Passive states of quantum systems are states from which no system energy can be extracted by any cyclic (unitary) process. Gibbs states of all temperatures are passive. Strong local (SL) passive states are defined to allow any general quantum operation, but the operation is required to be local, being applied only to a specific subsystem. Any mixture of eigenstates in a system-dependent neighborhood of a nondegenerate entangled ground state is found to be SL passive. In particular, Gibbs states are SL passive with respect to a subsystem only at or below a critical system-dependent temperature. SL passivity is associated in many-body systems with the presence of ground state entanglement in a way suggestive of collective quantum phenomena such as quantum phase transitions, superconductivity, and the quantum Hall effect. The presence of SL passivity is detailed for some simple spin systems where it is found that SL passivity is neither confined to systems of only a few particles nor limited to the near vicinity of the ground state.
Passive states of quantum systems are states from which no system energy can be extracted by any cyclic (unitary) process. Gibbs states of all temperatures are passive. Strong local (SL) passive states are defined to allow any general quantum operation, but the operation is required to be local, being applied only to a specific subsystem. Any mixture of eigenstates in a system-dependent neighborhood of a nondegenerate entangled ground state is found to be SL passive. In particular, Gibbs states are SL passive with respect to a subsystem only at or below a critical system-dependent temperature. SL passivity is associated in many-body systems with the presence of ground state entanglement in a way suggestive of collective quantum phenomena such as quantum phase transitions, superconductivity, and the quantum Hall effect. The presence of SL passivity is detailed for some simple spin systems where it is found that SL passivity is neither confined to systems of only a few particles nor limited to the near vicinity of the ground state.
Local energy in a component of a multipartite quantum system is the maximum energy that can be extracted by a general (Kraus, operator-sum) local operation on just that component. A component’s local energy is greater or less, or even completely absent, depending on extant correlations with the system’s other components. This is illustrated in different cases of quantum systems of spin-1/2 particles. These cases include a class of two-particle systems with different degrees of coupling anisotropy, three-particle systems, and systems of N particles, generally, with ring and star coupling topologies. Conditions are given in each case for zero local energy. Th3ese conditions establish for each case that, fir systems with a non-degenerate entangled ground state, local energy is absent when the system state is anywhere in a neighborhood of the ground state when the temperature is below critical value in a Gibbs thermal state even systems of many particles.
We examine when it is possible to locally extract energy from a bipartite quantum system in the presence of strong coupling and entanglement, a task which is expected to be restricted by entanglement in the low-energy eigenstates. We fully characterize this distinct notion of "passivity" by finding necessary and sufficient conditions for such extraction to be impossible, using techniques from semidefinite programing. This is the first time in which such techniques are used in the context of energy extraction, which opens a way of exploring further kinds of passivity in quantum thermodynamics. We also significantly strengthen a previous result of Frey et al., by showing a physically relevant quantitative bound on the threshold temperature at which this passivity appears. Furthermore, we show how this no-go result also holds for thermal states in the thermodynamic limit, provided that the spatial correlations decay sufficiently fast, and we give numerical examples.
Passive states are special configurations of a quantum system which exhibit no energy decrement at the end of an arbitrary cyclic driving of the model Hamiltonian. When applied to an increasing number of copies of the initial density matrix, the requirement of passivity induces a hierarchical ordering which, in the asymptotic limit of infinitely many elements, pinpoints ground states and thermal Gibbs states. In particular, for large values of N the energy content of a N -passive state which is also structurally stable (i.e. capable to maintain its passivity status under small perturbations of the model Hamiltonian), is expected to be close to the corresponding value of the thermal Gibbs state which has the same entropy. In the present paper we provide a quantitative assessment of this fact, by producing an upper bound for the energy of an arbitrary N -passive, structurally stable state which only depends on the spectral properties of the Hamiltonian of the system. We also show the condition under which our inequality can be saturated. A generalization of the bound is finally presented that, for sufficiently large N , applies to states which are N -passive, but not necessarily structurally stable.
We give a simple and intuitive proof that the only states which are completely passive, i.e., those states from which work cannot be extracted even with infinitely many copies, are Gibbs states at positive temperatures. The proof makes use of the idea of virtual temperatures, i.e., the association of temperatures to pairs of energy levels (transitions). We show that (1) passive states are those where every transition is at a positive temperature and (2) completely passive states are those where every transition is at the same positive temperature.
Passive states, i.e., those states from which no work can be extracted via unitary operations, play an important role in the foundations and applications of quantum thermodynamics. They generalize the familiar Gibbs thermal states, which are the sole passive states being stable under tensor product. Here, we introduce a partial order on the set of passive states that captures the idea of a passive state being virtually cooler than another one. This partial order, which we build by defining the notion of relative passivity, offers a fine-grained comparison between passive states based on virtual temperatures (just like thermal states are compared based on their temperatures). We then characterize the quantum operations that are closed on the set of virtually cooler states with respect to some fixed input and output passive states. Viewing the activity, i.e., nonpassivity, of a state as a resource, our main result is then a necessary and sufficient condition on the transformation of a class of pure active states under these relative passivity-preserving operations. This condition gives a quantum thermodynamical meaning to the majorization relation on the set of nonincreasing vectors due to Hoffman. The maximum extractable work under relative passivity-preserving operations is then shown to be equal to the ergotropy of these pure active states. Finally, we are able to fully characterize passivity-preserving operations in the simpler case of qubit systems, and hence to derive a state interconversion condition under passivity-preserving qubit operations. The prospect of this work is a general resource-theoretical framework for the extractable work via quantum operations going beyond thermal operations.
The second law of thermodynamics states that work cannot be extracted from thermal equilibrium, whose quantum formulation is known as complete passivity; a state is called completely passive if work cannot be extracted from any number of copies of the state by any unitary operations.It has been established that a quantum state is completely passive if and only if it is a Gibbs ensemble.In physically plausible setups, however, the class of possible operations is often restricted by fundamental constraints such as symmetries imposed on the system.In the present work, we investigate the concept of complete passivity under symmetry constraints.Specifically, we prove that a quantum state is completely passive under a symmetry constraint described by a connected compact Lie group, if and only if it is a generalized Gibbs ensemble including conserved charges associated with the symmetry.Remarkably, our result applies to noncommutative symmetry such as SU(2) symmetry, suggesting an unconventional extension of the notion of generalized Gibbs ensemble.Furthermore, we consider the setup where a quantum work storage is explicitly included, and prove that the characterization of complete passivity remains unchanged.Our result extends the notion of thermal equilibrium to systems protected by symmetries, and would lead to flexible design principles of quantum heat engines and batteries.Moreover, our approach serves as a foundation of the resource theory of thermodynamics in the presence of symmetries.