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arXiv:1205.5304 · Physical Review A

Formation of ultracold fermionic NaLi Feshbach molecules

Myoung-Sun Heo, Tout T. Wang, Caleb A. Christensen, Timur M. Rvachov, Dylan A. Cotta, Jae-Hoon Choi, Ye-Ryoung Lee, Wolfgang Ketterle

Published Aug 6, 2012• 112 citations
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Abstract

We describe the formation of fermionic NaLi Feshbach molecules from an ultracold mixture of bosonic ${}^{23}$Na and fermionic ${}^{6}$Li. Precise magnetic field sweeps across a narrow Feshbach resonance at 745 G result in a molecule conversion fraction of $5%$ for our experimental densities and temperatures, corresponding to a molecule number of $5\ifmmode\times\else\texttimes\fi{}{10}^{4}$. The observed molecular decay lifetime is $1.3$ ms after removing free Li and Na atoms from the trap. Due to its extremely low reactivity, NaLi molecules in the ground state will have a much longer lifetime than KRb.

DOI
10.1103/physreva.86.021602

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We report the creation of ultracold bosonic 23 Na 87 Rb Feshbach molecules via magneto-association. By ramping the magnetic field across an interspecies Feshbach resonance (FR), at least 4000 molecules can be produced out of the near degenerate ultracold mixture. Fast loss due to inelastic atom–molecule collisions is observed, which limits the pure molecule number, after residual atoms removal, to 1700. The pure molecule sample can live for 21.8(8) ms in the optical trap, long enough for future molecular spectroscopy studies toward coherently transferring to the singlet ro-vibrational ground state, where these molecules are stable against chemical reaction and have a permanent electric dipole moment of 3.3 Debye. We have also measured the Feshbach molecule's binding energy near the FR by the oscillating magnetic field method and found these molecules have a large closed-channel fraction.
Ultracold Feshbach molecules are a crucial intermediate step for the creation of quantum degenerate gases of strongly dipolar molecules. After coherent transfer to the rovibrational ground state, these dimers can realize stable dipolar gases with strong, tunable long-range interactions. Here, we report the creation of bosonic Na 23 K 41 Feshbach molecules by radio-frequency (RF) association. An RF pulse applied on the molecular side of an interspecies Feshbach resonance at 73.6(1) G associates up to 1.1 ( 1 ) × 10 4 molecules from a thermal mixture of Na 23 and K 41 atoms. Measurements of the binding energy reveal a broad resonance width of 5.1(2) G, facilitating robust control over interspecies interactions. The molecule lifetime in the presence of background atoms exceeds 2 ms and increases to approximately 7 ms after removal of Na 23 . These results constitute a key step toward the production of ultracold Na 23 K 41 ground-state molecules and for pursuing shielded evaporative cooling in the dipolar regime.
We create fermionic dipolar ^{23}Na^{6}Li molecules in their triplet ground state from an ultracold mixture of ^{23}Na and ^{6}Li. Using magnetoassociation across a narrow Feshbach resonance followed by a two-photon stimulated Raman adiabatic passage to the triplet ground state, we produce 3×10^{4} ground state molecules in a spin-polarized state. We observe a lifetime of 4.6 s in an isolated molecular sample, approaching the p-wave universal rate limit. Electron spin resonance spectroscopy of the triplet state was used to determine the hyperfine structure of this previously unobserved molecular state.
We report on the formation of ultracold weakly bound Feshbach molecules of [superscript 23]Na[superscript 40]K, the first fermionic molecule that is chemically stable in its absolute ground state. The lifetime of the nearly degenerate molecular gas exceeds 100 ms in the vicinity of the Feshbach resonance. The measured dependence of the molecular binding energy on the magnetic field demonstrates the open-channel character of the molecules over a wide field range and implies significant singlet admixture. This will enable efficient transfer into the singlet vibrational ground state, resulting in a stable molecular Fermi gas with strong dipolar interactions.
We investigate magnetoassociation of ultracold fermionic Feshbach molecules in a mixture of 40{}^{40}40K and 87{}^{87}87Rb atoms, where we can create 40{}^{40}40K87{}^{87}87Rb molecules with a conversion efficiency as high as 45%. In the limit of fast magnetic sweeps and small molecule fraction, we find that the time scale of molecule production is accurately predicted by a parameter-free model that uses only the atomic densities, masses, and the known Feshbach resonance parameters. We find that molecule production efficiency saturates for slower magnetic sweeps, at which point the maximum number of Feshbach molecules depends primarily on the atoms' phase-space density. At higher temperatures, our measurements agree with a phenomenological model that successfully describes the formation of bosonic molecules from either Bose or Fermi gases. However, for quantum degenerate atom gas mixtures, we measure significantly fewer molecules than this model predicts.
We create fermionic dipolar 23 Na 6 Li molecules in their triplet ground state from an ultracold mixture of 23 Na and 6 Li.Using magnetoassociation across a narrow Feshbach resonance followed by a two-photon stimulated Raman adiabatic passage to the triplet ground state, we produce 3 × 10 4 ground state molecules in a spin-polarized state.We observe a lifetime of 4.6 s in an isolated molecular sample, approaching the p-wave universal rate limit.Electron spin resonance spectroscopy of the triplet state was used to determine the hyperfine structure of this previously unobserved molecular state.