We investigate temporal evolution of von Neumann's entropy in exemplary quantum mechanical systems and show that it grows in systems evolving with incrementally increasing decoherence during scattering processes. We demonstrate that the origin of irreversibility lies in complexity of preparing time-reversed quantum states due to entanglement and in partitioning of the wave function of the evolving system.
We investigate temporal evolution of von Neumann's entropy in exemplary quantum mechanical systems and show that it grows in systems evolving with incrementally increasing decoherence during scattering processes. We demonstrate that the origin of irreversibility lies in complexity of preparing time-reversed quantum states due to entanglement and in partitioning of the wave function of the evolving system.
The problem of time’s arrow is (roughly) to understand why macroscopic physical processes typically evolve in a specific direction (the one we call “the future”) even though the underlying laws of physics describing the individual microscopic systems are time-reversal invariant. The standard answer to this problem is given by Boltzmann’s explanation of the II law of thermodynamics: a classical system starting in a non-equilibrium state spontaneously (i.e. with a high level of probability) tends towards equilibrium, thus implementing an irreversible process. However, this explanation has two drawbacks: 1. it needs a further assumption on the entropy of the initial state of the universe (past hypothesis); 2. microscopic systems (e.g. molecules in a box) should be represented as quantum states and not classical states. In this talk, I want to propose a different hypothesis to explain the origin of time’s arrow, based on quantum mechanics, specifically on decoherence theory. Differently from isolated systems, open quantum systems described by decoherence theory showirreversible behavior, as they evolve towards decoherence and von Neumann entropy increase. Is this behavior a sign of genuine irreversibility? And, if so, can this be linked to thermodynamic irreversibility?
The concept of time presents a profound challenge at the intersection of quantum mechanics and thermodynamics. While fundamental microscopic laws are largely time-symmetric, macroscopic phenomena universally exhibit a distinct thermodynamic arrow of time, characterized by increasing entropy. This paper explores the hypothesis that quantum entanglement plays a crucial role in the emergence of this thermodynamic arrow. We review how the entanglement between a quantum system and its environment leads to decoherence, effectively driving the system towards a state of higher entropy and classical-like behavior. By analyzing concepts such as von Neumann entropy, entanglement entropy, and the Page-Wootters mechanism, we propose a theoretical framework where the degradation and spreading of entanglement act as the underlying mechanism for the perceived unidirectional flow of time. This approach offers a potential resolution to the "problem of time" in quantum gravity and provides a unified perspective on the genesis of irreversibility from the inherently reversible laws of quantum mechanics. We discuss the implications of this entanglement-driven temporal emergence for our understanding of the universe's initial low-entropy state and the fundamental nature of reality.
This work investigates the fundamental connection between quantum mechanics and thermodynamics through the concept of the arrow of time. While the second law of thermodynamics identifies the arrow of time with the monotonic increase of entropy in isolated systems, closed quantum systems evolve unitarily and conserve von Neumann entropy, making the origin of irreversibility less apparent. Here we establish a no-go theorem proving that correlations in unknown states of closed quantum systems cannot be universally removed by any physical operation. This result demonstrates that correlation generation is inherently irreversible, providing a microscopic and universal basis for the arrow of time. In thermodynamic settings, this irreversibility ensures that heat flows spontaneously from hotter to colder subsystems, reproducing the Clausius formulation of the second law. More generally, the irreversible growth of correlations explains entropy increase, the approach to equilibrium, and decoherence as observable manifestations of the same principle. Our findings ground a quantum-mechanical foundation for the second law of thermodynamics and demonstrate the universality of the arrow of time.
Time asymmetry and irreversibility are signal features of our world. They are the reason of our aging and the basis for our belief that effects are preceded by causes. These features have many manifestations called arrows of time. In classical physics, some of these arrows are described by the increase of entropy or probability, and others by time‐asymmetric boundary conditions of time‐symmetric equations (e.g., Maxwell or Einstein). However, there is some controversy over whether probability or boundary conditions are more fundamental. For quantum systems, entropy increase is usually associated with the effects of an environment or measurement apparatus on a quantum system and is described by the von Neumann‐Liouville equation. But since the traditional (von Neumann) axioms of quantum mechanics do not allow time‐asymmetric boundary conditions for the dynamical differential equations (Schrödinger or Heisenberg), there is no quantum analogue of the radiation arrow of time. In this paper, we review consequences of a modification of a fundamental axiom of quantum mechanics. The new quantum theory is time asymmetric and accommodates an irreversible time evolution of isolated quantum systems.
Moscow Institute of Physics and Technology, Institutskii per. 9, Dolgoprudny, 141700, Moscow Region, Russia(Dated: July 17, 2014)Boltzmann’s H-theorem stating that entropy of a physical system would tend to increase overtime remains a foundation of thermodynamics. Original Boltzmann’s formulation given for classicalgases was resting on the molecular chaos hypothesis. Von Neumann’s quantum H-theorem claimedquantum origin of irreversibility but included as a part of the proof macroscopic measurement pro-cedure going thus beyond the strictly quantum consideration. Recent developments related entropygrowth to quantum entanglement hinting the solely quantum origin of macroscopic irreversibility.In particular, progress in quantum informatics brought in several rigorous results on the conditionsfor the non-negative entropy gain, however, many questions of how to adapt them to the realm ofphysics remain. Utilizing the mathematical formalism, we show that entanglement of electrons witheither electromagnetic environment or phonon bath results in the evolution of the electron densitymatrix that belong in the classes of evolution described in quantum informatics. Using exemplaryphysical systems we formulate and prove the H-theorem for a wide class of physical phenomena.1. INTRODUCTION
It has been shown that time reversal symmetry breaking in the dynamics of large systems originates from symmetry breaking in the occupation of the Hilbert space. The states ϕ, for which the entropy of the system (sub-system) increases, are automatically created in nature or can be prepared experimentally, in contrast to the respective complex-conjugate states (ϕ*), for which the entropy decreases (although formally, according to the superposition principle, they can exist). It is indicated that, in the general case, the dynamics reversal of unknown states is impossible because the complex conjugation operator is antilinear. The complexity of reversal of the known state is exponential in the typical case of a large system. The formulated statements are illustrated by simple models.