The ubiquitous effects of the environment on quantum-mechanical systems generally cause temporally correlated fluctuations. This particularly holds for systems of interest for quantum computation where such effects lead to correlated errors. The Markovian approximation neglects these correlations and thus fails to accurately describe open-system dynamics where these correlations become relevant. In driven open systems, yet another approximation is persistently used, often unknowingly, in which one describes the decay effects independently from the time-dependent controlling fields acting on the system, thereby ignoring further temporally correlated effects. To overcome these shortcomings, we develop a quantum master equation for driven systems weakly coupled to quantum environments that avoids the aforementioned field-independent approximation, as well as the Markovian approximation. Our method makes it possible to track all occurring decay channels and their time-dependent generalized rates which we illustrate in the example of a generally driven two-level system. We also demonstrate that correlated and field-dependent dissipative effects can lead to an increase in the performance of single-qubit gate operations.
The ubiquitous effects of the environment on quantum-mechanical systems generally cause temporally correlated fluctuations. This particularly holds for systems of interest for quantum computation where such effects lead to correlated errors. The Markovian approximation neglects these correlations and thus fails to accurately describe open-system dynamics where these correlations become relevant. In driven open systems, yet another approximation is persistently used, often unknowingly, in which one describes the decay effects independently from the time-dependent controlling fields acting on the system, thereby ignoring further temporally correlated effects. To overcome these shortcomings, we develop a quantum master equation for driven systems weakly coupled to quantum environments that avoids the aforementioned field-independent approximation, as well as the Markovian approximation. Our method makes it possible to track all occurring decay channels and their time-dependent generalized rates which we illustrate in the example of a generally driven two-level system. We also demonstrate that correlated and field-dependent dissipative effects can lead to an increase in the performance of single-qubit gate operations.
An essential action in quantum information processing is the manipulation (control) of a single qubit, ideally a closed two-level system. However, in realistic applications, quantum processes are often under the influence of the external environment, e.g., presenting some degree of dissipation and decoherence. In this paper we address the emerging difficulties in the (tracking) quantum control of a two-level system under the influence of both Markovian and non-Markovian noise. We employ a same framework to treat both situations, a Lindblad-type equation, but considering that for the former (latter) case, the decay rate $\mathrm{\ensuremath{\Gamma}}$ is time independent (dependent). We discuss the conditions leading to a breakdown of the quantum control and eventual ways to overcome the problem, like employing a fast control scheme or controlling the off-diagonal terms of the system density matrix. Surprisingly, for Markovian noise such breakdown time decreases with $\mathrm{\ensuremath{\Gamma}}$ not as an exponential but as a power law. This indicates that the quantum control should be possible for a coupling between the system and the environment stronger than previously expected. Moreover, we find that for non-Markovian noise, the breakdown time is longer when there is backflow, i.e., $\mathrm{\ensuremath{\Gamma}}(t)$ can be negative. The present theoretical results point to certain favorable scenarios to operate qubits even in a noisy medium.
Environmental noise is a major source of decoherence and errors in quantum systems. In a non-Markovian environment, the noise has a finite correlation time, and the system can retain information about its previous interactions with the environment. Here, we investigate how such environmental memory can be observed through a finite-duration coherent quantum operation. Coherent control dynamically reshapes the stochastic coupling operator and thereby changes how two-time noise correlations affect the quantum process. For Ornstein-Uhlenbeck noise, we show analytically that two different limits reduce the information on the correlation time. In the short-memory limit, the leading dynamics depend on the integrated-noise combination σ/τc, where σ is the noise variance and τc is the correlation time, making these parameters locally degenerate. In the long-memory limit, the stochastic field becomes quasi-static during the operation, and sensitivity to the correlation time is suppressed. Exact stochastic simulations for a driven single-qubit Xπ rotation and a two-qubit exchange gate show that independent correlation-time information becomes largest between these limits, when the environmental and control timescales are comparable. Noncommuting controls enhance this information, whereas commuting controls do not. Simulations at different gate durations tg further show that the information window approximately follows the dimensionless correlation ratio τc/tg. These results provide a timescale-matching principle for probing finite-correlation non-Markovian noise with coherent quantum control.
Driven quantum systems subject to non-Markovian noise are typically difficult to model even if the noise is classical. We present a systematic method based on generalized cumulant expansions for deriving a time-local master equation for such systems. This master equation has an intuitive form that directly parallels a standard Lindblad equation, but contains several surprising features: the combination of driving and non-Markovianity results in effective time-dependent dephasing rates that can be negative, and the noise can generate Hamiltonian renormalizations even though it is classical. We analyze in detail the highly relevant case of a Rabi-driven qubit subject to various kinds of non-Markovian noise including 1/f fluctuations, finding an excellent agreement between our master equation and numerically-exact simulations over relevant timescales. The approach outlined here is more accurate than commonly employed phenomenological master equations which ignore the interplay between driving and noise.
