing a common ground state suffices for power enhancement.
We consider a quantum engine driven by repeated weak interactions with a heat bath of identical three-level atoms. This model was first introduced by Scully et al. [Science 299, 862 (2003)SCIEAS0036-807510.1126/science.1078955], who showed that coherence between the energy-degenerate ground states serves as a thermodynamic resource that allows operation of a thermal cycle with a coherence-dependent thermalization temperature. We consider a similar engine out of the quasistatic limit and find that the ground-state coherence also determines the rate of thermalization, therefore increasing the output power and the engine efficiency only when the thermalization temperature is reduced; revealing a more nuanced perspective of coherence as a resource. This allows us to optimize the output power by adjusting the coherence and relative stroke durations.
Abstract We work on a comprehensive theoretical investigation of a three-level quantum heat engine operating with engineered squeezed thermal reservoirs. Unlike conventional quantum heat engines that use thermal reservoirs, we demonstrate that squeezed reservoirs can significantly enhance the engine's performance by increasing both efficiency and output power. Using a rigorous open-quantum-system approach, we derive the full Lindblad master equation for a three-level system interacting with hot and cold squeezed thermal baths. Through a detailed analysis of the steady-state thermodynamics, we obtain explicit expressions for heat currents, work output, and efficiency. Our results reveal that moderate squeezing parameters (r≈0.5r \approx 0.5r≈0.5) combined with optimal squeezing phase (ϕ=π/2\phi = \pi/2ϕ=π/2) enhance the engine efficiency by up to 40\% compared to the classical Carnot limit for the same temperature ratio. The power output shows a non-monotonic behavior with squeezing, exhibiting an optimal squeezing parameter that maximizes performance. We identify three distinct operational regimes: (i) heat engine regime, (ii) refrigerator regime, and (iii) heat pump regime, which can be tuned by adjusting the squeezing phase. The efficiency at maximum power follows a universal scaling ηMP≈ηCarnot/2+Δη(r)\eta_{MP} \approx \eta_{Carnot}/2 + \Delta\eta(r)ηMP​≈ηCarnot​/2+Δη(r), where Δη(r)\Delta\eta(r)Δη(r) represents the squeezing-induced enhancement. Our findings provide fundamental insights into the role of non-thermal reservoirs in quantum thermodynamics and offer practical guidelines for designing high-performance quantum heat engines using squeezed light and engineered baths.
We study the optimization of the performance of arbitrary periodically driven thermal machines. Within the assumption of fast modulation of the driving parameters, we derive the optimal cycle that universally maximizes the extracted power of heat engines, the cooling power of refrigerators, and in general any linear combination of the heat currents. We denote this optimal solution as ``generalized Otto cycle'' since it shares the basic structure with the standard Otto cycle, but it is characterized by a greater number of fast strokes. We bound this number in terms of the dimension of the Hilbert space of the system used as working fluid. The generality of these results allows for a widespread range of applications, such as reducing the computational complexity for numerical approaches, or obtaining the explicit form of the optimal protocols when the system-baths interactions are characterized by a single thermalization scale. In this case, we compare the thermodynamic performance of a collection of optimally driven noninteracting and interacting qubits. Remarkably, for refrigerators the noninteracting qubits perform almost as well as the interacting ones, while in the heat engine case there is a many-body advantage both in the maximum power, and in the efficiency at maximum power. Additionally, we illustrate our general results studying the paradigmatic model of a qutrit-based heat engine. Our results strictly hold in the semiclassical case in which no coherence is generated by the driving, and finally we discuss the noncommuting case.
Quantum coherence has been demonstrated in various systems including organic solar cells and solid state devices. In this article, we report the lower and upper bounds for the performance of quantum heat engines determined by the efficiency at maximum power. Our prediction based on the canonical three-level Scovil and Schulz-Dubois maser model strongly depends on the ratio of system-bath couplings for the hot and cold baths and recovers the theoretical bounds established previously for the Carnot engine. Further, introducing a fourth level to the maser model can enhance the maximal power and its efficiency, thus demonstrating the importance of quantum coherence in the thermodynamics and operation of the heat engines beyond the classical limit.
The two-level quantum heat engines have been studied extensively. Before that, the optimization of most heat engines was mainly concentrated in non-degenerate cases. We consider the level degeneracy, then calculate the maximum operation time and the irreversible dissipation coefficient of the two-level system under the scheme of linear tuned levels. In the high-temperature limit, we find that the level degeneracy affects the maximum power of the two-level heat engine. Especially in the case of the same degeneracy of the ground state and the excited state, the influence is the greatest. In addition, we also show that the degeneracy does not affect the efficiency at maximum power and the consistent relation of the two-level Carnot-like heat engine.
Conventional continuous quantum heat engines with incoherent heat transfer perform poorly as they exploit two-body interactions between the system and hot or cold baths, thus having limited capability to outperform their classical counterparts. We introduce distinct continuous quantum heat engines that utilize coherent heat transfer with baths, yielding genuine quantum enhancement in performance. These coherent engines consist of one qutrit system and two photonic baths and enable coherent heat transfer via two-photon transitions involving three-body interactions between the system and hot and cold baths. We demonstrate that coherent engines deliver significantly higher power output with much greater reliability, i.e., lower signal-to-noise ratio of the power, by hundreds of folds over their incoherent counterparts. Importantly, coherent engines can operate close to or at the maximal achievable reliability allowed by the quantum thermodynamic uncertainty relation. Moreover, coherent engines manifest more nonclassical features than incoherent engines because they violate the classical thermodynamic uncertainty relation by a greater amount and for a wider range of parameters. These genuine enhancements in the performance of coherent engines are directly attributed to their capacity to harness higher energetic coherence for the resonant driving case. The experimental feasibility of coherent engines and the improved understanding of how quantum properties can enhance performance may find applications in quantum enabled technologies.