Topological states of matter present a wide variety of striking new phenomena. Prominent among these is the fractionalisation of electrons into unusual particles: Majorana fermions [1], Laughlin quasiparticles [2] or magnetic monopoles [3]. Their detection, however, is fundamentally complicated by the lack of any local order, such as, for example, the magnetisation in a ferromagnet. While there are now several instances of candidate topological spin liquids [4], their identification remains challenging [5]. Here, we provide a complete and exact theoretical study of the dynamical structure factor of a two-dimensional quantum spin liquid in gapless and gapped phases. We show that there are direct signatures - qualitative and quantitative - of the Majorana fermions and gauge fluxes emerging in Kitaev's honeycomb model. These include counterintuitive manifestations of quantum number fractionalisation, such as a neutron scattering response with a gap even in the presence of gapless excitations, and a sharp component despite the fractionalisation of electron spin. Our analysis identifies new varieties of the venerable X-ray edge problem and explores connections to the physics of quantum quenches.
We provide a complete and exact theoretical study of the dynamical structure factor of a twodimensional quantum spin liquid in gapless and gapped phases, as realized in Kitaev's honeycomb model.We show that there are direct signatures-qualitative and quantitative-of the Majorana fermions and gauge fluxes emerging in this model.These include counterintuitive manifestations of quantum number fractionalization, such as a neutron scattering response with a gap even in the presence of gapless excitations, and a sharp component despite the fractionalization of electron spin.Our analysis identifies new varieties of the venerable x-ray edge problem and explores connections to the physics of quantum quenches.
Quantum spin liquids (QSLs) host a variety of fractionalized particles. In Kitaev's paradigmatic honeycomb model a spin-fractionalizes intoflux due to emergentgauge field and matter Majorana fermions. Although these excitations have well-defined dynamics in the integrable limit, their direct experimental identification is notoriously challenging: realistic materials inevitably host additional symmetry-allowed interactions that break integrability and hybridize gauge and matter sectors, while magnetic fields, which are often required to suppress competing order and stabilize a putative QSL regime, further entangle the responses of different fractionalized quasiparticles and may even drive the system into field-induced spin-liquid phases that are not adiabatically connected to the integrable limit. A prominent example is the quantum Majorana metal, in which the distinct dynamics of fractionalized Majorana fermions can become directly visible in scattering. This review highlights recent progress on these related questions: in which field-stabilized QSL regimes and nearby emergent phases, and under what conditions, can the response of a specific fractionalized quasiparticle be isolated and positively understood, thereby clarifying the existence and the experimental scope of putative spin liquids? We review the progress on these questions across Abelian, non-Abelian, and emergent quantum phases under magnetic field that are not perturbatively connected to the integrable limit. We connect these field-induced dynamical phenomena to concrete experimental observables, relevant for neutron scattering, resonant inelastic x-ray scattering, and pump-probe spectroscopy, techniques that are capable of identifying the nature of different magnetic-field-induced phases and resolving specific types of fractionalized particles, including Majoranas andfluxes.
The formation of quantum spin liquids in frustrated magnets represents an exciting possibility due to the rather exotic features they harbor, including fractionalized excitations and emergent gauge fields. \nUnfortunately, they are notoriously difficult to study as there are often no good analytical methods available and quantum Monte Carlo simulations are hindered by the negative sign problem. \nThe Kitaev honeycomb model is a notable exception of a frustrated quantum model which is exactly solvable and which hosts a number of distinct quantum spin liquid ground states. \nAs such, it allows for a rare opportunity to study the physics of spin liquids with full analytical control. \n \nIn this thesis, we study the fractionalization of spin-1/2 moments into Majorana fermions and an emergent Z2 gauge field in a generalization of the Kitaev honeycomb model to a number of three-dimensional lattices. \nWhile the excitations of the gauge field are always gapped, the fermionic quasiparticles may exhibit a gapless dispersion, forming fully two-dimensional Fermi surfaces, symmetry protected nodal lines, or topological Weyl nodes. \nWe show that one can deduce rather general constraints on the possible gapless excitations by making use of an object called the projective symmetry group. \nIn doing so we provide a scheme for classifying the various gapless Kitaev spin liquids. \nA thorough analysis is carried out for a number of these spin liquids, primarily investigating the stability of the gapless modes and the novel features resulting from their sometimes non-trivial topology, as well as their effects on certain equal-time correlation functions.
