Quantum systems are invariably open, evolving under surrounding influences rather than in isolation. Standard open quantum system methods eliminate all information on the environmental state to yield a tractable description of the system dynamics. By incorporating a collective coordinate of the environment into the system Hamiltonian, we circumvent this limitation. Our theory provides straightforward access to important environmental properties that would otherwise be obscured, allowing us to quantify the evolving system-environment correlations. As a direct result, we show that the generation of robust system-environment correlations that persist into equilibrium (heralded also by the emergence of non-Gaussian environmental states) renders the canonical system steady state almost always incorrect. The resulting equilibrium states deviate markedly from those predicted by standard perturbative techniques and are instead fully characterized by thermal states of the mapped system-collective coordinate Hamiltonian. We outline how noncanonical system states could be investigated experimentally to study deviations from canonical thermodynamics, with direct relevance to molecular and solid-state nanosystems.
Quantum systems are invariably open, evolving under surrounding influences rather than in isolation. Standard open quantum system methods eliminate all information on the environmental state to yield a tractable description of the system dynamics. By incorporating a collective coordinate of the environment into the system Hamiltonian, we circumvent this limitation. Our theory provides straightforward access to important environmental properties that would otherwise be obscured, allowing us to quantify the evolving system-environment correlations. As a direct result, we show that the generation of robust system-environment correlations that persist into equilibrium (heralded also by the emergence of non-Gaussian environmental states) renders the canonical system steady state almost always incorrect. The resulting equilibrium states deviate markedly from those predicted by standard perturbative techniques and are instead fully characterized by thermal states of the mapped system-collective coordinate Hamiltonian. We outline how noncanonical system states could be investigated experimentally to study deviations from canonical thermodynamics, with direct relevance to molecular and solid-state nanosystems.
Quantum systems are invariably open, evolving under surrounding influences rather than in isolation. Standard open quantum system methods eliminate all information on the environmental state to yield a tractable description of the system dynamics. By incorporating a collective coordinate of the environment into the system Hamiltonian, we circumvent this limitation. Our theory provides straightforward access to important environmental properties that would otherwise be obscured, allowing us to quantify the evolving system-environment correlations. As a direct result, we show that the generation of robust system-environment correlations that persist into equilibrium (heralded also by the emergence of non-Gaussian environmental states) renders the canonical system steady-state almost always incorrect. The resulting equilibrium states deviate markedly from those predicted by standard perturbative techniques and are instead fully characterised by thermal states of the mapped system-collective coordinate Hamiltonian. We outline how noncanonical system states could be investigated experimentally to study deviations from canonical thermodynamics, with direct relevance to molecular and solid-state nanosystems.
In this work we investigate the late-time steady states of open quantum systems coupled to a thermal reservoir in the strong coupling regime. In general such systems do not necessarily relax to a Boltzmann distribution if the coupling to the thermal reservoir is nonvanishing or equivalently if the relaxation time scales are finite. Using a variety of nonequilibrium formalisms valid for non-Markovian processes, we show that starting from a product state of the closed system = system+environment, with the environment in its thermal state, the open system which results from coarse graining the environment will evolve towards an equilibrium state at late times. This state can be expressed as the reduced state of the closed system thermal state at the temperature of the environment. For a linear (harmonic) system and environment, which is exactly solvable, we are able to show in a rigorous way that all multitime correlations of the open system evolve towards those of the closed system thermal state. Multitime correlations are especially relevant in the non-Markovian regime, since they cannot be generated by the dynamics of the single-time correlations. For more general systems, which cannot be exactly solved, we are able to provide a general proof that all single-time correlations of the open system evolve to those of the closed system thermal state, to first order in the relaxation rates. For the special case of a zero-temperature reservoir, we are able to explicitly construct the reduced closed system thermal state in terms of the environmental correlations.
We study the role of correlations with the environment as the source of non-Markovian quantum evolutions. We first focus on the impact that correlations with the environment can have on the dynamical map that evolve the system. We expand the set of initial states of a system and its environment that are known to guarantee completely positive reduced dynamics for the system when the combined state evolves unitarily. We characterize the correlations in the initial state in terms of its quantum discord. The induced maps can be not completely positive when quantum correlations including, but not limited to, entanglement are present. We discuss the implications and limitations of the Markov approximation necessary to derive the Kossakowski-Lindblad master equation. A generalized non-Markovian master equation is derived from the dynamical map of systems correlated with their environment. The physical meaning of not completely positive maps is studied to obtain a consistent theory of non-Markovian quantum dynamics. These are associated to inverse maps necessary to establish correlations and they give rise to a canonical embedding map that is local in time. This master equation goes beyond the Kossakowski-Lindblad master equation. Non-equilibrium quantum thermodynamics can be be studied within this theory. Through out this discussion, the general dynamics of two interacting qubits is used as an example for illustrations.
