We introduce a general formalism to describe the effects of Markovian noise which is spatially correlated, typically decaying over some finite correlation length. For any system of interest, this formalism describes spatial correlations without the necessity to choose a particular microscopic model for the environment. We present a method of mapping the equations to Lindblad form and discuss functional forms for homogeneous spatial correlation functions. We also discuss two example microscopic models for the environment which exhibit nontrivial spatial-temporal correlation functions.
We introduce a general formalism to describe the effects of Markovian noise which is spatially correlated, typically decaying over some finite correlation length. For any system of interest, this formalism describes spatial correlations without the necessity to choose a particular microscopic model for the environment. We present a method of mapping the equations to Lindblad form and discuss functional forms for homogeneous spatial correlation functions. We also discuss two example microscopic models for the environment which exhibit nontrivial spatial-temporal correlation functions.
The challenge of making nano-scale quantum systems experimentally accessible is being overcome for an increasing diversity of systems by improved fabrication techniques and experimental control. Despite rapid progress, one of the main hindrances in all experiments is the difficulty of isolating the quantum system from the surrounding environment and its fluctuations. This experimental “noise” perturbs the quantum system, a process that is generally referred to as decoherence: the system slowly loses its distinguishing quantum features. In this thesis the effects of spatial correlations in the noise environment with a finite correlation length are investigated. The consequences for the experimental design of controlled quantum systems as well as the dynamics of solid state systems are presented. We utilize the Bloch-Redfield formalism, a Markovian master equation approach, which gives a close connection to the underpinning system-environment model. We show how to use this formalism to model any spatial correlation function of the noise environment. Using microscopic environmental models, several correlation functions are derived and their properties connected to the environmental parameters. Several phenomenological correlation functions are also studied and a mapping to the Lindblad master equation is presented, which provides a test of positivity for phenomenological models. For quantum transport through spin chains and networks, noise is generally detrimental. Spatial correlations however reduce the effect of dephasing noise and can reinstate the transport dynamics. The critical correlation length proves to be closely connected to the maximal packet width of one excitation in the transfer process. For dissipation noise, relaxation-free states emerge with spatial correlations. The decay of an excitation is therefore fundamentally modified into a fast decay towards an intermediate relaxation-reduced state and a subsequent decay to the ground state on a much longer time scale. In quantum metrology noise correlations have been observed in experiments with trapped ions, in which they limit the use of such experiments for metrology. Quantum advantage, i.e. a better precision scaling than the standard quantum limit has been proven impossible in the presence of uncorrelated Markovian noise only. We show that for certain optimized states the best possible quantum advantage, Heisenberg scaling, can be achieved in the presence of noise with a finite spatial decay of correlations. We furthermore identify how dephasing effects change and a topology dependence arises in strength with increasing correlation length for entangled states in a general way. Biological photosynthetic complexes have recently been found to potentially include quantum coherent dynamics, particularly in the process of transmitting an exciton from the point of creation to the reaction centre. We show how the formalism of spatially correlated decoherence adapts to this significantly different energy regime. Typical effects of decoherence in this field are presented and we show how the light-harvesting efficiency is influenced by spatial correlations in the noise. This thesis highlights the fundamental relevance of noise correlations to several fields of quantum physics and the importance of the efficient and comprehensive modelling techniques presented.
An open quantum system is a quantum system that interacts with some environment whose degrees of freedom have been coarse grained away. This model describes non-equilibrium processes more general than scattering-matrix formulations. Furthermore, the microscopically-derived environment provides a model of noise, dissipation and decoherence far more general than Markovian (white noise) models. The latter are fully characterized by Lindblad equations and can be motivated phenomenologically. Non-Markovian processes consistently account for backreaction with the environment and can incorporate effects such as finite temperature and spatial correlations. We consider linear systems with bilinear coupling to the environment, or quantum Brownian motion, and nonlinear systems with weak coupling to the environment. For linear systems we provide exact solutions with analytical results for a variety of spectral densities. Furthermore, we point out an important mathematical subtlety which led to incorrect master-equation coefficients in earlier derivations, given nonlocal dissipation. For nonlinear systems we provide perturbative solutions by translating the formalism of canonical perturbation theory into the context of master equations. It is shown that unavoidable degeneracy causes an unfortunate reduction in accuracy between perturbative master equations and their solutions. We also extend the famous theorem of Lindblad, Gorini, Kossakowski and Sudarshan on completely positivity to non-Markovian master equations. Our application is primarily to model atoms interacting via a common electromagnetic field. The electromagnetic field contains correlations in both space and time, which are related to its relativistic (photon-mediated) nature. As such, atoms residing in the same field experience different environmental effects depending upon their relative position and orientation. Our more accurate solutions were necessary to assess sudden death of entanglement at zero temperature. In contrast to previous claims, we found that all initial states of two-level atoms undergo finite-time disentanglement. We were also able to access regimes which cannot be described by Lindblad equations and other simpler methods, such as near resonance. Finally we revisit the infamous Abraham-Lorentz force, wherein a single particle in motion experiences backreaction from the electromagnetic field. This leads to a number of well-known problems including pre-acceleration and runaway solutions. We found a more a more-suitable open-system treatment of the nonrelativistic particle to be perfectly causal and dissipative without any extraneous requirements for finite size of the particle, weak coupling to the field, etc..