Motivated by recent synthesis of the hyperhoneycomb material $\ensuremath{\beta}\text{\ensuremath{-}}{\mathrm{Li}}_{2}{\mathrm{IrO}}_{3}$, we study the dynamical structure factor (DSF) of the corresponding 3D Kitaev quantum spin-liquid (QSL), whose fractionalized degrees of freedom are Majorana fermions and emergent flux loops. The properties of this 3D model are known to differ in important ways from those of its 2D counterpart---it has a finite-temperature phase transition, as well as distinct features in the Raman response. We show, however, that the qualitative behavior of the DSF is broadly dimension-independent. Characteristics of the 3D DSF include a response gap even in the gapless QSL phase and an energy dependence deriving from the Majorana fermion density of states. Since the majority of the response is from states containing a single Majorana excitation, our results suggest inelastic neutron scattering as the spectroscopy of choice to illuminate the physics of Majorana fermions in Kitaev QSLs.
Unambiguous identification of fractionalized excitations in quantum spin liquids has been a long-standing issue in correlated topological phases. Conventional spectroscopic probes, such as the dynamical spin structure factor, can only detect composites of fractionalized excitations, leading to a broad continuum in energy. Lacking a clear signature in conventional probes has been the biggest obstacle in the field. In this work, we theoretically investigate what kinds of distinctive signatures of fractionalized excitations can be probed in two-dimensional nonlinear spectroscopy by considering the exactly solvable Kitaev spin liquids. We demonstrate the existence of a number of salient features of the Majorana fermions and fluxes in two-dimensional nonlinear spectroscopy, which provide crucial information about such excitations.
The Kitaev model on a honeycomb lattice with bond-dependent Ising interactions offers an exactly solvable model of a quantum spin liquid (QSL) with fractionalized excitations: gapped
Z2 fluxes and gapless linearly dispersing Majorana fermions in the isotropic limit (
Kx=Ky=Kz). We explore the phase diagram along two axes, an external magnetic field
h, applied out of plane of the honeycomb, and anisotropic interactions
Kz larger than the other two (${K}_{x}={K}_{y}\ensuremath{\equiv}K$). For ${K}_{z}/K\ensuremath{\gg}2$ and
h=0, the matter Majorana fermions have the largest gap, and the system is described by a gapped
Z2 toric code. One of the central questions we address is whether the fractionalized excitations in the different phases have sharp signatures that can be detected in experiments. We show that while the response to single-spin excitations is broad, the spectral function corresponding to two-spin excitations across a bond has sharp signatures that can be attributed to specific anyons. In the toric code regime, the $\ensuremath{\epsilon}=e\ifmmode\times\else\texttimes\fi{}m$ fermion, formed from the bosonic Ising electric (
e) and magnetic (
m) charges, disperses along a specific one-dimensional direction that provides a fingerprint of fractionalization. At lower
Kz in the center of the Abelian phase, in a regime we dub the primordial fractionalized regime, the field generates a hybridization between the $\ensuremath{\epsilon}$ fermion and the Majorana matter fermion, resulting in a $\ensuremath{\psi}$ fermion which too has a distinct quasi-one-dimensional dispersion. All the other phases in the field-anisotropy plane are naturally obtained from this primordial soup. These highly constrained fractonlike dispersions can be observable by inelastic light and neutron scattering, thereby providing ``smoking gun'' signatures of fractionalization in the QSL phase. Our analysis is based on calculations of susceptibilities, topological entanglement entropy, and excitation dynamics, obtained using exact diagonalization and density matrix renormalization group, and supported by perturbation theory.