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arXiv:1309.1787

Revisiting Dirac and Schrödinger: A Proof Offered for the Non-Relativistic Time-Dependent Schrödinger Equation

Sanayei, Ali

Published Sep 6, 2013• 1 citation
arXivHTMLPDF

Abstract

In this paper, three plausible axioms together with two definitions are employed to build an axiomatic framework, and then with the help of the Dirac formalism, it is demonstrated that the time-dependent Schrödinger wave equation is no longer a postulate for the whole theory, but a theorem. Subsequently, a proof for the theorem is presented. The result implies that the other remaining axioms of the picture essentially involve the Schrödinger equation, and this consequence lets the whole theory become stronger.

DOI
10.48550/arxiv.1309.1787

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In this paper, three plausible axioms together with two definitions are employed to build an axiomatic framework, and then with the help of the Dirac formalism, it is demonstrated that the time-dependent Schrödinger wave equation is no longer a postulate for the whole theory, but a theorem. Subsequently, a proof for the theorem is presented. The result implies that the other remaining axioms of the picture essentially involve the Schrödinger equation, and this consequence lets the whole theory become stronger.
The time dependent Schrodinger equation is frequently 'derived' by postulating the energy E → i ℏ(∂/∂ t ) and momentum → (ℏ/ i ) operator relations. In the present paper we review the quantum field theoretic route to the Schrodinger wave equation which treats time and space as parameters, not operators. Furthermore, we recall that a classical (nonlinear) wave equation can be derived from the classical action via Hamiltonian-Jacobi theory. By requiring the wave equation to be linear we again arrive at the Schrodinger equation, without postulating operator relations. The underlying philosophy is operational: namely 'a particle is what a particle detector detects.' This leads us to a useful physical picture combining the wave (field) and particle paradigms which points the way to the time-dependent Schrodinger equation.
An axiomatic approach to quantum mechanics that has, as a theorem, the Schrödinger equation may be of enormous value to cope with interpretation issues, since all the interpretation constructs must be present in the axioms, or directly derived by them from their mathematical unfolding. Thus, it is critical to show that this axiomatic derivation is reliable beyond any possible doubt. To show this, it is possible to make generalizations and extensions of the axioms to derive the Schrödinger equation in the underlying generalized or extended formats. In previous papers, we have shown that the axiomatic approach we propose can be used to derive the Schrödinger equation as a direct axiom. Since then, we have also shown that it was possible to generalize that derivation to coordinate systems other than the Cartesian, as well as its relativistic extensions that lead to the relativistic wave equations. An extension to dissipative systems was also performed, allowing us to mathematically derive the Caldirola–Kanai equation from first principles. All these derivations were performed using pure states and in the absence of the electromagnetic field. This means that we can further generalize the approach to embrace these two possibilities. Being an axiomatic approach, we show that we need only to slightly modify the axioms to derive the Schrödinger equation for these two contexts. Despite being quite direct, the algebraic complexity of these derivations should give the reader the desired confidence in the proposed axioms.
In non-relativistic quantum mechanics, there exist several different ways of describing the time dependence of dynamics of physical systems. Of particular importance for quantum scattering theory are the Schrodinger, Heisenberg and Dirac pictures. For establishing a connection between quantum mechanical formalisms and classical mechanics, as well as for investigating relativistic solutions, the Heisenberg picture appears to be the most convenient. This picture of quantum mechanics is particularly adapted for the examination of free fields. The customary wave-mechanical version of quantum theory is obtained if we choose, e.g., in the framework of the Schrodinger picture to work with the coordinate representation. Possible results of measurements on a quantum system are called eigenvalues. To each of the latter values corresponds one or more eigenstates. An eigenstate is degenerate when more than one eigenstate correspond to a single eigenvalue.
In this paper, we present a derivation of the relativistic equations of Quantum Mechanics. We focus on the second order equations (both Klein Gordon’s and Dirac’s), since the linear Dirac equation can be derived from these. This derivation is an extension of the same method applied to the non-relativistic case in a in a previous series of articles by us. We show that, to extend the theoretical framework to the relativistic case, we have only to extend the axioms in a relativistically compatible way, as should be the case with any extension of an axiomatic method. We also show that this quantization method throws light in a different way to interpret some descriptors of the usual formalism, mainly those regarding the expression for the probability density function. This, on the other hand, gives the teacher following this approach in classes on the subject to assess the epistemological issue of the role of manuals in the learning of Quantum Mechanics.
A new relativistic quantum wave equation has been derived by applying the quantum prescription to the momentum and the kinetic energy rather than to the momentum and the total energy, since after all it is the kinetic energy that generates the momentum. The resulting equation reduces to the Schrodinger equation in the nonrelativistic limit and to the Klein-Gordon equation for “massless particles” in the relativistic limit, i.e., if the velocity of the particle approaches that of light, c. For massive particles in general, the new equation deviates from the Klein-Gordon equation. The same equation is shown to decouple according to the Dirac formalism, yielding a modified form of Dirac equation. When applied to a rest particle, the modified Dirac equation is shown to avoid a negative energy solution and instead include a constant solution. The other, the time-dependent particle solution of the modified Dirac equation, has the characteristic frequency Mc2/(ћ/2) , i.e., twice those of the Dirac solutions, Mc2/ћ.