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arXiv:1312.2419 · International Journal of Modern Physics C

Wave packet dynamics of an atomic ion in a Paul trap

A. Hashemloo, Claude M. Dion, G. Rahali

Published Jul 13, 2015• 10 citations
arXivHTMLPDF

Abstract

Using numerical simulations of the time-dependent Schrödinger equation, we study the full quantum dynamics of the motion of an atomic ion in a linear Paul trap. Such a trap is based on a time-varying, periodic electric field and hence corresponds to a time-dependent potential for the ion, which we model exactly. We compare the center-of-mass motion with that obtained from classical equations of motion, as well as to results based on a time-independent effective potential. We also study the oscillations of the width of the ion’s wave packet, including close to the border between stable (bounded) and unstable (unbounded) trajectories. Our results confirm that the center-of-mass motion always follows the classical trajectory, that the width of the wave packet is bounded for trapping within the stability region, and therefore that the classical trapping criterion is fully applicable to quantum motion.

DOI
10.1142/s0129183116500145

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Using numerical simulations of the time-dependent Schrödinger equation, we study the full quantum dynamics of the motion of an atomic ion in a linear Paul trap. Such a trap is based on a time-varying, periodic electric field and hence corresponds to a time-dependent potential for the ion, which we model exactly. We compare the center-of-mass motion with that obtained from classical equations of motion, as well as to results based on a time-independent effective potential. We also study the oscillations of the width of the ion’s wave packet, including close to the border between stable (bounded) and unstable (unbounded) trajectories. Our results confirm that the center-of-mass motion always follows the classical trajectory, that the width of the wave packet is bounded for trapping within the stability region, and therefore that the classical trapping criterion is fully applicable to quantum motion.
We study the quantum stability of the dynamics of ions in a Paul trap. We revisit previous results that showed that quantum trajectories did not have the same region of stability as their classical counterpart, contrary to what is obtained from a Floquet analysis of the motion in the periodic trapping field. Using numerical simulations of the full wave-packet dynamics, we confirm that the classical trapping criterion is fully applicable to quantum motion, when considering both the expectation value of the position of the wave packet and its width.
We investigate the quantum motion of two ions stored in a Paul trap and interacting with a time-periodic laser field. In the pseudopotential approximation and large detuning condition, we find that the relative motion is independent of the laser field, but the exact centre-of-mass motion is closely related to the laser field. By adjusting the laser intensity and frequency, we can well control the quantum motion of the centre-of-mass. We illustrate some physical properties described by the centre-of-mass states, such as the squeezed coherent property, the widths and heights of the wavepackets of probability density, the classical-quantum correspondence, the resonance ladders of expectation energy and the transition probabilities between time-dependent quantum levels.
We present models for a heteronuclear diatomic molecular ion in a linear Paul trap in a rigid-rotor approximation, one purely classical and the other where the center-of-mass motion is treated classically, while rotational motion is quantized. We study the rotational dynamics and their influence on the motion of the center-of-mass, in the presence of the coupling between the permanent dipole moment of the ion and the trapping electric field. We show that the presence of the permanent dipole moment affects the trajectory of the ion and that it departs from the Mathieu equation solution found for atomic ions. For the case of quantum rotations, we also evidence the effect of the above-mentioned coupling on the rotational states of the ion.
This thesis explores the dynamics of a heteronuclear diatomic molecular ion, possessing a permanent electric dipole moment, µ, which is trapped in a linear Paul trap and can interact with an off-resonance laser field. To build our model we use the rigid-rotor approximation, where the dynamics of the molecular ion are limited to its translational and rotational motions of the center-of-mass. These dynamics are investigated by carrying out suitable numerical calculations. To introduce our numerical methods, we divide our research topic into two different subjects. First, we ignore the rotational dynamics of the ion by assuming µ = 0. By this assumption, the system resembles an atomic ion, which mainly exhibits translational motion for its center of the mass when exposed to an external trapping field. To study this translational behavior, we implement full-quantum numerical simulations, in which a wave function is attributed to the ion. Finally, we study the quantum dynamics of the mentioned wave packet and we compare our results with those obtained classically. In the latter case, we keep the permanent dipole moment of the ion and we study the probable effects of the interaction between the dipole moment and the trapping electric field, on both the translational and the rotational dynamics of the trapped molecular ion. In order to study these dynamics, we implement both classical and semi-classical numerical simulations. In the classical method, the rotational and the translational motions of the center of mass of the ion are obtained via classical equations of motion. On the other hand, in the semi-classical method, while the translational motion of the center-of-mass is still obtained classically, the rotation is treated full-quantum mechanically by considering the rotational wave function of the ion. In the semi-classical approach, we mainly study the probable couplings between the rotational states of the molecular ion, due to the interaction of the permanent dipole moment with the trapping electric field. In the end, we also present a semi-classical model, where the trapped molecular ion interacts with an off-resonance laser field.
Large quantum uncertainties for the Paul trap are obtained near the stability border. These results are important as a trapped ion can be stored only as long as the fluctuations are smaller than the trap dimensions. Exact transition probabilities for the forced Paul trap and harmonic oscillator are also obtained based on a simplified version of the propagator for time-dependent harmonic oscillator. The results have important implications, e.g., the methods of mass spectrometry can be applied only in the region of small fluctuations, which can be calculated exactly by our method. The classical trajectory of a general forced harmonic oscillator is also calculated which may exhibit chaotic behavior.
We have studied the quantum and classical motions of a single Paul trapped ion interacting with a time-periodic laser field. By using the test-function method, we construct n exact solutions of quantum dynamics that describe the generalized squeezed coherent states with the expectation orbits being the corresponding classical ones. The space-time evolutions of the exact probability densities show some wavepacket trains. It is demonstrated analytically that by adjusting the laser intensity and frequency, we can control the center motions of the wavepacket trains. We also discuss the other physical properties such as the expectation value of energy, the widths and heights of the wavepackets, and the resonance loss of stability.