In this thesis, we discuss aspects of the simulation, characterisation, and control of the dynamics of open quantum systems. The latter are systems governed by quantum mechanical laws and interacting with an environment, which is typically much larger than the system itself. According to the standard approach, one is usually able to perform a suitable average over the environmental degrees of freedom, resulting in an effective description of the main system dynamics, which accounts for the effects of the interaction with the surroundings. In standard scenarios, usually studied within the so-called Born-Markov approximation, the system-environment coupling is weak and such that we can perform a neat separation of timescales: the environmental dynamics is assumed to be fast compared to the typical evolution timescale of the system of interest. However, nowadays we are able to inspect physical scenarios where the usual Born-Markov approximation breaks down: the interaction between system and environment can be strong, likely leading to non-negligible memory (non-Markovian) effects. In this work, we discuss some instances in which we cannot work in the standard Born-Markov regime. We introduce and analyse some numerical and analytical techniques to characterise and simulate non-standard scenarios. We show that, even in the Markovian regime, the traditional formulation of thermodynamic irreversibility shows flaws and inconsistencies. We thus use phase-space methods to assess the role of initial correlations shared by the two parties of a bipartite harmonic system in the entropy production rate, including non-Markovian effects. Furthermore, we show that certain interactions enable to redraw the boundaries between the system and the environment in an effective manner, resulting in a new picture where the system degrees of freedom are augmented, while the residual environment is rearranged in such a way that the Born-Markov approximation is recovered. This analytical technique, known as reaction coordinate mapping approach, is employed in this work to show that, upon an accurate choice of the parameter regime, a spin-boson model can serve as a quantum analogue simulator of non-Markovian multiphoton Jaynes-Cummings models. These systematic studies shed light on the thermodynamic characterisation of open quantum systems, as well as on their numerical simulation.
Quantum systems are inherently open to their environment and thus they evolve under the influence of dissipation, decoherence and driving from external fields. This poses a significant theoretical challenge: how to track the dynamics of the system of interest while tracing out environmental degrees of freedom. Markovian master equations offer a longstanding solution to this problem, where under a series of assumptions the reduced density matrix of the system can be obtained. These flexible approaches provide a conceptually and numerically simple framework for describing complex many-body systems. However, the assumptions enforced by Markovian master equations create a gap in the availability of generic, simple, and analytical techniques capable of treating open quantum systems beyond the regimes of standard Markovian master equations. In this thesis, we introduce three studies addressing three regimes that are inaccessible to standard Markovian master equations and investigate their consequences in quantum thermodynamics-inspired applications. We begin by developing a Markovian embedding technique to tackle non-Markovian dynamics induced by the long correlation times of a qubit coupled to a structured environment. Subsequently, we propose an "effective" Hamiltonian theory enabling the study of equilibrium properties of strong coupling to a thermal reservoir through a dressed version of the Gibbs state. This framework can also be applied to address problems of equilibration, transport, quantum thermal machines, and quantum dynamics. Lastly, we showcase the importance of including non-secular terms in the quantum master equation, which results in a drastic separation of timescales leading to rich metastable dynamics. We apply this quantum master equation approach to temperature sensing in a nonequilibrium setting offering an alternative to standard equilibrium probes. Overall, this thesis contributes novel theoretical techniques for tackling open quantum systems beyond standard approximations with applications in quantum thermodynamics.
Standard theoretical descriptions of the dynamics of open quantum systems rely on the assumption that the correlations with the environment can be neglected at some reference (initial) time. While being reasonable in specific instances, such as when the coupling between the system and the environment is weak or when the interaction starts at a distinguished time, the use of initially uncorrelated states is questionable if one wants to deal with general models, taking into account the mutual influence that the open-system and environmental evolutions perform on each other. Here we introduce a perturbative method that can be applied to any microscopic modeling of the system-environment interaction, including fully general initial correlations. Extending the standard technique based on projection operators that single out the relevant part of the global dynamics, we define a family of projections adapted to a convenient decomposition of the initial state, which involves a convex mixture of product operators with proper environmental states. This leads us to characterize the open-system dynamics via an uncoupled system of differential equations, which are homogeneous and whose number is limited by the dimensionality of the open system, for any kind of initial correlations. Our method is further illustrated by means of two case studies, for which it reproduces the expected dynamical behavior in the long-time regime more consistently than the standard projection technique.