The second law of thermodynamics states that entropy increases (or does not change) by time in an isolated system. As microscopic physical laws are reversible, the origin of irreversibility is not straightforward. Although the outcome of a measurement on a pure quantum state is not fully predictable due to the Heisenberg uncertainty principle, quantum and finite entropy uncertainties are thought to be fundamentally different. We propose to calculate the predictability of measurements comprising both quantum and entropic uncertainties. We show that the unpredictability of measurements is identical to entropy in case of semiclassical statistical mechanics, and it increases by time in a pure entangled quantum state as a result of quantum measurement.
The second law of thermodynamics states that entropy increases (or does not change) by time in an isolated system. As microscopic physical laws are reversible, the origin of irreversibility is not straightforward. Although the outcome of a measurement on a pure quantum state is not fully predictable due to the Heisenberg uncertainty principle, quantum and finite entropy uncertainties are thought to be fundamentally different. We propose to calculate the predictability of measurements comprising both quantum and entropic uncertainties. We show that the unpredictability of measurements is identical to entropy in case of semiclassical statistical mechanics, and it increases by time in a pure entangled quantum state as a result of quantum measurement.
The entropic uncertainty relation with quantum side information (EUR-QSI) from (Berta et al 2010 Nat. Phys. 6 659 ) is a unifying principle relating two distinctive features of quantum mechanics: quantum uncertainty due to measurement incompatibility, and entanglement. In these relations, quantum uncertainty takes the form of preparation uncertainty where one of two incompatible measurements is applied. In particular, the 'uncertainty witness' lower bound in the EUR-QSI is not a function of a post-measurement state. An insightful proof of the EUR-QSI from (Coles et al 2012 Phys. Rev. Lett. 108 210405 ) makes use of a fundamental mathematical consequence of the postulates of quantum mechanics known as the non-increase of quantum relative entropy under quantum channels. Here, we exploit this perspective to establish a tightening of the EUR-QSI which adds a new state-dependent term in the lower bound, related to how well one can reverse the action of a quantum measurement. As such, this new term is a direct function of the post-measurement state and can be thought of as quantifying how much disturbance a given measurement causes. Our result thus quantitatively unifies this feature of quantum mechanics with the others mentioned above. We have experimentally tested our theoretical predictions on the IBM quantum experience and find reasonable agreement between our predictions and experimental outcomes.
Measurement outcomes of a quantum state can be genuinely random (unpredictable) according to the basic laws of quantum mechanics. The Heisenberg-Robertson uncertainty relation puts constrains on the accuracy of two non-commuting observables. The existing uncertainty relations adopt variance or entropic measures, which are functions of observed outcome distributions, to quantify the uncertainty. According to recent studies of quantum coherence, such uncertainty measures contain both classical (predictable) and quantum (unpredictable) components. In order to extract out the quantum effects, we define quantum uncertainty to be the coherence of the state on the measurement basis. We discover a quantum uncertainty relation of coherence between two measurement non-commuting bases. Furthermore, we analytically derive the quantum uncertainty relation for the qubit case with three widely adopted coherence measures, the relative entropy of coherence, the coherence of formation, and the l1 norm of coherence.
Quantum mechanics is widely recognised as being incomplete. It is not consistent with the second law of thermodynamics and does not provide a scientifically credible physical account of the measurement process, the means by which coherence is broken and classically observable states are recorded. This has led to many ad hoc assumptions being used to account for various properties of quantum systems, among which is the coherence time of quantum devices that determines their ability to perform computations. Here, we show that all these properties can be accommodated naturally and consistently in the context of mixing quantum systems which exhibit continuous spectra, as arises in the thermodynamic limit in quantum statistical mechanics and quantum gravity. In particular, for isolated systems we show that the time-reversal symmetry associated with unitary time evolution of the quantum state gives rise to time-symmetry breaking and a semi-group evolution which attains thermodynamic equilibrium at long times. Moreover, the emergence of this non-unitary time-asymmetry leads to microcanonical equilibrium states in which all quantum coherence is lost and is accompanied by the transformation of pure states into mixtures, leading in turn to an increase in entropy. Inclusion of a macroscopic measurement apparatus shows how the outcome of a measurement corresponds to the von Neumann projection postulate, arising with probabilities in conformance with the Born rule. The mathematical structure of the theory which applies to quantum systems with continuous spectra is closely analogous to the classical ergodic theory of dynamical systems and the conditions under which they attain equilibrium states.
