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arXiv:1312.6570 · Physical Review E

Equivalence of two Bochkov-Kuzovlev equalities in quantum two-level systems

Fei Liu

Published Apr 14, 2014• 27 citations
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Abstract

We present two kinds of Bochkov-Kuzovlev work equalities in a two-level system that is described by a quantum Markovian master equation. One is based on multiple time correlation functions and the other is based on the quantum trajectory viewpoint. We show that these two equalities are indeed equivalent. Importantly, this equivalence provides us a way to calculate the probability density function of the quantum work by solving the evolution equation for its characteristic function. We use a numerical model to verify these results.

DOI
10.1103/physreve.89.042122

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We present two kinds of Bochkov-Kuzovlev work equalities in a two-level system that is described by a quantum Markovian master equation. One is based on multiple time correlation functions and the other is based on the quantum trajectory viewpoint. We show that these two equalities are indeed equivalent. Importantly, this equivalence provides us a way to calculate the probability density function of the quantum work by solving the evolution equation for its characteristic function. We use a numerical model to verify these results.
We briefly introduce the quantum Jarzynski and Bochkov-Kuzovlev equalities in isolated quantum Hamiltonian systems, which includes the origin of the equalities, their derivations using a quantum Feynman-Kac formula, the quantum Crooks equality, the evolution equations governing the characteristic functions of the probability density functions for the quantum work, the recent experimental verifications. Some results are given here first time. We particularly emphasize the formally structural consistence between these quantum equalities and their classical counterparts, which shall be useful in understanding the existing equalities and pursuing new fluctuation relations in other complex quantum systems.
We present a characteristic function method to calculate the probability density functions of the inclusive work in adiabatic two-level quantum Markovian master equations. These systems are steered by some slowly varying parameters and the dissipations may depend on time. Our theory is based on the interpretation of the quantum jump for the master equations. In addition to the calculation, we also find that the fluctuation properties of the work can be described by the symmetry of the characteristic functions, which is exactly the same as in the case of isolated systems. A periodically driven two-level model is used to demonstrate the method.
The quantum version of the Bochkov-Kuzovlev identity is derived on the basis of the appropriate definition of work as the difference of the measured internal energies of a quantum system at the beginning and the end of an external action on the system given by a prescribed protocol. According to the spirit of the original Bochkov-Kuzovlev approach, we adopt the 'exclusive' viewpoint, meaning that the coupling to the external work source is not counted as part of the internal energy. The corresponding canonical and microcanonical quantum fluctuation theorems are derived as well, and are compared with the respective theorems obtained within the 'inclusive' approach. The relations between the quantum inclusive work w, the exclusive work w(0) and the dissipated work w(dis), are discussed and clarified. We show by an explicit example that w(0) and w(dis) are distinct stochastic quantities obeying different statistics.
I present a technical report indicating that the two methods used for calculating characteristic functions for the work distribution in weakly driven quantum master equations are equivalent. One involves applying the notion of quantum jump trajectory [Phys. Rev. E 89, 042122 (2014)PLEEE81539-375510.1103/PhysRevE.89.042122], while the other is based on two energy measurements on the combined system and reservoir [Silaev et al., Phys. Rev. E 90, 022103 (2014)PLEEE81539-375510.1103/PhysRevE.90.022103]. These represent backward and forward methods, respectively, which adopt a very similar approach to that of the Kolmogorov backward and forward equations used in classical stochastic theory. The microscopic basis for the former method is also clarified. In addition, a previously unnoticed equality related to the heat is also revealed.
As quantum systems become more experimentally accessible, we are forced to reconsider the notions of control and work to fully account for quantum effects. To this end, we identify the work injected into a quantum system during a general quantum-mechanical driving protocol and quantify the relevant heat flows. The known results that are applicable in the limit of a classical drive are shown to emerge from our equations as a special case. Using the established framework, we show that the Bochkov-Kuzovlev identity for the exclusive work distribution is modified in a nontrivial way by the accumulation of system-drive correlations resulting from quantum back action. Our results accentuate the conceptual and discernible differences between a fully quantum-mechanical and classical driving protocols of quantum systems.