The theory of open quantum systems represents one of the major developments of quantum mechanics over the last 50 years. Its central object of study is constituted by quantum systems that cannot be regarded as fully isolated, but instead interact with additional degrees of freedom, giving rise to irreversible phenomena such as dissipation and decoherence. The tools provided by this framework are nowadays of paramount importance across many active areas of research, including quantum computation, thermodynamics, metrology and biology. In this thesis, we investigate three main topics within the field. The first contribution concerns the microscopic derivation of the evolution equations, socalled quantum master equations, for open systems which are also subject to external driving fields. Standard techniques developed for time-independent Hamiltonians encounter several difficulties in the time-dependent case, largely restricting their applicability to specific instances, such as periodic or adiabatic drivings. In contrast, a core result of the derivation presented in the thesis is that, when the environment is sufficiently Markovian (essentially, memoryless), the non-adiabatic contributions to the driving field can be neglected in a controlled fashion, yielding an accurate master equation with time-dependent generator, capable of correctly reproducing the open dynamics even for strong drivings. This result is further supported by benchmarks against numerically exact simulations. The second contribution addresses the long-time behavior of general types of (Markovian) quantum master equations, including those of the form introduced above. While this problem has been extensively analyzed in the time-independent setting, virtually no results are known for time-dependent generators. In particular, we establish the foundations of a general theory of relaxation, that is, convergence towards an asymptotic trajectory in the long-time limit, independently of the initial state. The main results include a theorem guaranteeing sufficient conditions for relaxation and the derivation of a rate function governing the convergence to the asymptotic trajectory. The analysis is further extended to a simple non-Markovian case. Moreover, we treat in detail the specific master equation derived in the first part, connecting the aforementioned relaxation property directly to the underlying microscopic dynamics. The third contribution investigates chirality-induced spin selectivity (CISS) effects from the perspective of open quantum systems. Although the majority of theoretical studies aiming to model CISS are based on a coherent description of the spin dynamics, such effects have been observed also for electrons subject to incoherent transport across molecular networks. In this regard, we provide a rigorous ab initio derivation of the microscopic Hamiltonian describing the electronic transport, incorporating electron spin effects and contributions stemming from the nuclear vibrations. Within this result, we critically revise a master equation approach aiming to explain the origin of CISS effects observed in photosynthetic complexes. Taken together, these contributions offer fresh insights and original results on the interplay between driving fields and dissipation, relaxation phenomena, and electronic spin transport in the presence of incoherent dynamics. More broadly, these results provide new theoretical tools with several potential applications in quantum technologies, from modeling of control pulses in noisy environments to quantum reservoir engineering, and contribute to a deeper understanding of the role of quantum effects in biological systems.
We describe temporally correlated noise processes that influence the idle evolution of a superconducting transmon qubit. To model the composite qubit-environment system we use quantum circuit theory, and we show how a circuit Hamiltonian can be derived for transverse noise affecting the qubit. Based on the time-convolutionless projection operator method, we construct a time-local master equation which, when transformed to its canonical Lindblad form, exhibits a decay rate that is negative at all times, corresponding to eternally non-Markovian dynamics. By expressing the solution of the master equation in the Kraus representation, we identify two crucial non-Markovian phenomena: periodic revivals of coherence, and the appearance of additional frequencies far from the qubit frequency in the precession of the qubit state. When a single qubit gate acts on the qubit state, these extra frequency terms rotate undesirably and they effectively act as the memory of the state prior to the rotation around the Bloch sphere.
We propose a model based on a generalized effective Hamiltonian for studying the effect of noise in quantum computations. The system-environment interactions are taken into account by including stochastic fluctuating terms in the system Hamiltonian. Treating these fluctuations as Gaussian Markov processes with zero mean and $\ensuremath{\delta}$-function correlation times, we derive an exact equation of motion describing the dissipative dynamics for a system of n qubits. We then apply this model to study the effect of noise on the quantum teleportation and a generic quantum controlled-NOT (CNOT) gate. For quantum teleportation, the effect of noise in the quantum channels is found to be additive, and the teleportation fidelity depends on the state of the teleported qubit. The effect of collective decoherence is also studied for the two-qubit entangled states. For the quantum CNOT gate, we study the effect of noise on a set of one- and two-qubit quantum gates, and show that the results can be assembled together to investigate the quality of a quantum CNOT gate operation. We compute the averaged gate fidelity and gate purity for the quantum CNOT gate and investigate phase, bit-flip, and flip-flop errors during the CNOT gate operation. The effects of direct interqubit coupling and fluctuations on the control fields are also studied. We find that the quality of the CNOT gate operation is sensitive to the strengths of the control fields and the strengths of the noise, and the effect of noise is additive regardless of its origin. We discuss the limitations and possible extensions of this model. In sum, we demonstrate a simple model that enables us to investigate the effect of noise in arbitrary quantum circuits under realistic device conditions.