We microscopically model the decoherence dynamics of entangled coherent states under the influence of vacuum fluctuation. We derive an exact master equation with time-dependent coefficients reflecting the memory effect of the environment, by using the Feynman-Vernon influence functional theory in the coherent-state representation. Under the Markovian approximation, our master equation recovers the widely used Lindblad equation in quantum optics. We then investigate the non-Markovian entanglement dynamics of the quantum channel in terms of the entangled coherent states under noise. Compared with the results in Markovian limit, it shows that the non-Markovian effect enhances the disentanglement to the initially entangled coherent state. Our analysis also shows that the decoherence behaviors of the entangled coherent states depend sensitively on the symmetrical properties of the entangled coherent states as well as the interactions between the system and the environment.
The ubiquitous effects of the environment on quantum-mechanical systems generally cause temporally correlated fluctuations. This particularly holds for systems of interest for quantum computation where such effects lead to correlated errors. The Markovian approximation neglects these correlations and thus fails to accurately describe open-system dynamics where these correlations become relevant. In driven open systems, yet another approximation is persistently used, often unknowingly, in which one describes the decay effects independently from the time-dependent controlling fields acting on the system, thereby ignoring further temporally correlated effects. To overcome these shortcomings, we develop a quantum master equation for driven systems weakly coupled to quantum environments that avoids the aforementioned field-independent approximation, as well as the Markovian approximation. Our method makes it possible to track all occurring decay channels and their time-dependent generalized rates which we illustrate in the example of a generally driven two-level system. We also demonstrate that correlated and field-dependent dissipative effects can lead to an increase in the performance of single-qubit gate operations.
We study the role of correlations with the environment as the source of non-Markovian quantum evolutions. We first focus on the impact that correlations with the environment can have on the dynamical map that evolve the system. We expand the set of initial states of a system and its environment that are known to guarantee completely positive reduced dynamics for the system when the combined state evolves unitarily. We characterize the correlations in the initial state in terms of its quantum discord. The induced maps can be not completely positive when quantum correlations including, but not limited to, entanglement are present. We discuss the implications and limitations of the Markov approximation necessary to derive the Kossakowski-Lindblad master equation. A generalized non-Markovian master equation is derived from the dynamical map of systems correlated with their environment. The physical meaning of not completely positive maps is studied to obtain a consistent theory of non-Markovian quantum dynamics. These are associated to inverse maps necessary to establish correlations and they give rise to a canonical embedding map that is local in time. This master equation goes beyond the Kossakowski-Lindblad master equation. Non-equilibrium quantum thermodynamics can be be studied within this theory. Through out this discussion, the general dynamics of two interacting qubits is used as an example for illustrations.
Decoherence is often modeled using Markovian master equations that predict exponential suppression of coherence and are frequently used as effective bounds on quantum behavior in complex environments. Such descriptions, however, correspond to the singular physical limit of vanishing environmental memory. Here we formulate decoherence using a general time-nonlocal decoherence functional determined solely by the environmental force correlation function, with Markovian dynamics recovered explicitly as a limiting case.
For arbitrary stationary environments with finite temporal correlations, we show that the decoherence functional exhibits quadratic short-time growth that is model-independent within the finite-memory class considered. Consequently, the decoherence time defined operationally-without assuming exponential decay-scales as the square root of the environmental correlation time, independent of the detailed form of the bath correlation kernel.
These results are illustrated analytically for Gaussian-correlated, soft power-law, and Ornstein-Uhlenbeck environments. In the Ornstein-Uhlenbeck case, the non-Markovian dynamics admit an exact analytical closure, yielding a closed evolution equation for the coherence. Exact numerical simulations based on a pseudomode mapping confirm the predicted scaling and show that exponential decoherence emerges only in the memoryless limit.
Beyond coherence decay, we distinguish decoherence rates from observable loss of quantum signatures by analyzing purity and von Neumann entropy dynamics. We show that suppression of a specific coherence element need not coincide with irreversible entropy production. Finally, we introduce an inferred-memory perspective in which the environmental correlation time is treated as an operationally extractable parameter from dynamical data.