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arXiv:1403.5216 · Physical Review A

Anisotropic atom-surface interactions in the Casimir-Polder regime

Thierry Taillandier-Loize, J. Baudon, G. Dutier, F. Perales, M. Boustimi, M. Ducloy

Published May 19, 2014• 9 citations
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Abstract

The distance dependence of the anisotropic atom-wall interaction is studied. The central result is the $1/{z}^{6}$ quadrupolar anisotropy decay in the retarded Casimir-Polder regime. Analysis of the transition region between nonretarded van der Waals regime (in $1/{z}^{3}$) and Casimir-Polder regime shows that the anisotropy crossover occurs at very short distances from the surface, on the order of $0.03\ensuremath{\lambda}$, where $\ensuremath{\lambda}$ is the atom characteristic wavelength. Possible experimental verifications of this distance dependence using surface-induced inelastic transitions are discussed.

DOI
10.1103/physreva.89.052514

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The distance dependence of the anisotropic atom-wall interaction is studied. The central result is the 1/z61/{z}^{6}1/z6 quadrupolar anisotropy decay in the retarded Casimir-Polder regime. Analysis of the transition region between nonretarded van der Waals regime (in 1/z31/{z}^{3}1/z3) and Casimir-Polder regime shows that the anisotropy crossover occurs at very short distances from the surface, on the order of 0.03\ensuremathλ0.03\ensuremath{\lambda}0.03\ensuremathλ, where \ensuremathλ\ensuremath{\lambda}\ensuremathλ is the atom characteristic wavelength. Possible experimental verifications of this distance dependence using surface-induced inelastic transitions are discussed.
This chapter deals with atom-wall interaction occurring in the "long-range" regime (typical distances: 1-1000 nm), when the electromagnetic fluctuations of an isolated atom are modified by the vicinity with a surface. Various regimes of interaction are discussed in an Introductory part, from Cavity Quantum ElectroDynamics modifications of the spontaneous emission, to Casimir effect, with emphasis on the atom-surface van der Waals interaction, characterized as a near-field interaction governed by a z-3 dependence. The major part of the Chapter focuses on the experimental measurements of this van der Waals interaction, reviewing various recent techniques, and insists upon optical techniques, and notably selective reflection spectroscopy which is particularly well-suited when excited atoms are considered. A review of various experiments illustrates the specific effects associated with a resonant coupling between the atomic excitation and surface modes, from van der Waals repulsion to surface-induced resonant transfer, and with anisotropy effects, including metastability transfer induced by a quadrupole contribution in the interaction. The effects of a thermal excitation of the surface -with a possible remote energy transfer to an atom-, and of interaction with nanobodies -which are intrinsically non planar- are notably discussed among the prospects.
The modification of quantum fluctuations by a surface of finite reflectivity shifts the energy levels of atoms and changes their radiative properties (Casimir-Polder effect). At nanometric distances away from a surface (near field), the Casimir-Polder energy shift is given by −C3/z3 (where C3 is the van der Waals coefficient and z is the atom-surface distance) corresponding to the interaction of the fluctuating atomic dipole with its surface induced image. Near field Rydberg-surface interactions are of fundamental interest because the atomic size, scaling as n∗2 (where n∗ is the principle quantum number corrected by the quantum defect), is no longer negligible compared to the atom-surface separation, z. In this case, the dipole approximation, (−C3/z3 law of interaction), is no longer valid and higher-order terms, corresponding to the interaction of the fluctuation quadrupole with its own image, need to be taken into account. Quadrupole interaction terms in the atom-surface interaction manifest themselves with a novel distance dependence of z5 that has not been experimentally investigated yet1. Casimir-Polder experiments were first performed with low-lying Rydberg states (n= 10-14), demonstrating the −C3/z3 law of interaction2. Nevertheless, more recent experiments with high-lying rubidium Rydbergs (n=32-43)3 were not in agreement with Casimir-Polder theory thus highlighting the need for further experimental studies.
The 1%-accurate calculations of the van der Waals interaction between an atom and a cavity wall are performed in the separation region from 3nmto150nm3\phantom{\rule{0.3em}{0ex}}\mathrm{nm}\phantom{\rule{0.3em}{0ex}}\text{to}\phantom{\rule{0.3em}{0ex}}150\phantom{\rule{0.3em}{0ex}}\mathrm{nm}3nmto150nm. The cases of metastable He∗{\mathrm{He}}^{*}He∗ and Na atoms near metal, semiconductor, and dielectric walls are considered. Different approximations to the description of wall material and atomic dynamic polarizability are carefully compared. The smooth transition to the Casimir-Polder interaction is verified. It is shown that to obtain accurate results for the atom-wall van der Waals interaction at short separations with an error less than 1% one should use the complete optical-tabulated data for the complex refractive index of the wall material and the accurate dynamic polarizability of an atom. The obtained results may be useful for the theoretical interpretation of recent experiments on quantum reflection and Bose-Einstein condensation of ultracold atoms on or near surfaces of different kinds.
The Casimir-Polder (C-P) interaction between an atom and a surface, described as early as 1948, but observed much later on, is now a topic of broad interest, as connected to fundamental problems of quantum fluctuations, with the atomic energy levels renormalized by the wall-dependent vacuum fluctuations. Dependence of the C-P interaction with the equilibrium temperature is predicted, but had not been observed until now. However, more pronounced effects were predicted in an out-of-equilibrium situation, and were remarkably observed on a Rb BEC, at 6-10 μm from the wall, with the vacuum temperature (~ 300K) strongly differing from the surface temperature (~ 1000 K).
At nanometer separation, the dominant interaction between an atom and a material surface is the fluctuation-induced Casimir-Polder potential. We demonstrate that slow atoms crossing a silicon nitride transmission nanograting are a remarkably sensitive probe for that potential. A 15% difference between nonretarded (van der Waals) and retarded Casimir-Polder potentials is discernible at distances smaller than 51 nm. We discuss the relative influence of various theoretical and experimental parameters on the potential in detail. Our work paves the way to high-precision measurement of the Casimir-Polder potential as a prerequisite for understanding fundamental physics and its relevance to applications in quantum-enhanced sensing.