Measurement outcomes of a quantum state can be genuinely random (unpredictable) according to the basic laws of quantum mechanics. The Heisenberg-Robertson uncertainty relation puts constraints on the accuracy of two noncommuting observables. The existing uncertainty relations adopt variance or entropic measures, which are functions of observed outcome distributions, to quantify the uncertainty. According to recent studies of quantum coherence, such uncertainty measures contain both classical (predictable) and quantum (unpredictable) components. In order to extract out the quantum effects, we define quantum uncertainty to be the coherence of the state on the measurement basis. We discover a quantum uncertainty relation using coherence between two measurement noncommuting bases. Furthermore, we analytically derive the quantum uncertainty relation for the qubit case with three widely adopted coherence measures, the relative entropy of coherence, the coherence of formation, and the l1 norm of coherence.
We consider the temporal evolution of an isolated system of particles from a non-equilibrium state of entropy S = S′ to the equilibrium state of maximum entropy S = S max, S′ ≤ S max. The application of usual density matrix theory to the temporal development of S leads us to the unexpected result P = dS/dt = 0. The entropy does not change in time. This result is valid in case of the equilibrium state. However it is wrong for a non-equilibrium state, which could not irreversibly change from S′ to S max by entropy production P > 0. This contradicts the second law of thermodynamics. The paradoxial result can be traced back to the Liouville theorem. To overcome this difficulty, we introduce the t–P space. The time t and the entropy production P are observables in quantum thermodynamics. They are defined by the eigenvalue equations t|t〉 = t|t〉 and P|P〉 = P|P〉. The operators t and P do not commute. We have a non-vanishing commutator, [t,P] = ik, and consequently a t–P uncertainty relation, ΔtΔP ≥ k/2. The Boltzmann constant k is characteristic of quantum thermodynamics and represents the atomic entropy unit. — The time evolution operator U(τ) = exp[−(i/k)τP] shifts the time t by τ, U(τ)|t〉 = |t + τ〉. The generator of τ is the operator P of entropy production. Then the eigenvector |P〉 is also an eigenket of U(t), and it follows with progressing time τ ≥ 0 that τP ≥ 0 and hence P = dS/dt ≥ 0. This is the second law of thermodynamics, which is correctly reproduced in quantum thermodynamics. — Exchanging −τ for +τ replaces the equations of forward time +τ by the equations of backward time −τ. Independent of the direction of the arrow of time, the entropy of the system always increases or remains constant in the limit of the equilibrium state, dS ≥ 0. This is characteristic of irreversibility, for the system does not return to its initial state on time reversal. — The t–P uncertainty relation allows to discuss the temporal evolution of the expectation value 〈P〉 of entropy production and the lifetime Δt of the transient states, the system passes through on approaching the equilibrium state. In case of a non-equilibrium state 〈P〉, ΔP, and Δt are finite. On approaching the equilibrium state, 〈P〉 and ΔP decrease, consequently Δt increases. Finally, in the case of equilibrium (eq), we have 〈P〉eq = 0, ΔP eq = 0, and Δt eq → ∞. The lifetime of the equilibrium state is unlimited, because the entropy production 〈P〉 and the uncertainty of entropy production ΔP exactly vanish. The temporal evolution of the system can be described by means of a phenomenological equation.
The notion of entropy has been at the core of thermodynamics and statistical physics since the 19th century, originally mentioned in the statement of the second law of thermodynamics as ``entropy is non-decreasing in an isolated system.'' In the context of both classical and quantum mechanics, there are cases where the second law is violated. In other words, entropy of the system may fluctuate downward. The question of how low or high the entropy of a quantum system can get is of interest in the context of small systems that can maintain quantum coherence for short times, and in the context of our universe, assuming it is an isolated quantum system. We explore the rare and extreme fluctuations of two well-developed notions of entropy that are relevant and interesting in isolated thermodynamic quantum systems, namely the observational and entanglement entropy. We find several fundamental differences in the behavior of the two when fluctuating to their extremes. We also provide an analytical proof of a tight upper bound on entanglement entropy for systems constrained to conservation laws.