For a certain class of isolated quantum systems, we report the existence of irreversible processes in which the energy is not dissipated. After a closed cycle in which the initial energy distribution is fully recovered, the expectation value of a symmetry-breaking observable changes from a value differing from zero in the initial state to zero in the final state. This entails the unavoidable loss of a certain amount of information and constitutes a source of irreversibility. We show that the von Neumann entropy of time-averaged equilibrium states increases in the same magnitude as a consequence of the process. We support this result by means of numerical calculations in an experimentally feasible system, the Lipkin-Meshkov-Glick model.
For a certain class of isolated quantum systems, we report the existence of irreversible processes in which the energy is not dissipated. After a closed cycle in which the initial energy distribution is fully recovered, the expectation value of a symmetry-breaking observable changes from a value differing from zero in the initial state to zero in the final state. This entails the unavoidable loss of a certain amount of information and constitutes a source of irreversibility. We show that the von Neumann entropy of time-averaged equilibrium states increases in the same magnitude as a consequence of the process. We support this result by means of numerical calculations in an experimentally feasible system, the Lipkin-Meshkov-Glick model.
We report a kind of phase transition which takes place in isolated quantum systems with a discrete symmetry. Different phases are separated by a critical energy and recognized by means of an order parameter, which can be experimentally measured. Below the critical energy, the symmetry is broken and the equilibrium state is non-thermal, keeping large amounts of memory of the initial condition. Above, the symmetry is restored and a thermal equilibrium state is reached. We identify two universality classes, one showing a second-order phase transition and represented by the Lipkin-Meshkov-Glick model, and another showing a first-order phase transition and represented by the Dicke model. This work is dedicated to the memory of Joaquín Retamosa .
The second law of thermodynamics states that the entropy of an isolated system can only increase over time. This appears to conflict with the reversible evolution of isolated quantum systems under the Schrödinger equation, which preserves the von Neumann entropy. Nonetheless, one finds that with respect to many observables, expectation values approach a fixed value—their equilibrium value. This ultimately raises the question: ? For classical systems, one introduces the assumption of a low-entropy initial state along with the concept of ignorance about the microscopic details of the physical system, leading to a statistical interpretation of the second law. By considering the observables through which we examine quantum systems, both these assumptions can be incorporated, building upon recent studies of the of observables. While the statistical behavior of observable expectation values is well established, a quantitative connection to entropy increase has been lacking so far. In deriving novel bounds for the equilibration of observables, and considering the entropy of the system relative to observables, we recover a variant of the second law: the entropy with respect to a given observable tends toward its equilibrium value in the course of the system’s unitary evolution. These results also support recent findings that question the necessity of nonintegrability for equilibration in quantum systems. We further illustrate our bounds using numerical results from the paradigmatic example of a quantum Ising model on a chain of spins. There, we observe entropy increasing up to equilibrium values, as well as fluctuations, which expose the underlying reversible evolution in accordance with the derived bounds.
The irreversibility and thermalization of many-body systems can be attributed to the erasure of spread non-equilibrium state information by local operations. This thermalization mechanism can be demonstrated by the sequence of O^i(ti), where Oi^ is a local operator, Oi^(ti)=eiH^tiOi^e−iH^ti, H^ is the system Hamiltonian, ti can take positive, negative, or zero values, and the sequence is arranged according to the subscript i. We numerically demonstrate the information erasure of initial non-equilibrium quantum states through such sequence in a one-dimensional Hubbard model. During this process, the system's entanglement entropy increases monotonically toward a stable value. By incorporating this information erasure mechanism into an isolated system, our numerical simulations reveal that in this completely isolated system, a thermalization process emerges.
In this contribution we prove that the entropy of an N-body isolated system can not decrease and the entropy production should be non-negative provided the system possesses an equilibrium state. We define the entropy as a functional of the set of n-particle reduced density operators (n=0,....,N) generalizing the von Neumann fine-grained entropy formula. Additionally, as a consequence of our analysis we find the expression of the equilibrium n-particle reduced density operators which enter the definition of the entropy as well as the dissipated energy in an irreversible process.
Abstract We consider the temporal evolution of an isolated system of N particles from a non-equilibrium state of entropy S = S′ to the equilibrium state of maximum entropy, S = S max, S′ ≤ S max. The application of usual density matrix theory to the temporal development of S leads us to dS/dt = 0: The entropy S does not change in time t. Thereby it is irrelevant, whether we consider a non-equilibrium state or an equilibrium state. Consequently, the system cannot irreversibly change by entropy production dS/dt > 0 from S′ to S max. This is a paradoxial result, which contradicts the experience. It can be traced back to the von Neumann equation, which in principle describes reversible processes and hence is unsuitable for calculating the irreversible evolution of the entropy S in time t. Each irreversible process is accompanied by a positive entropy production P = dS/dt ≥ 0 inside the system, which only vanishes in case of the equilibrium state. In order to overcome the above mentioned difficulties, we assign an operator P to the entropy production P, which is defined by the eigenvalue equation P |u〉 = P|u〉 with the state vector |u〉 of the N-particle system. There was an extensive discussion about the relation between the production of entropy P on one hand and the progression of time t on the other. Making use of this concept, we combine the operator of entropy production P with the time-development operator U (t, t 0) of the system and finally deduce the infinitesimal unitary operator U (t+τ,t) = 1 + (i/k)τ P by means of very general assumptions. Here P means the generator of the infinitesimal progression of time τ = t − t 0 and k the Boltzmann constant, representing the atomic entropy unit. Similarly to P we also treat the time t as an observable, defined by t |u〉 = t|u〉. We apply the infinitesimal time-evolution operator U (t+τ,t) to the operator of time t and finally obtain the P – t commutation relation i[ P , t ] = k, which is independent of τ. It shows that the operators P and t do not commute, and hence P and t are not sharply defined simultaneously. Instead we have uncertainties ΔP and Δt on measuring P and t, which are given by the P–t uncertainty relation ΔPΔt ≥ k/2. It readily allows a discussion of the evolution of the entropy S of the isolated system in time t from S′ to S max. Now, the irreversible steps are correctly described by the entropy production P = dS/dt > 0, while the thermal equilibrium is given by P = 0, ΔP = 0, and thus the lifetime of the equilibrium state Δt = ∞. According to the P–t uncertainty relation, the Boltzmann constant k is similarly important to the quantum thermodynamics of irreversible processes like Planck′s constant h to usual quantum mechanics.
It is shown that nuclear matter described by quasispin or pseudospin operators may exhibit irreversible behavior, in the sense of modern kinetic theory. With the help of the group-contraction technique, a harmonic oscillator can be associated to the many-body system and it is seen that in the standard Lipkin-Meshkov-Glick model the ground-state phase transition gives rise to a significant change in the spectral properties of the characteristic operators. This fact makes room for the introduction of the microscopic operators of irreversible dynamics. Their meaning and the consequences of their existence are examined and it is seen that the time evolution of the quasispin arrangement closely resembles the approach to equilibrium of a macroscopic system.NUCLEAR STRUCTURE Operators of irreversible Hamiltonian dynamics; quasispin nuclear matter; group contraction, Lipkin-Meshkov-Glick model; ground-state phase transition; entropy; irreversible approach to equilibrium.